公开(公告)号：EP2874991A1

公开(公告)日：2015-05-27

申请号：EP13739190.0

申请日：2013-07-16

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  RÜDENAUER, Stefan ,  SCHNEIDER, Daniel ,  PACIELLO, Rocco

IPC: C07C67/00 ,  B01J31/22

CPC classification number: C07C67/00 ,  B01J31/2273 ,  B01J2231/763 ,  B01J2531/821 ,  B01J2531/827 ,  C07C69/24 ,  C07C69/78

Abstract: The present invention relates to a method for producing carboxylic acid esters, comprising the reaction of at least one primary mono alcohol or a mixture of a primary mono alcohol and at least one alcohol differing from this in the presence of a transition metal carbene complex catalyst (K), which has as the central atom (M) at least one transition metal atom of group 8, 9 or 10 of the periodic table (IUPAC) and at least one monodentate N-heterocyclic carbene ligand, in the presence of a base, characterized in that the catalyst (K) is produced by reaction of a transition metal compound (V), which has at least one transition metal atom of group 8, 9 or 10 of the periodic table (IUPAC), but no carbene ligand, with an imidazolium salt in the presence of the primary mono alcohol and the base, wherein the reaction is a bulk reaction.

Abstract translation: 本发明涉及一种用于生产羧酸酯，其包含至少一个伯一元醇的在过渡金属卡宾络合物催化剂的存在下与此不同的反应或伯单醇的混合物和至少一种醇（ K），其具有作为中心原子（M）基团8,9或周期表的第10中的至少一个过渡金属原子（IUPAC）和至少一种单齿N-杂环卡宾配体，在碱的存在下， dadurch gekennzeichnet，DASS模具催化剂（K）是由过渡金属化合物（V），其具有第8族，9或周期表（IUPAC）10中的至少一个过渡金属原子的反应所产生，但无碳烯配体，具有 在主元醇与碱的存在咪唑鎓盐，worin反应是本体反应。

公开(公告)号：EP2588439B1

公开(公告)日：2014-04-23

申请号：EP11726423.4

申请日：2011-06-21

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  FRIES, Donata Maria ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  RITTINGER, Stefan ,  SCHNEIDER, Daniel

IPC: C07C51/00 ,  C07C53/02

CPC classification number: C07C51/00 ,  C07C53/02

公开(公告)号：EP2445860B1

公开(公告)日：2013-05-29

申请号：EP10725137.3

申请日：2010-06-11

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHNEIDER, Daniel ,  SCHÄFER, Martin ,  RITTINGER, Stefan

IPC: C07C51/00 ,  C07C51/44 ,  C07C53/02

CPC classification number: C07C51/00 ,  B01J31/0237 ,  B01J31/24 ,  B01J31/2414 ,  B01J2231/625 ,  B01J2531/821 ,  C07C51/44 ,  Y02P20/582 ,  C07C53/02

公开(公告)号：EP2588440A1

公开(公告)日：2013-05-08

申请号：EP11728826.6

申请日：2011-06-28

Applicant: BASF SE

Inventor： SCHNEIDER, Daniel ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  PICKENÄCKER, Karin ,  RITTINGER, Stefan ,  SCHAUB, Thomas ,  TELES, Joaquim Henrique ,  PACIELLO, Rocco ,  KAIBEL, Gerd

IPC: C07C51/44 ,  C07C51/50 ,  C07C53/02

CPC classification number: C07C51/44 ,  C07C51/09 ,  C07C51/50 ,  C07C53/02

Abstract: The invention relates to a method for obtaining formic acid by the thermal separation of a flow containing formic acid and a tertiary amine (I), wherein a liquid flow which contains formic acid and a tertiary amine (I) in a molar ratio of 0.5 to 5 is produced by combining tertiary amine (I) and a source of formic acid, 10 to 100 wt % of the secondary components contained in said flow are separated, and formic acid is removed by distillation from the resulting liquid flow in a distillation device at a bottoms temperature of 100 to 300°C and a pressure of 30 to 3000 hPa abs, wherein the bottoms product from the distillation device is separated into two liquid phases and the upper liquid phase is returned to the source of formic acid and the lower liquid phase is returned for separation of the secondary components and/or to the distillation device.

Abstract translation: 本发明涉及通过含有甲酸和叔胺（I）的流的热分离来获得甲酸的方法，其中含有摩尔比为0.5至1.5的甲酸和叔胺（I）的液体流 5是通过混合叔胺（I）和甲酸来制备的，分离所述流中含有10-100重量％的二次成分，并通过蒸馏从蒸馏装置中得到的液流中除去甲酸 底部温度为100〜300℃，压力为30〜3000hPa abs，其中来自蒸馏装置的塔底产物分离成两液相，上液相返回到甲酸源，下液 返回相分离次级组分和/或蒸馏装置。