公开(公告)号：EP3846929A1

公开(公告)日：2021-07-14

申请号：EP19762156.8

申请日：2019-09-03

Applicant: BASF SE

Inventor： BEY, Oliver ,  ZEHNER, Peter ,  ACKER, Michael ,  PACIELLO, Rocco ,  SCHELWIES, Mathias ,  HAUBNER, Martin ,  WEGNER, Guenter ,  TEBBEN, Gerd ,  HEYDRICH, Gunnar ,  SEEBER, Georg

IPC: B01J10/00 ,  B01J19/18 ,  B01J19/26 ,  B01J19/30 ,  C07C29/17 ,  C07C29/56 ,  C07C45/62 ,  C07B53/00 ,  B01J19/24 ,  B01J19/32 ,  B01J19/00 ,  B01J3/04

公开(公告)号：EP3362426B1

公开(公告)日：2020-09-02

申请号：EP16784149.3

申请日：2016-10-11

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  PACIELLO, Rocco ,  ERNST, Martin ,  MORMUL, Jaroslaw ,  BREITENFELD, Jan ,  TRAPP, Oliver ,  HOFMANN, Peter

IPC: C07C29/141 ,  C07C45/49 ,  C07C51/16 ,  C07C209/26 ,  C07C31/18 ,  C07C47/12 ,  C07C55/14 ,  C07C211/12

公开(公告)号：EP3638655A1

公开(公告)日：2020-04-22

申请号：EP18730325.0

申请日：2018-06-06

Applicant: BASF SE

Inventor： PAZICKY, Marek ,  ERNST, Martin ,  MARION, Nicolas ,  PACIELLO, Rocco ,  MELDER, Johann-Peter ,  LUYKEN, Hermann

IPC: C07D317/26 ,  C07C29/141 ,  B01J31/00

公开(公告)号：EP3137445B1

公开(公告)日：2019-10-02

申请号：EP15718908.5

申请日：2015-04-29

Applicant: BASF SE

Inventor： SCHELWIES, Mathias ,  PACIELLO, Rocco ,  ECKHARDT, Heinz ,  DEHN, Martine

IPC: C07C45/54 ,  C07C45/62 ,  C07C49/04 ,  C07C49/203

公开(公告)号：EP3172356B1

公开(公告)日：2018-09-19

申请号：EP15749738.9

申请日：2015-07-22

Applicant: BASF SE

Inventor： STRAUTMANN, Julia ,  PACIELLO, Rocco ,  SCHAUB, Thomas ,  EICKEMEYER, Felix ,  LÖFFLER, Daniel ,  WILMER, Hagen ,  RADIUS, Udo ,  BERTHEL, Johannes ,  HERING, Florian

IPC: C23C16/18 ,  C23C16/455

CPC classification number: C23C16/45553 ,  C07F15/04 ,  C07F15/06 ,  C23C16/18

Abstract: The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. In detail the present invention relates a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state (Fig.) and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R1 and R4 are independent of each other an alkyl group, an aryl group or a trialkylsilyl group, R2, R3, R5 and R6 are independent of each other hydrogen, an alkyl group, an aryl group or a trialkylsilyl group, n is an integer from 1 to 3, M is Ni or Co, X is a ligand which coordinates M, and m is an integer from 0 to 4.

公开(公告)号：EP3083528A1

公开(公告)日：2016-10-26

申请号：EP14815284.6

申请日：2014-12-09

Applicant: BASF SE

Inventor： SCHWARZTRAUBER, Michael ,  SCHELPER, Michael ,  GARCIA ANDARCIA, Hugo Rafael ,  TURKSEVEN, Avni ,  PACIELLO, Rocco ,  SCHAUB, Thomas

IPC: C07C2/46 ,  C07C7/04 ,  C07C13/277

CPC classification number: C07C7/005 ,  B01J31/143 ,  B01J31/2234 ,  B01J31/38 ,  B01J31/4015 ,  B01J2231/20 ,  B01J2531/46 ,  C07C2/42 ,  C07C7/04 ,  C07C7/14858 ,  C07C7/14866 ,  C07C2527/135 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/38 ,  C07C2601/20 ,  Y02P20/584 ,  C07C13/277

Abstract: The invention relates to a method for processing a reaction mixture (R
G ) containing cyclododecatriene and an active catalyst system (K), which contains an aluminum-organic compound. Said method comprises the following steps: a) the reaction mixture (R
G ) is brought into contact with gaseous ammonia to obtain a first mixture (G1); b) the first mixture (G1) is brought into contact with water to obtain a second mixture (G2); c) cyclododecatriene is separated from the second mixture (G2) by distillation.

Abstract translation: 本发明涉及用于处理包含环十二碳三烯的反应混合物（RG）和活性催化剂体系（K），其在铝 - 有机化合物包含的方法。 所述方法包括以下步骤：a）将反应混合物（RG）抵接用气态氨，以得到第一混合物（G1）; b）所述第一混合物（G1）被带入与水接触，以获得第二混合物（G2）; c）中环十二碳三烯是通过蒸馏从第二混合物（G2）分离。

公开(公告)号：EP2858970A1

公开(公告)日：2015-04-15

申请号：EP13727893.3

申请日：2013-06-10

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  HUBER, Sabine ,  PACIELLO, Rocco ,  MEIER, Anton ,  FACHINETTI, Giuseppe ,  PRETI, Debora

IPC: C07C51/00 ,  C07C53/02

CPC classification number: C07C51/00 ,  B01J23/52 ,  B01J23/66 ,  B01J31/0237 ,  B01J35/0013 ,  B01J2231/643 ,  C07C51/44 ,  C07C53/02

Abstract: A process for preparing formic acid by hydrogenation of carbon dioxide in the presence of a tertiary amine (I), a diamine (II), a polar solvent and a catalyst comprising gold at a pressure of from 0.2 to 30 MPa abs and a temperature of from 0 to 200°C, wherein the catalyst is a heterogeneous catalyst comprising gold.

公开(公告)号：EP2855409A1

公开(公告)日：2015-04-08

申请号：EP13724287.1

申请日：2013-05-23

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  DIMITROVA, Pepa ,  PACIELLO, Rocco ,  BAUER, Frederic

IPC: C07C29/34 ,  C07C29/86 ,  C07C31/125

CPC classification number: C07C29/34 ,  C07C29/86 ,  C07C31/125

Abstract: The invention relates to a method for reprocessing a mixture, containing at least one alcohol of general formula (I) R
1 -CH
2 -CH
2 -OH (I) or at least one branched alcohol of general formula (II) R
1 -CH
2 -CHR
1 -CH
2 -OH (II), at least one oil-soluble complex compound of at least one metal of the 8th, 9th, or 10th group of the periodic table of the elements, which is selected from complex compounds that have at least one ligand L
1 that is at least bidentate, at least one coordination site of L
1 being a nitrogen atom, and at least one acid of general formula (III) R
1 -CH
2 -COOH (III) in the form of a salt of said acid, the groups R
1 being selected from C
2 -C
10 alkyl, linear or branched, characterized in that (a) the mixture is treated with water, which can contain an alkali metal hydroxide, (b) which extract/s salts of acid of general formula (III).

公开(公告)号：EP2838872A1

公开(公告)日：2015-02-25

申请号：EP13715241.9

申请日：2013-04-12

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  DIMITROVA, Pepa ,  PACIELLO, Rocco ,  BAUER, Frederic

IPC: C07C29/34 ,  C07C31/125 ,  B01J31/18

CPC classification number: B01J31/1815 ,  B01J31/181 ,  B01J31/2273 ,  B01J2231/52 ,  B01J2531/0241 ,  B01J2531/821 ,  C07C29/34 ,  C07C31/125

Abstract: The invention relates to a method for producing branched alcohols of general formula (I), the groups R
1 being different or the same and being selected from C
2 -C
3 alkyl, linear or branched, using at least one alcohol of formula (II) R
1 -CH
2 -CH
2 -OH in a homogeneous phase in the presence of at least one base, characterized in that at least one complex compound containing Ru(II) is used, in which the Ru(II) has at least one ligand L
1 , which is at least bidentate, at least one coordination site of L
1 being a nitrogen atom.

公开(公告)号：EP2588438A1

公开(公告)日：2013-05-08

申请号：EP11726411.9

申请日：2011-06-16

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  FRIES, Donata Maria ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  RITTINGER, Stefan ,  SCHNEIDER, Daniel

IPC: C07C51/00 ,  C07C53/02

CPC classification number: C07C51/00 ,  C07C53/02

Abstract: A process is proposed for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst containing an element from group 8, 9 or 10 of the Periodic Table, of a tertiary amine containing at least 12 carbon atoms per molecule, and of a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols and butanols, and water, to form formic acid/amine adducts as intermediates, which are subsequently cleaved thermally, with workup of the outputs (3) from the hydrogenation reactor (I) in several process steps, a stream (13) comprising tertiary amine from the workup being used as a selective solvent for the catalyst.

Abstract translation: 提出了一种通过在含有元素周期表第8,9或10族元素的催化剂存在下在氢化反应器（I）中使二氧化碳（1）与氢气（2）反应来制备甲酸的方法， 每分子包含至少12个碳原子的叔胺和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和水的极性溶剂以形成甲酸/胺加合物作为中间体，其随后被热裂解 在几个工艺步骤中处理来自氢化反应器（I）的输出物（3），包含来自处理的叔胺的物流（13）用作催化剂的选择性溶剂。