摘要:
The invention relates to a method for obtaining an alkanoic acid, wherein molecular oxygen, a solid biogenic material and a solution of a catalyst are used in a catalytic reaction, wherein the catalyst is a polyoxometallate ion, a VO2+ containing salt, a [VO3]- containing salt, a vanadium phosphate, a vanadium pentoxide, an ammonium iron sulfate, a copper sulfate or a nickel sulfate, wherein the biogenic material is insoluble in the solution of the catalyst, wherein the method comprises providing the molecular oxygen, the biogenic material and the solution of the catalyst and forming a triphasic composition by bringing into contact the biogenic material, the solution of the catalyst and the molecular oxygen.
摘要:
Provided is a method for recovering a carboxylic acid, by which method the carboxylic acid is separated from an aqueous solution containing water and the carboxylic acid and the separated carboxylic acid is obtained as a carboxylic acid anhydride. The method includes a) a first step of bringing the aqueous solution into liquid-liquid contact with a prepared extractant, the prepared extractant containing a component for extracting the carboxylic acid and a diluent to dissolve the component, b) a second step of distilling the prepared extractant that is subjected to the first step, azeotropically distilling the diluent in the prepared extractant and water, separating the distillate into an extractant component layer mainly containing the diluent and an aqueous layer and then discharging the aqueous layer, returning the extractant component layer mainly containing the diluent to the distillation step as reflux, and discharging the prepared extractant containing the carboxylic acid through a bottom of the column; and c) a third step comprising re-distilling the prepared extractant containing the carboxylic acid discharged by the second step, and returning, to the first step, the prepared extractant from which the carboxylic acid and water are removed, the prepared extractant being discharged through a bottom of the column, where the diluent in the prepared extractant have a minimum boiling azeotrope with water.
摘要:
Die Erfindung betrifft ein Verfahren zur katalytischen Erzeugung eines Alkylformiats, wobei mindestens ein alpha-Hydroxyaldehyd, mindestens eine alpha-Hydroxycarbonsäure, mindestens ein Kohlenhydrat und/oder mindestens ein Glycosid mittels einer Vanadium in der Oxidationsstufe +IV oder +V enthaltenden Vanadium-Sauerstoff-Verbindung oder eines Salzes davon als Katalysator in einer Lösung umgesetzt wird, wobei die Lösung ein Alkanol enthält, wobei das dabei als Reaktionsprodukt entstehende Alkylformiat von mindestens einem dabei entstehenden weiteren Reaktionsprodukt separiert wird, wobei der bei der katalytischen Reaktion reduzierte Katalysator durch Oxidation wieder in seinen Ausgangszustand versetzt wird.
摘要:
A co-salt of a polyunsaturated fatty acid and a non-fatty acid is formed as a precipitate. The co-salt formed is free flowing and does not tend to agglomerate (cake) in storage. The resultant co-salt product will be easy to blend with other products to produce dietary supplements. These novel co-salt products may also tablet very well and may be added to current dietary supplement tablets.
摘要:
A compound synthetic pathway is generated without limiting chemical conversion rules. A synthetic pathway generating apparatus includes: a converting unit to convert chemical structures of compounds into numerical values; a calculation unit to create a compound pair and to calculate a difference value by subtracting the numerical value of one compound of the compound pair from the numerical value of the other compound thereof; a determining unit to compare the difference value of the compound pair of the reaction between which is already known with the difference value of the compound pair of the reaction between which is unknown, and to determine unknown reactions of the compound pairs with the difference values being coincident as virtual reactions; a generating unit to generate compound synthetic pathways by use of nodes representing the compounds and edges representing the known reaction and the virtual reaction respectively; and a selecting unit to select a synthetic pathway from a starting compound to a target compound out of the generated compound synthetic pathways.
摘要:
The invention relates to a process to separate formic acid from methyltetrahydrofuran (MTHF) said process comprising subjecting a composition comprising formic acid and MTHF to distillation, characterized in that the process comprises adding water to said distillation. This allows for cost-efficient recovery and recycling of MTHF, for example in process to produce and recover formic acid from a biomass hydrolysate.
摘要:
The method of the utilization of carbon dioxide gas for the production of energy valuable products like formic acid, methanol and formaldehyde by the way of the low temperature conversion of carbon dioxide aqueous solutions under supercritical pressure over the heterogeneous catalyst in a form of composite membrane on the basis of the copper, zinc, and aluminium oxides supported on a carrier and activated by lead, zirconium, titanium and niobium oxides.
摘要:
The invention provides a process for the production of a biomass hydrolysate suitable for the production of levulinic acid and formic acid, a biomass hydrolysate obtainable by said process, a process for the production of levulinic acid and formic acid from said biomass, and levulinic acid and formic acid obtainable by said process. The hydrolysis process includes a single hydrolysis step wherein a slurried biomass is subjected to a temperature of between 120 and 200° C., preferably between 160 and 190° C., for a time period of between 2 and 8 hours, preferably between 20 and 140 minutes at a mineral acid concentration of between 1-15 wt %. The process can be carried out starting from lignocellulosic biomass, and also from glucose and fructose.