METHOD FOR OBTAINING AN ALKANOIC ACID
    1.
    发明公开

    公开(公告)号:EP4431487A1

    公开(公告)日:2024-09-18

    申请号:EP23162609.4

    申请日:2023-03-17

    申请人: OxFA GmbH

    IPC分类号: C07C51/00 C07C53/02 C07C53/08

    CPC分类号: C07C51/00

    摘要: The invention relates to a method for obtaining an alkanoic acid, wherein molecular oxygen, a solid biogenic material and a solution of a catalyst are used in a catalytic reaction, wherein the catalyst is a polyoxometallate ion, a VO2+ containing salt, a [VO3]- containing salt, a vanadium phosphate, a vanadium pentoxide, an ammonium iron sulfate, a copper sulfate or a nickel sulfate, wherein the biogenic material is insoluble in the solution of the catalyst, wherein the method comprises providing the molecular oxygen, the biogenic material and the solution of the catalyst and forming a triphasic composition by bringing into contact the biogenic material, the solution of the catalyst and the molecular oxygen.

    METHOD FOR COLLECTING CARBOXYLIC ACID
    2.
    发明公开

    公开(公告)号:EP4339183A1

    公开(公告)日:2024-03-20

    申请号:EP22807545.3

    申请日:2022-05-12

    IPC分类号: C07C51/44 C07C51/48 C07C53/02

    摘要: Provided is a method for recovering a carboxylic acid, by which method the carboxylic acid is separated from an aqueous solution containing water and the carboxylic acid and the separated carboxylic acid is obtained as a carboxylic acid anhydride. The method includes a) a first step of bringing the aqueous solution into liquid-liquid contact with a prepared extractant, the prepared extractant containing a component for extracting the carboxylic acid and a diluent to dissolve the component, b) a second step of distilling the prepared extractant that is subjected to the first step, azeotropically distilling the diluent in the prepared extractant and water, separating the distillate into an extractant component layer mainly containing the diluent and an aqueous layer and then discharging the aqueous layer, returning the extractant component layer mainly containing the diluent to the distillation step as reflux, and discharging the prepared extractant containing the carboxylic acid through a bottom of the column; and c) a third step comprising re-distilling the prepared extractant containing the carboxylic acid discharged by the second step, and returning, to the first step, the prepared extractant from which the carboxylic acid and water are removed, the prepared extractant being discharged through a bottom of the column, where the diluent in the prepared extractant have a minimum boiling azeotrope with water.

    VERFAHREN ZUR KATALYTISCHEN ERZEUGUNG EINES ALKYLFORMIATS

    公开(公告)号:EP3854778A1

    公开(公告)日:2021-07-28

    申请号:EP20153906.1

    申请日:2020-01-27

    摘要: Die Erfindung betrifft ein Verfahren zur katalytischen Erzeugung eines Alkylformiats, wobei mindestens ein alpha-Hydroxyaldehyd, mindestens eine alpha-Hydroxycarbonsäure, mindestens ein Kohlenhydrat und/oder mindestens ein Glycosid mittels einer Vanadium in der Oxidationsstufe +IV oder +V enthaltenden Vanadium-Sauerstoff-Verbindung oder eines Salzes davon als Katalysator in einer Lösung umgesetzt wird, wobei die Lösung ein Alkanol enthält, wobei das dabei als Reaktionsprodukt entstehende Alkylformiat von mindestens einem dabei entstehenden weiteren Reaktionsprodukt separiert wird, wobei der bei der katalytischen Reaktion reduzierte Katalysator durch Oxidation wieder in seinen Ausgangszustand versetzt wird.

    PROCESS FOR THE PRODUCTION OF A BIOMASS HYDROLYSATE
    10.
    发明公开
    PROCESS FOR THE PRODUCTION OF A BIOMASS HYDROLYSATE 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINES BIOMASSEHYDROLYSATS

    公开(公告)号:EP2928856A1

    公开(公告)日:2015-10-14

    申请号:EP13802053.2

    申请日:2013-12-09

    摘要: The invention provides a process for the production of a biomass hydrolysate suitable for the production of levulinic acid and formic acid, a biomass hydrolysate obtainable by said process, a process for the production of levulinic acid and formic acid from said biomass, and levulinic acid and formic acid obtainable by said process. The hydrolysis process includes a single hydrolysis step wherein a slurried biomass is subjected to a temperature of between 120 and 200° C., preferably between 160 and 190° C., for a time period of between 2 and 8 hours, preferably between 20 and 140 minutes at a mineral acid concentration of between 1-15 wt %. The process can be carried out starting from lignocellulosic biomass, and also from glucose and fructose.

    摘要翻译: 本发明提供一种生产适用于生产乙酰丙酸和甲酸的生物质水解产物的方法,可通过所述方法获得的生物质水解产物,从所述生物质生产乙酰丙酸和甲酸的方法,以及乙酰丙酸和 通过所述方法可得到的甲酸。 水解过程包括单一水解步骤,其中将浆化生物质经受120至200℃之间,优选在160至190℃之间的温度,时间为2至8小时,优选20至 无机酸浓度为1-15%(重量)之间为140分钟。 该方法可以从木质纤维素生物质以及葡萄糖和果糖开始进行。