Method for producing ethylenically unsaturated graftable orthoesters
    27.
    发明公开
    Method for producing ethylenically unsaturated graftable orthoesters 失效
    法尔赫·赫尔斯特朗

    公开(公告)号:EP0576147A1

    公开(公告)日:1993-12-29

    申请号:EP93304021.4

    申请日:1993-05-25

    IPC分类号: C07D317/34

    CPC分类号: C07D317/34

    摘要: Ethylenically unsaturated graftable monomers are prepared by reacting hydroxy substituted orthoesters with electrophilic reagents, an alkaline reagent, and a phase transfer catalyst. Preferably the hydroxy orthoester is 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane, and the preferred reagent is acryloyl chloride with sodium hydroxide as the base and methyltrialkylammonium (C₈₋₁₀) chloride as the phase transfer catalyst.

    摘要翻译: 乙烯基不饱和可接枝单体是通过使羟基取代的原酸酯与亲电子试剂,碱性试剂和相转移催化剂反应来制备的。 优选地,羟基原酸酯是4-羟甲基-2-甲氧基-2-甲基-1,3-二氧戊环,优选的试剂是以氢氧化钠为碱的丙烯酰氯和作为相转移催化剂的甲基三烷基铵(C8-10)氯化物。

    Polymers of ethylenically unsaturated cyclic ortho esters
    30.
    发明公开
    Polymers of ethylenically unsaturated cyclic ortho esters 失效
    Polymere vonäthylenischungesättigtecyclische Orthoestern。

    公开(公告)号:EP0496116A1

    公开(公告)日:1992-07-29

    申请号:EP91122273.5

    申请日:1991-12-27

    IPC分类号: C08F20/28 C08F255/06

    CPC分类号: C08F20/26 C08F255/06

    摘要: Ethylenically unsaturated cyclic ortho esters are prepared by the reaction of a hydroxy-substituted cyclic ortho ester such as 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane with acryloyl chloride, methacryolyl chloride, vinylbenzyl chloride or the like. They form polymers, especially random copolymers with styrene and EPDM graft copolymers; the latter are useful in the formation of copolymer-containing compositions with polyesters, polyamides and the like. The copolymer-containing compositions have excellent physical properties and may be employed to compatibilize blends of the same polymers.

    摘要翻译: 乙烯基不饱和环状原酸酯通过羟基取代的环状原酸酯如4-羟甲基-2-甲氧基-2-甲基-1,3-二氧戊环与丙烯酰氯,甲基丙烯酰氯,乙烯基苄基氯等反应制备。 它们形成聚合物,特别是与苯乙烯和EPDM接枝共聚物的无规共聚物; 后者可用于用聚酯,聚酰胺等形成含共聚物的组合物。 含共聚物的组合物具有优异的物理性能,并且可用于使相同聚合物的共混物相容化。