Methacrylic acid ester resin composition and film made thereof
    24.
    发明公开
    Methacrylic acid ester resin composition and film made thereof 有权
    Methacrylsäureesterharz-Zusammensetzung und daraus hergestellte Folie

    公开(公告)号:EP0897954A1

    公开(公告)日:1999-02-24

    申请号:EP98115503.9

    申请日:1998-08-18

    IPC分类号: C08L33/10 C08J5/18

    摘要: A methacrylate resin composition having an excellent processability and capable of providing films having excellent impact resistance, transparency, weatherability, solvent resistance and plasticizer migration resistance, which comprises (A) 5 to 50% by weight of a crosslinked acrylate elastomer having a two layer structure of a crosslinked polymer component (a-1) having a glass transition temperature of -30 to 10°C and a crosslinked polymer component (a-2) having a glass transition temperature of less than -30°C wherein the component (a-1) is located on the inner side or the outer side and the component (a-2) is located on the outer side or the inner side, and (B) 95 to 50 % by weight of an alkyl methacrylate polymer prepared by polymerizing an acrylic monomer containing 80 to 100 % by weight of an alkyl methacrylate and 20 to 0 % by weight of an alkyl acrylate in the presence of a chain transfer agent and in the presence or absence of the elastomer (A). The composition may further contain a core-shell polymer prepared by graft-polymerizing a monomer containing a major amount of an alkyl methacrylate onto a crosslinked acrylate polymer, whereby molded articles having a matt surface and an excellent flex whitening resistance are obtained.

    摘要翻译: 具有优异的加工性的能够提供耐冲击性,透明性,耐候性,耐溶剂性和增塑剂耐迁移性优异的薄膜的甲基丙烯酸酯树脂组合物,其包含(A)5〜50重量%的具有两层结构的交联丙烯酸酯弹性体 的玻璃化转变温度为-30〜10℃的交联聚合物组分(a-1)和玻璃化转变温度低于-30℃的交联聚合物组分(a-2),其中组分(a- 1)位于内侧或外侧,成分(a-2)位于外侧或内侧,(B)95〜50重量%的通过聚合制备的甲基丙烯酸烷基酯聚合物 在链转移剂的存在下和在弹性体(A)的存在或不存在下,含有80〜100重量%的甲基丙烯酸烷基酯和20〜0重量%的丙烯酸烷基酯的丙烯酸类单体。 该组合物可以进一步含有通过将含有大量甲基丙烯酸烷基酯的单体接枝聚合到丙交酯交联聚合物上制备的核 - 壳聚合物,从而获得具有无光泽表面和优异耐弯曲增白性的模塑制品。

    ETHYLENE ACRYLIC RUBBER COMPOSITION, ETHYLENE ACRYLIC RUBBER, RUBBER-METAL COMPOSITE, AND BONDED PISTON SEAL

    公开(公告)号:EP3150664A4

    公开(公告)日:2017-12-06

    申请号:EP15789404

    申请日:2015-04-30

    申请人: NOK CORP

    发明人: FURUKAWA TOMONORI

    摘要: An object of the present invention is to provide an ethylene-acrylic rubber composition that is excellent in the compression set and also in the crosslinking bonding even when no secondary crosslinking is caused therein, an ethylene-acrylic rubber produced by causing primary crosslinking in the composition, a rubber metal composite formed by bonding the ethylene-acrylic rubber and a metal with each other, and a bonded piston sealing including the rubber metal composite. The object is achieved by an ethylene-acrylic rubber composition including 1 to 7 phr by weight of calcium hydroxide relative to 100 phr by weight of a binary ethylene-acrylic rubber polymer that includes ethylene and an acrylic acid ester, an ethylene-acrylic rubber produced by causing peroxide-crosslinking by primary crosslinking in the ethylene-acrylic rubber composition, a rubber metal composite formed by crosslinking-bonding the ethylene-acrylic rubber and a metal with each other bonded with the primary crosslinking, and a bonded piston sealing including the rubber metal composite.

    PROCESS FOR PRODUCING PIGMENT-CONTAINING MODIFIED POLYMER PARTICLES
    30.
    发明公开
    PROCESS FOR PRODUCING PIGMENT-CONTAINING MODIFIED POLYMER PARTICLES 审中-公开
    生产含颜料改性聚合物颗粒的方法

    公开(公告)号:EP3239212A1

    公开(公告)日:2017-11-01

    申请号:EP15873073.9

    申请日:2015-12-22

    申请人: Kao Corporation

    摘要: The present invention relates to [1] a process for producing pigment-containing modified polymer particles, including the step of reacting pigment-containing polymer particles (A) containing a functional group and a compound (B) containing a reactive group capable of reacting with the functional group of the polymer particles (A) in a medium under such a condition that a ratio [(B)/(A)] of total moles of the reactive group of the compound (B) to total moles of the functional group of the polymer particles (A) is from 0.10 to 0.62; [2] a pigment water dispersion including an aqueous medium and the modified polymer particles produced by the aforementioned process which are dispersed in the aqueous medium; and [3] an ink including the aforementioned pigment water dispersion and an organic solvent. The modified polymer particles are free from formation of coarse particles upon production of pigment particles, so that an ink obtained by using the modified polymer particles can be prevented from suffering from increase in viscosity thereof when the ink is being concentrated by evaporation of water from the ink, and is excellent in rub fastness when printed on a low-water absorbing recording medium.

    摘要翻译: 本发明涉及[1]一种含颜料改性聚合物粒子的制造方法,该方法包括使含有官能团的含颜料聚合物粒子(A)与含有能够与含有能够反应的反应性基团的化合物(B) (A)的官能团在化合物(B)的反应性基团的总摩尔数与(B)的官能团的总摩尔数之比[(B)/ 聚合物粒子(A)为0.10〜0.62, [2]颜料水分散体,其包含水性介质和通过上述方法制备的改性聚合物颗粒,所述改性聚合物颗粒分散在水性介质中; [3]包含上述颜料水分散体和有机溶剂的油墨。 改性聚合物颗粒在制备颜料颗粒时不会形成粗颗粒,从而可以防止通过使用改性聚合物颗粒获得的油墨在通过蒸发来自 油墨,并且当印刷在低吸水性记录介质上时耐摩擦性优异。