摘要:
The present invention provides a system and method for purifying vanadium pentoxide. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to plasma oxidation, thereby obtaining a high-purity vanadium pentoxide product and chlorine gas. The chlorine gas is returned for low temperature chlorination. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
摘要:
The chlorides of elements of Groups III, IV and V of the Periodic Table, such as, boron trichloride, silicon tetrachloride, zirconium tetrachloride and vanadium tetrachloride are prepared by heating activated carbon particles having a supported aqueous solution of compounds of the elements of Groups III, IV and V of the Periodic Table thereon at a temperature of from 300 through 1000°C and, then, reacting the resultant activated carbon particles with chlorine.
摘要:
A fluidized bed reactor system comprises a vessel (10) adapted to contain a fluidized bed, a plurality of fluid injector means (24) mounted through the vessel wall (20) for injecting and distributing a fluidizing medium into the lower portion of the vessel, each injector means being made up of an elongated injector having a nozzle end (26) projecting into the vessel. The injector is withdrawably mounted through the vessel wall and has at least one downwardly directed orifice (28). Shield means (32) are provided which are mounted on the vessel wall above the injector extending along the length of the injector for maintaining an opening in the bed when the injector is withdrawn. The opening is substantially equivalent to the length of the injector. The reactor system further includes fluid supply means (48) in fluid communication with each elongated injector (24) for supplying the fluidizing medium to each nozzle end (26). When it is required to replace the injector due, for example, to clogging of the orifices or deterioration, the injector is withdrawn from the vessel, replaced or repaired and then inserted into the vessel, The shield means allows for the easy insertion of the injector into the vessel by maintaining an opening in the bed, whether fluidized or non-fluidized. The fluidized bed reactor system allows for the replacement or repair of injectors without the necessity for shutting down and/or cleaning out the vessel.
摘要:
The present invention provides a system and method for purifying and preparing vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase ammonification, thereby obtaining ammonium metavanadate, and further obtaining a high-purity vanadium pentoxide powder product through fluidized calcination. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
摘要:
The present invention provides a system and method for producing high-purity vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation and fluidized calcination, thereby producing a high-purity vanadium pentoxide product and a by-product of hydrochloric acid solution. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption in production and low operation cost, stable product quality and so on, and are suitable for large-scale industrial production of high-purity vanadium pentoxide powder with a purity of above 4N.
摘要:
The present invention provides a system and method for preparing high-purity vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is subjected to purification by rectification, ammonium salt precipitation and fluidized calcination, thereby obtaining high-purity vanadium pentoxide, wherein the ammonia gas produced during calcination is condensed and then recycled for ammonium salt precipitation. The system and method have advantages of favorable adaptability to a raw material, less pollution, low energy consumption in production and low operation cost, stable product quality and so on, and are suitable for large-scale production of high-purity vanadium pentoxide powder with a purity of above 4N.
摘要:
A refractory which is prepared by forming a refractory material composition comprising a refractory material comprising graphite particles having an average particle diameter of 500 nm or less or a refractory material comprising graphite particles obtained by graphitizing carbon black and a refractory aggregate; or a refractory which is prepared by forming a refractory material composition comprising a carbonaceous particles (A) having a DBP absorption (x) of 80 ml/100 g or more selected from carbon black and graphite particles obtained by graphitizing carbon black, a carbonaceous particles (B) having a DBP absorption (x) of less than 80 ml/100 g selected from carbon black and graphite particles obtained by graphitizing carbon black, and a refractory aggregate. The refractory provides a carbon-containing refractory, in particular, the one having a reduced content of carbon, which is excellent in the resistance to corrosion, oxidation and thermal shock.
摘要:
A refractory which is prepared by forming a refractory material composition comprising a refractory material comprising graphite particles having an average particle diameter of 500 nm or less or a refractory material comprising graphite particles obtained by graphitizing carbon black and a refractory aggregate; or a refractory which is prepared by forming a refractory material composition comprising a carbonaceous particles (A) having a DBP absorption (x) of 80 ml/100 g or more selected from carbon black and graphite particles obtained by graphitizing carbon black, a carbonaceous particles (B) having a DBP absorption (x) of less than 80 ml/100 g selected from carbon black and graphite particles obtained by graphitizing carbon black, and a refractory aggregate. The refractory provides a carbon-containing refractory, in particular, the one having a reduced content of carbon, which is excellent in the resistance to corrosion, oxidation and thermal shock.