摘要:
The present invention relates to the pyrolysis of hydrochlorofluorocarbons to form fluoromonomers such as tetrafluoroethylene, the pyrolysis being carried out in a reaction zone lined with nickel and mechanically supported by a jacket of other corrosion resistant metal, the nickel lining providing an improved yield of valuable reaction products.
摘要:
Methods and materials are disclosed for the conversion hydrofluorocarbons. More specifically methods and materials are provided for converting hydrofluorocarbons such as HFC-227, HFC-236, HFC-245, HFC-125, HFC-134, HFC-143, HFC-152, HFC-32, HFC-23 and their respective isomers. Methods are provided for converting hydrofluorocarbons such as these to fluoromonomer precursors such as CFC-217, CFC-216, CFC-215, CFC-115, CFC-114, CFC-113, CFC-112, CFC-22, HCFC-22, CFC-12, CFC-13 and their respective isomers. Materials and methods are provided for the conversion of these fluoromonomer precursors to fluoromonomers such as HFP, PFP, TFP, TFE, and VDF.
摘要:
A process for purifying octafluorocyclobutane according to the present invention is characterized by contacting a crude octafluorocyclobutane containing impurities with an impurity decomposing agent under elevated temperature and then with an adsorbent to substantially remove the impurities from the crude octafluorocyclobutane. According to the purification process or preparation process of octafluorocyclobutane of the present invention, the impurities such as fluorocarbon can be substantially removed and a high-purity octafluorocyclobutane can be easily obtained. The octafluorocyclobutane obtained by the purification process of the present invention is substantially free of impurities and therefore, can be used as an etching or cleaning gas for use in the production process of a semiconductor device or the like.
摘要:
There is provided a process for recovering tetrafluoroethylene wherein an amount of energy required to obtain TFE is reduced. In the process for producing a TFE mixture as an intended mixture which contains TFE at a higher concentration from a raw material mixture (10) which contains TFE, a component of which boiling point is lower than that of TFE and a component of which boiling point is higher than that of TFE,
(1) the raw material is subjected to a preliminary distillation treatment (12) so as to obtain (a) a first fraction (15) which contains at least a portion of the component of which boiling point is higher than that of TFE and (b) a second fraction (14) as the balance which contains TFE and the component of which boiling point is lower than that of TFE, and then (2) the second fraction is subjected to a main distillation treatment (16) so as to obtain (c) a third faction (20) formed by distilling off the component of which boiling point is lower than that of TFE, and (d) a fourth fraction (18) as the intended mixture being the balance which contains TFE.
摘要:
Processes are disclosed for decreasing the chlorine to carbon ratio for halogenated hydrocarbons containing chlorine and from 1 to 6 carbon atoms, in the presence of a multiphase catalyst. The processes each involve (1) preparing a single phase solid catalyst precursor which has a structure that collapses at a temperature of about 400 °C or less and has the formula (NH3)6Ru1-r-sCorCrsMF6, where r+s is in the range of 0.00 to 0.99, and M is at least one trivalent metal selected from the group consisting of Al, Cr, Fe, V, Sc and Ga; and (2) producing the multiphase catalyst by heating the single phase solid catalyst precursor to about 400 °C or less in a non-oxidizing atmosphere to produce a multiphase composition wherein a phase containing ruthenium is homogeneously dispersed with a phase containing metal fluoride. Also disclosed are single phase fluoride compositions having the formula (NH3)6Ru1-r-sCorCrsMF6, where r+s is in the range of 0.00 to 0.99, and M is at least one trivalent element selected from the group consisting of Al, Cr, Fe, V, Sc and Ga; and multiphase catalyst compositions consisting essentially of metallic ruthenium and fluorides of at least one element selected from the group consisting of Al, Co, Cr, Fe, V, Sc and Ga, wherein the ruthenium is homogeneously dispersed with phases of the fluorides.
摘要:
Pour fabriquer du pentafluoroéthane (F125) et/ou du 1,1,1,2,3,3,3-heptafluoropropane (F227ea), on soumet un courant gazeux de trifluorométhane à une pyrolyse, puis on met le mélange de gaz issus de cette pyrolyse en contact avec un catalyseur de fluoration.
摘要:
A preparation of perfluoroolefins from fluoroform is described in which the fluoroform is pyrolyzed in a flame submerged in water in which the water acts as the walls of a reaction vessel.
摘要:
The present disclosure provides a method for producing a reaction gas containing 1,1,2-trifluoroethane (R-143) and/or (E,Z)-1,2-difluoroethylene (R-1132(E,Z)) using a starting material that is easier to obtain than those used in conventional methods. Specifically, the present disclosure provides a method for producing a reaction gas containing 1,1,2-trifluoroethane (R-143) and/or (E,Z)-1,2-difluoroethylene (R-1132(E,Z)), the method comprising subjecting a starting material gas containing difluoromethane (R-32) to a reaction that involves thermal decomposition at a pressure of 0.6 MPaG or more and 2.0 MPaG or less and a temperature of 600°C or more and 1000°C or less, thereby obtaining the reaction gas.