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    Process and catalyst for the dehydrohalogenation of halogenated hydrocarbons or alkylene halohydrins
    332.
    发明公开
    Process and catalyst for the dehydrohalogenation of halogenated hydrocarbons or alkylene halohydrins 失效
    一种用于卤化烃或Alkylenhalogenhydrinen的脱卤化氢方法和催化剂。

    公开(公告)号：EP0389650A1

    公开(公告)日：1990-10-03

    申请号：EP89105385.2

    申请日：1989-03-25

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： Harley, Dale, A.

    IPC: B01J27/138 ,  C07B35/06 ,  C07D301/26

    CPC classification number: B01J27/138 ,  B01J21/08 ,  B01J37/0201 ,  C07C17/25 ,  C07C21/08

    Abstract: This invention relates to an unsaturated halohydrocarbon such as vinylidene chloride produced by the dehydrohalogenation of haloalkanes such as 1,1,1-trichloroethane or 1,1,2-trichloroethane, by contacting the haloalkane with a Group IA metal halide and a Group IIA or IIB metal oxide or metal hydroxide, together supported on a porous carrier material, under reaction conditions sufficient to form the corresponding unsaturated hydrocarbon and a Group IIA or IIB metal halide. The Group IIA or IIB metal oxide or metal hydroxide may be regenerated by contacting the Group IIA or IIB metal halide with an alkanol or water. In one embodiment, the process is initiated by contacting a novel catalyst comprising a Group IA metal cation such as Cs, a Group IIA or IIB metal cation such as Mg and a neutralizing number of halide anions such as chloride distributed on a support such as silica, with water or an alkanol under reaction conditions sufficient to form the Group IA metal halide and the Group IIA or IIB metal oxide or metal hydroxide supported on a porous carrier material. The process of the invention is also useful for the dehydrohalogenation of alkylene halohydrins to produce alkylene oxides. The process of the invention may be carried out in a riser reactor system, whereby the reactants are cycled in a continuous process. The novel catalyst is highly selective, has high catalytic capacity and does not rapidly deactivate in typical dehydrohalogenation reactions when used in the presence of an alkanol and oxygen.

    Abstract translation: 本发明涉及不饱和在卤代烃：如由卤代烷烃的脱卤化氢产生的偏二氯乙烯：诸如1,1,1-三氯乙烷或1,1,2-三氯乙烷，通过与IA族金属卤化物和一种ⅡA族或接触卤代烷烃 ⅡB族金属氧化物或金属氢氧化物，一起负载在多孔载体材料，在足以形成相应的不饱和烃和IIA族或IIB族金属卤化物的反应条件下。 第IIA族或IIB族金属氧化物或金属氢氧化物可以通过在链烷醇或水与接触的IIA族或IIB族金属卤化物再生。 在一个，实施例的处理是通过接触的新型催化剂包含IA族金属阳离子引发：例如Cs，IIA族或IIB族金属阳离子：例如Mg和卤素阴离子的中和号码：如氯化分布在载体上：例如二氧化硅 与水或足以形成IA族金属卤化物和负载在多孔载体材料中的IIA族或IIB族金属氧化物或金属氢氧化物的反应条件下，以链烷醇。 在本发明的方法是有用的，因此用于卤代醇的脱卤化氢以产生亚烷基，烯化氧。 本发明的方法可以在提升管反应器系统，由此反应物是在连续过程中循环来进行。 新型催化剂是高度选择性的，具有高的催化能力和不典型的脱卤化氢反应迅速失活当在链烷醇和氧气的存在下使用。

    Biocidal thickening additive for an organic composition
    335.
    发明公开
    Biocidal thickening additive for an organic composition 失效
    Biozider Verdickungszusatzfüreine organische Zusammensetzung。

    公开(公告)号：EP0265101A2

    公开(公告)日：1988-04-27

    申请号：EP87308744.9

    申请日：1987-10-02

    Applicant: RHEOX INTERNATIONAL, INC.

    Inventor： Guilbeaux, Ronald

    IPC: A01N33/12 ,  A01N25/08 ,  A61K7/48 ,  C01B33/21

    CPC classification number: A61K8/416 ,  A01N25/08 ,  A01N33/12 ,  A61K8/26 ,  A61Q17/005 ,  B01J37/0201 ,  C01B33/44

    Abstract: A thickened organic composition containing a first organophilic clay which will increase the viscosity of the composition and a second organophilic clay which is different from the first and which will impart biocidal activity to the composition. The second organophilic clay is the reaction product of a smectite-type clay and an organic cation having a benzyl group and a long chain alkyl group. The first and second organophilic clays can be mixed into the organic composition as and additive and may be prepared by using a mixture of cations.

    Abstract translation: 一种杀生物亲油性粘土，其特征在于i）一种具有至少约75毫当量的阳离子交换容量/ 100克粘土，100％活性基的阳离子交换容量和ii）具有下式的有机阳离子的反应产物： CHEM>其中R1是苄基或生物活性苄基衍生物; R2是具有8-22个碳原子的直链或支链，饱和或不饱和的烷基; 并且R 3和R 4选自（a）具有1至22个碳原子的直链或支链烷基; （b）苄基和取代的苄基部分的芳烷基，包括在结构的烷基部分中具有直链或支链的1至22个碳原子的稠环部分; （c）芳基如苯基和取代的苯基，包括稠环芳香族取代基; （d）具有6个或更少碳原子的β，γ，不饱和基团; 和（e）氢。 杀生物有机亲土性粘土可以与适于增加有机液体的粘度的不同的亲有机粘土混合使用，特别是在化妆品制剂中。

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