公开(公告)号：EP3303268A4

公开(公告)日：2018-04-11

申请号：EP16807969

申请日：2016-05-02

申请人： SABIC GLOBAL TECHNOLOGIES BV

发明人： LIANG WUGENG ,  SARSANI SAGAR ,  WEST DAVID ,  LOWREY JAMES ,  MAMEDOV AGHADDIN ,  LENGYEL ISTVAN

IPC分类号： C07C2/84 ,  B01J23/10 ,  B01J23/30 ,  B01J23/34 ,  B01J32/00 ,  C07C7/20 ,  C07C9/04 ,  C07C9/06 ,  C07C11/04 ,  C10L3/12

CPC分类号： B01J23/10 ,  B01J21/08 ,  B01J23/34 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0236 ,  C07C2/84 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： Disclosed is a process for producing C2+ hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700 °C, contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C2+ hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C2+ hydrocarbons in the second product stream is greater than the amount of C2+ hydrocarbons in the first product stream.

公开(公告)号：EP3303268A1

公开(公告)日：2018-04-11

申请号：EP16807969.7

申请日：2016-05-02

申请人： SABIC Global Technologies B.V.

发明人： LIANG, Wugeng ,  SARSANI, Sagar ,  WEST, David ,  LOWREY, James ,  MAMEDOV, Aghaddin ,  LENGYEL, Istvan

IPC分类号： C07C2/84 ,  C07C7/20 ,  C07C9/04 ,  C07C9/06 ,  C07C11/04 ,  C10L3/12 ,  B01J23/34 ,  B01J23/30 ,  B01J23/10 ,  B01J32/00

CPC分类号： C07C2/84 ,  B01J19/245 ,  B01J21/08 ,  B01J23/10 ,  B01J23/34 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0236 ,  B01J2219/00074 ,  B01J2219/24 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： Disclosed is a process for producing C2+ hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700° C. contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C2+ hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C2+ hydrocarbons in the second product stream is greater than the amount of C2+ hydrocarbons in the first product stream.

公开(公告)号：EP3259242A1

公开(公告)日：2017-12-27

申请号：EP16753181.3

申请日：2016-02-19

申请人： Northwestern University

发明人： MARKS, Tobin J. ,  PETER, Matthias

IPC分类号： C07C7/20 ,  C07C9/04 ,  C07C11/04 ,  B01J23/34 ,  B01J21/06 ,  B01J23/04 ,  B01J23/06 ,  B01J23/30 ,  B01J23/26 ,  B01J23/745

CPC分类号： C07C2/84 ,  B01J21/06 ,  B01J21/10 ,  B01J23/06 ,  B01J23/10 ,  B01J23/24 ,  B01J23/745 ,  B01J27/04 ,  B01J27/043 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/20 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/06 ,  C07C2523/10 ,  C07C2523/26 ,  C07C2523/30 ,  C07C2523/745 ,  C07C2527/04 ,  C07C2527/043 ,  C07C2527/047 ,  C07C2527/051 ,  Y02P20/52 ,  C07C11/04 ,  C07C9/06

摘要： Methods for oxidative coupling of methane using metal oxide catalysts and a sulfur oxidant.

公开(公告)号：EP3230239A1

公开(公告)日：2017-10-18

申请号：EP15868404.3

申请日：2015-12-09

申请人： SABIC Global Technologies B.V.

发明人： MAMEDOV, Aghaddin ,  WEST, David ,  BALAKOTAIAH, Vemuri ,  SARSANI, Sagar ,  LIANG, Wugeng

IPC分类号： C07C2/82 ,  C07C1/12 ,  C07C7/20 ,  C07C11/04 ,  B01J23/02 ,  B01J27/138

CPC分类号： C07C2/84 ,  B01J23/002 ,  B01J23/34 ,  B01J2523/00 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/128 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/3706 ,  B01J2523/41 ,  B01J2523/69 ,  B01J2523/72 ,  C07C11/04

摘要： Disclosed is a method for production of synthesis gas and ethylene by a combined oxidative coupling and dry reforming of methane process. Heat generated from the oxidative coupling of methane can be used to drive the endothermic dry reforming of methane reaction.

摘要翻译： 本发明公开了一种通过甲烷法的联合氧化偶合和干重整制备合成气和乙烯的方法。 甲烷氧化偶联产生的热量可用于驱动甲烷反应的吸热干重整。

公开(公告)号：EP3102554A4

公开(公告)日：2017-10-04

申请号：EP15742636

申请日：2015-01-28

申请人： BATTELLE MEMORIAL INSTITUTE

发明人： LILGA MICHAEL A ,  FRYE JR JOHN G ,  LEE SUH-JANE ,  ALBRECHT KARL O

IPC分类号： C07C1/24 ,  B01J21/06 ,  B01J21/08 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J27/18 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07C1/207 ,  C07C1/30 ,  C07C29/60 ,  C07C49/203

CPC分类号： C07C1/24 ,  B01J19/00 ,  B01J21/066 ,  B01J21/08 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J27/1806 ,  B01J37/031 ,  B01J37/04 ,  B01J37/086 ,  B01J37/088 ,  B01J2523/00 ,  B01J2523/33 ,  B01J2523/35 ,  B01J2523/3781 ,  B01J2523/48 ,  C07C1/2078 ,  C07C1/30 ,  C07C29/60 ,  C07C49/203 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2527/167 ,  C07C2529/40 ,  C07C2529/70 ,  C07C33/03 ,  C07C11/167 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/23 ,  B01J2523/3762 ,  B01J2523/3775 ,  B01J2523/3793 ,  B01J2523/27 ,  B01J2523/3743 ,  B01J2523/36 ,  B01J2523/25 ,  B01J2523/51 ,  B01J2523/11 ,  B01J2523/305 ,  B01J2523/22 ,  B01J2523/375 ,  B01J2523/3768 ,  B01J2523/3725 ,  B01J2523/3718 ,  B01J2523/3737 ,  B01J2523/3756 ,  B01J2523/3787 ,  B01J2523/3712 ,  B01J2523/68 ,  B01J2523/49 ,  B01J2523/69 ,  B01J2523/41

公开(公告)号：EP3148688A1

公开(公告)日：2017-04-05

申请号：EP15732808.9

申请日：2015-05-27

申请人： L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude ,  Centre National de la Recherche Scientifique (C.N.R.S.) ,  Ecole Superieure De Chimie Physique Electronique De Lyon

发明人： BASIN, Marie ,  BERTAIL, Caroline ,  DEL-GALLO, Pascal ,  GARY, Daniel ,  FEZOUA, Amara ,  LYGEROS, Nik ,  NIKITINE, Clémence ,  PITAULT, Isabelle ,  BORNETTE, Frédéric

IPC分类号： B01J19/30 ,  B01J35/02 ,  B01J35/10 ,  C01B3/40 ,  C07C1/04 ,  C10G2/00 ,  C10G35/06

CPC分类号： B01J35/026 ,  B01J8/0214 ,  B01J19/30 ,  B01J23/28 ,  B01J23/56 ,  B01J23/74 ,  B01J35/023 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1028 ,  B01J2208/00539 ,  B01J2219/30265 ,  B01J2219/30416 ,  B01J2219/30475 ,  B01J2219/3083 ,  B01J2219/312 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0266 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C07C1/0425 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G35/06 ,  C10G35/085 ,  Y02P20/142 ,  Y02P20/52 ,  C07C9/04

摘要： The invention relates to a catalyst for catalytic reactors of which the outer shape is a helix with n blades, where n≥1 and is such that the stack void fraction percentage (SVFP) is between 75 % and 85 % and the surface area/volume ratio (S/V) is greater than 1000 m
2 /m
3 .

摘要翻译： 本发明涉及一种用于催化反应器的催化剂，其外形为具有n个叶片的螺旋，其中n≥1并且使得堆积空隙率百分比（SVFP）在75％和85％之间，并且表面积/体积 比（S / V）大于1000m2 / m3。

公开(公告)号：EP2997000A4

公开(公告)日：2017-04-05

申请号：EP13884408

申请日：2013-07-24

申请人： DALIAN INST CHEMICAL PHYSICS CAS

发明人： BAO XINHE ,  GUO XIAOGUANG ,  FANG GUANGZONG ,  DENG DEHUI ,  MA HAO ,  TAN DALI

IPC分类号： C07C2/08 ,  B01J29/00 ,  C01B33/113

CPC分类号： B01J23/06 ,  B01J21/08 ,  B01J23/002 ,  B01J23/02 ,  B01J23/10 ,  B01J23/14 ,  B01J23/745 ,  B01J23/75 ,  B01J23/78 ,  B01J23/8892 ,  B01J27/224 ,  B01J27/24 ,  B01J35/002 ,  B01J37/0081 ,  B01J37/0203 ,  B01J37/0236 ,  B01J37/0238 ,  B01J37/349 ,  B01J2523/00 ,  C07C2/76 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/224 ,  C07C2527/24 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C15/073 ,  C07C15/24 ,  B01J2523/41 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/13 ,  B01J2523/842 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/43 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/44

摘要： Provided are the preparation of a metal lattice-doping catalyst in an amorphous molten state, and the process of catalyzing methane to prepare olefins, aromatics, and hydrogen using the catalyst under oxygen-free, continuous flowing conditions. Such a process has little coke deposition and realizes atom-economic conversion. Under the conditions encountered in a fixed bed reactor (i.e. reaction temperature: 750-1200 °C; reaction pressure: atmospheric pressure; the weight hourly space velocity of feed gas: 1000-30000 ml/g/h; and fixed bed), the conversion of methane is 8-50%. The selectivity of olefins is 30-90%. And the selectivity of aromatics is 10-70%.

摘要翻译： 本发明提供一种金属晶格掺杂催化剂在无定形熔融状态的制剂，和催化甲烷使用无氧的，连续流动的条件下与催化剂以制备烯烃，芳烃和氢的过程。 这样的方法具有很少焦炭沉积，实现原子经济转换。 下，在固定床反应器中所遇到的条件（即反应温度：750〜1200℃;反应压力：常压，进料气体的重时空速：1000-30000毫升/克/小时，和固定床），则 甲烷的转化率是8-50％。 烯烃的选择性为30-90％。 和芳烃的选择性为10-70％。

公开(公告)号：EP2952252A1

公开(公告)日：2015-12-09

申请号：EP14746478.8

申请日：2014-01-31

申请人： Osaka University ,  N.E. Chemcat Corporation

发明人： KANEDA, Kiyotomi ,  TAKAGI, Yukio

IPC分类号： B01J23/66 ,  B01J35/08 ,  B01J37/04 ,  B01J37/08 ,  C07C1/247 ,  C07C15/46 ,  C07C29/141 ,  C07C29/145 ,  C07C33/02 ,  C07C33/14 ,  C07C33/20 ,  C07C33/22 ,  C07C33/48 ,  C07C35/44 ,  C07C41/26 ,  C07C43/23 ,  C07B61/00

CPC分类号： B01J23/66 ,  B01J35/08 ,  B01J37/04 ,  B01J37/08 ,  C07C1/247 ,  C07C15/46 ,  C07C29/141 ,  C07C41/26 ,  C07C209/36 ,  C07C2523/10 ,  C07C2523/50 ,  C07C2523/66 ,  C07C2601/16 ,  C07C33/32 ,  C07C33/03 ,  C07C33/14 ,  C07C43/23 ,  C07C33/483 ,  C07C33/30 ,  C07C33/025 ,  C07C211/45

摘要： Provided are a selective hydrogenation catalyst exhibiting a superior reactivity and selectivity against an oxygen-containing polar functional group(s) in a compound having a hydrogenation reaction site(s) such as a carbon-carbon double bond and an oxygen-containing polar functional group(s) such as an epoxy bond; a method for producing such selective hydrogenation catalyst; and a method for selectively hydrogenating such compound using this type of selective hydrogenation catalyst. In a method for hydrogenating a compound having a hydrogenation reaction site(s) and an oxygen-containing polar functional groups(s), this compound is brought into contact with a hydrogen gas in a liquid phase under the presence of a selective hydrogenation catalyst with a silver component-cerium oxide complex being supported on a metal oxide support, the silver component-cerium oxide complex including silver component particles and a cerium oxide supported on the surfaces of such silver component particles. Thus, the oxygen atoms in the oxygen-containing polar functional group(s) can be selectively hydrogenated.

公开(公告)号：EP2660228B1

公开(公告)日：2015-11-25

申请号：EP11853767.9

申请日：2011-06-24

申请人： Dalian Institute Of Chemical Physics, Chinese Academy of Sciences

发明人： LIU, Zhongmin ,  WEI, Yingxu ,  QI, Yue ,  YE, Mao ,  LI, Mingzhi ,  LI, Bing ,  WANG, Xiangao ,  HE, Changqing ,  SUN, Xinde

IPC分类号： C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C4/06 ,  C07C1/20 ,  B01J29/40 ,  C10G11/05 ,  C07C11/02 ,  C10G11/10 ,  C10G11/18 ,  C10G3/00 ,  B01J37/00 ,  C07C2/84

CPC分类号： C07C2/84 ,  B01J29/405 ,  B01J37/0036 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/42 ,  C07C1/20 ,  C07C2523/10 ,  C07C2527/14 ,  C07C2529/40 ,  C10G3/49 ,  C10G11/05 ,  C10G11/10 ,  C10G11/18 ,  C10G2300/1044 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

公开(公告)号：EP2928603A1

公开(公告)日：2015-10-14

申请号：EP13814454.8

申请日：2013-12-04

申请人： BASF SE

发明人： GRÜNE, Philipp ,  RÜTTINGER, Wolfgang ,  HAMMEN, Oliver ,  WALSDORFF, Christian

IPC分类号： B01J37/03 ,  B01J23/887 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  C07C5/48

CPC分类号： B01J23/8878 ,  B01J23/28 ,  B01J35/008 ,  B01J35/026 ,  B01J37/0221 ,  B01J37/033 ,  B01J37/08 ,  B01J2523/00 ,  C07C2/06 ,  C07C5/32 ,  C07C5/48 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/16 ,  C07C2523/18 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G27/04 ,  C10G2400/02 ,  C10G2400/04 ,  B01J2523/13 ,  B01J2523/54 ,  B01J2523/67 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  C07C11/167 ,  C07C11/08

摘要： The invention relates to a catalyst which is obtainable from a catalyst precursor comprising a catalytically active multimetal oxide which contains molybdenum and at least one further metal and is of the general formula (I) Mo
12 Bi
a Fe
b Co
c Ni
d Cr
e X
1
f X
2
g O
x ,in which the variables have the following meaning: X
1 = W, Sn, Mn, La, Ce, Ge, Ti, Zr, Hf, Nb, P, Si, Sb, Al, Cd and/or Mg; X
2 = Li, Na, K, Cs and/or Rb, a = 0.1 to 7, preferably 0.3 to 1.5; b = 0 to 5, preferably 2 to 4; c = 0 to 10, preferably 3 to 10; d = 0 to 10; e = 0 to 5, preferably 0.1 to 2; f = 0 to 24, preferably 0.1 to 2; g = 0 to 2, preferably 0.01 to 1; and x = a number which is determined by the valency and frequency of the elements in (I) that are different from oxygen, characterized in that the catalyst has the shape of a hollow cylinder, wherein the inner diameter is 0.2 to 0.8-times the outer diameter and the length is 0.5 to 2.5-times the outer diameter, and in that the catalyst precursor does not contain pore formers.

摘要翻译： 本发明涉及可由包含催化活性多金属氧化物的催化剂前体获得的催化剂，所述催化活性多金属氧化物包含钼和至少一种其他金属并且具有通式（I）Mo 12 Bi a Fe b Co c Ni dCr eX 1 fX 2 gO x， 其中变量具有以下含义：X 1 = W，Sn，Mn，La，Ce，Ge，Ti，Zr，Hf，Nb，P，Si，Sb，Al，Cd和/或Mg; X 2 = Li，Na，K，Cs和/或Rb，a = 0.1至7，优选0.3至1.5; b = 0至5，优选2至4; c = 0至10，优选3至10; d = 0至10; e = 0-5，优选0.1-2; f = 0-24，优选0.1-2; g = 0-2，优选0.01-1; x =由（I）中的元素的价数和频率确定的与氧不同的数，其特征在于，催化剂具有中空圆柱体的形状，其中内径为0.2至0.8倍 外径和长度为外径的0.5至2.5倍，并且催化剂前体不含成孔剂。