SOLUTION POLYMERIZATION PROCESS FOR PREPARING POLYOLEFINS
    32.
    发明公开
    SOLUTION POLYMERIZATION PROCESS FOR PREPARING POLYOLEFINS 无效
    解决方案聚合物制备聚合物的方法

    公开(公告)号:EP2225290A1

    公开(公告)日:2010-09-08

    申请号:EP08864802.7

    申请日:2008-12-18

    IPC分类号: C08F6/10 C08F10/00

    摘要: A solution process for polymerizingone or more α-olefins of formula CH2=CHR, where R is H or an alkyl radical C1-12,to produce a polyolefin soluble in the reaction medium, the process comprising: a) polymerizing said one or more α-olefins in a solution phase in the presence of a polymerization catalyst and a inert solvent having a vapor pressure lower than 100 kPa at 20°C; b) separating the produced polyolefin from the unreacted monomers and the inert solvent by means of a sequence of at least three volatilization chambers operating at a decreasing pressure, the second devolatilization chamber being operated at a pressure from 0.8 to 5 bar.

    摘要翻译: 一种聚合一种或多种式CH 2 = CHR(其中R为H或烷基C1-12)的α-烯烃以制备可溶于反应介质中的聚烯烃的溶液方法,所述方法包括:a)使所述一种或多种α 在20℃下在聚合催化剂和蒸气压低于100kPa的惰性溶剂存在下在溶液相中进行聚合; b)通过一系列在减压下操作的至少三个挥发室将所生产的聚烯烃与未反应的单体和惰性溶剂分离,第二脱挥发室在0.8-5巴的压力下操作。