摘要:
Process for the gas-phase catalytic polymerization of olefins carried out in a plurality of interconnected polymerization zones, the process comprising feeding one or more monomers to said polymerization zones in the presence of a catalyst under reaction conditions and collecting the polymer product from said polymerization zones, in which process the polymer particles grow within a first polymerization zone where a fluidized bed is formed, at least a part of said polymer particles leave said first polymerization zone to enter a second polymerization zone through which they flow downward, leave said second polymerization zone and enter a third polymerization zone through which they flow upward under fast fluidization or transport conditions, leave said third polymerization zone and are reintroduced into the first polymerization zone, thus establishing a circulation of polymer between the different polymerization zones.
摘要:
A fibre for spunbonded fabrics comprising a propylene polymer composition (A) having an MFR (1) value from 6 to 150 g/10 min and being selected from (i) a crystalline propylene random copolymer or crystalline propylene polymer composition containing at least 0.8% by weight of ethylene and having a melting temperature of 153° C or higher, a content of fraction soluble in xylene at room temperature lower than 10% by weight, and a value of the ratio of the polymer fraction collected at the temperature range from 25° to 95° C to the xylene soluble fraction at room temperature higher than 4; and (ii) a crystalline propylene polymer composition having a melting temperature of 153° C or higher, a content of fraction soluble in xylene at room temperature lower than 10% by weight; the said composition containing at least 0.64 wt% of ethylene or a C4-C10 a-olefin recurring unit and comprising: (1) 20-80 wt% of a crystalline propylene polymer containing up to 1.5 wt% of ethylene and/or C4-C10 a-olefin; and (II) 20-80 wt% of a crystalline propylene random copolymer selected from (IIa) a copolymer of propylene with 0.8 to 10 wt% of ethylene and/or (IIb) a copolymer of propylene with 1.5 to 18 wt% of a C4-CIO a-olefin. Said polymer composition (A) is obtainable by way of chemical degradation of a precursor polymer composition (A) having MFR values (MFR (2)) of from 0.5 to 50 g/10 min, provided that the ratio of MFR (1) to MFR (2) be from 1.5 to 60. Propylene polymer composition (ii) as described above and non-woven fabrics that are prepared with the said fibres. The said fabric is useful for coverstock and diapers.
摘要:
A polymer blend having a high melt strength and a low Young's modulus after irradiation of the polymers contains (1) a propylene homopolymer or copolymer having an isotactic index of greater than 90 and (2) a propylene homopolymer or copolymer having a crystallinity of
摘要:
Polymers containing N-phenylimide groups are made by reacting polymers containing succinic or glutaric anhydride groups with a substituted or unsubstituted aminobenzoic acid in a devolatilizing extruder at a barrel temperature of about 180° to about 320 °C, whereby complete decarboxylation takes place during the formation of the N-phenylimide groups.
摘要:
A process for effecting a coupling between a plastic material and a metal surface comprising the steps of applying a powder of a adhesive polymer composition to the metal surface; then overmoulding the metal surface with a plastic material by injection moulding; and finally applying heat to the metal surface.
摘要:
A polypropylene resin composition comprising (by weight) 40 to 80% of a polypropylene component (A) comprising a copolymer of propylene with ethylene and/or a C4-12 α-olefin, or a homopolymer of propylene, and 20 to 60% of a copolymer component (B) containing a copolymer (B-1) and a copolymer (B-2), wherein both (B-1) and (B-2) are copolymers of propylene with ethylene and/or a C4-12 α-olefin, in (B-1) the amount of units derived from propylene is from more than 50% by weight to 85% by weight, and in (B-2) the amount of units derived from propylene is 15 to 50% by weight, the molecular weight distribution (Mw/Mn) is 3.0 or less, and blockness (CSD) determined using the measured NMR values is 1.3 or less; in which composition the amount of (B-2) with respect to the whole polypropylene resin composition is 3% or more, and the ratio of the limiting viscosity of (B-1) to the viscosity of (A) ([η]B-1/[η]A) is 1.5 or less, and the ratio of the limiting viscosity of (B-1) to the viscosity of (B-2) ([η]B-1/[η]B-2) is 0.8 or more.
摘要:
The thermal oxidative stability of acrylic grafted polymers is improved by (a) graft polymerizing monomers selected from the group consisting of (i) an ester or salt of an unsubstituted or 1-3 C alkyl-substituted acrylic acid and (ii) an ester or salt of an unsubstituted or 1-3 C alkyl-substituted acrylic acid and about 1 to about 10 mole %, based on the total monomers added, of an unsubstituted or 1-3 C alkyl-substituted acrylic acid, to a backbone of a propylene polymer material in the presence of a 4-vinyl-substituted 5-12 C cyclic 1-alkene, wherein the total amount of polymerized monomer is about 20 to about 200 parts per hundred parts of the propylene polymer material and the vinyl-substituted cyclic alkene is present in an amount of about 1 mole % to about 30 mole %, based on the total moles of monomer added, and (b) removing any unreacted grafting monomer from the resulting grafted propylene polymer material, decomposing any unreacted initiator, and deactivating any residual free radicals in the material, wherein steps (a) and (b) are carried out in a substantially non-oxidizing environment.
摘要:
Polyolefin compositions for seal peel films, comprising (percent by weight): A) from 20 to 50 % of HDPE, LDPE or EVA having MFR higher than 0.3 g/10 min; B) from 30 to 80 % of a random copolymer of propylene with ethylene and/or a C4-C8 α-olefin, or of a polyolefin composition comprising not less than 20 % of said random copolymer of propylene; C) from 0 to 20 % of an elastomeric or elastomeric thermoplastic olefin polymer.