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公开(公告)号：EP1169416A1
公开(公告)日：2002-01-09
申请号：EP00908284.3
申请日：2000-01-14
Applicant: ExxonMobil Research and Engineering Company
Inventor： RILEY, Kenneth, Lloyd , SCHUETTE, William, Lee , SOLED, Stuart, Leon , MISEO, Sabato
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2300/1062 , C10G2300/301 , C10G2300/302 , C10G2300/4018 , C10G2300/44 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/67 , B01J2523/847 , B01J2523/31 , B01J2523/41
Abstract: A two stage hydrodesulfurizing process for producing low sulfur distillates. A distillate boiling range feedstock containing in excess of about 3,000 wppm sulfur is hydrodesulfurized in a first hydrodesulfurizing stage containing one or more reaction zones in the presence of hydrogen and a hydrodesulfurizing catalyst. The liquid product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid product stream, which has a substantially lower sulfur and nitrogen content than the original feedstream is passed to a second hydrodesulfurizing stage also containing one or more reaction zones where it is reacted in the presence of hydrogen and a second hydrodesulfurizing catalyst at hydrodesulfurizing conditions. The catalyst in any one or more reaction zones is a bulk multimetallic catalyst comprised of at lease one Group VIII non-noble metal and at least two Group VIB metals.
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32.发明公开MULTISTAGE PROCESS FOR HYDRODESULFURIZING-HYDROGENATING DISTILLATES USING BULK MULTIMETALLIC CATALYST 审中-公开多阶段过程FOR DISTILLATEN的HYDRODESULPHORIERUNG加氢与散装形式更多金属催化剂
公开(公告)号：EP1169413A1
公开(公告)日：2002-01-09
申请号：EP00904363.9
申请日：2000-01-14
Inventor： RILEY, Kenneth, Lloyd , KLEIN, Darryl, Patrick , HOU, Zhiguo , SOLED, Stuart, Leon , KERBY, Michael, Charles , MCVICKER, Gary, Brice , ELLIS, Edward, Stanley , TOUVELLE, Michele, Sue , MISEO, Sabato
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2300/1062 , C10G2300/301 , C10G2300/302 , C10G2300/4018 , C10G2300/44 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/67 , B01J2523/847 , B01J2523/31 , B01J2523/41
Abstract: A two stage hydrodesulfurizing process for producing low sulfur distillates. A distillate boiling range feedstock containing in excess of about 3,000 wppm sulfur is hydrodesulfurized in a first hydrdesulfurzing stage containing one or more reaction ones in the presence of hydrogen and a hydrodesulfurizing catalyst. The liquid product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid product stream, which has a substantially lower sulfur and nitrogen content than the original feedstream is passed to a second hydrodesulfurizing stage also containing one or more reaction zones where it is reacted in the presence of hydrogen and a second hydrodesulfurizing catalyst at hydrodesulfurizing conditions. The catalyst in any one or more reaction zones is a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals.
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33.发明公开HYDROTREATING OR RAW VIRGIN DISTILLATES USING NOVEL BULK MULTIMETALLIC CATALYSTS 审中-公开罗德风格加氢新LATEN MEHRMETALLISCHEM催化剂散装形式
公开(公告)号：EP1169411A1
公开(公告)日：2002-01-09
申请号：EP00908283.5
申请日：2000-01-14
Applicant: ExxonMobil Research and Engineering Company
Inventor： RILEY, Kenneth, Lloyd , KLEIN, Darryl, Patrick , HOU, Zhiguo , SOLED, Stuart, Leon , KERBY, Michael, Charles , McVICKER, Gary, Brice , ELLIS, Edward, Stanley , TOUVELLE, Michele, Sue , MISEO, Sabato
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2300/1062 , C10G2300/301 , C10G2300/302 , C10G2300/4018 , C10G2300/44 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/67 , B01J2523/847 , B01J2523/31 , B01J2523/41
Abstract: Hydrotreating a petroleum feedstream comprised of at least 50 wt. % of an atmospheric distillation distillate boiling range product stream, preferably hydrodesulfurization of raw virgin petroleum distillates, using a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.
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公开(公告)号：EP3221429A1
公开(公告)日：2017-09-27
申请号：EP15797556.6
申请日：2015-11-10
Applicant: Exxonmobil Research And Engineering Company
Inventor： XU, Xiaochun , WILSON, Keith , SOLED, Stuart, Leon , MISEO, Sabato , LEVIN, Doron , BAUMGARTNER, Joseph, Ernest
CPC classification number: C10G45/50 , B01J23/882 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J37/20 , C10G35/06 , C10G45/08 , C10G47/06 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G69/02 , C10G69/08 , C10G2300/1048 , C10G2300/202 , C10G2300/301 , C10G2400/00 , C10M101/02
Abstract: Methods are provided for hydroprocessing a feed (such as hydrotreating, hydrocracking, or hydrofining a feed) to generate a product with a reduced or minimized aromatics content relative to the severity of the hydroprocessing conditions. In some types of hydroprocessing applications, it can be desirable to select the severity of hydroprocessing conditions to achieve a desired level of removal for sulfur, a desired level for removal of nitrogen, and/or a desired level for increasing the viscosity index of a feed. The severity for heteroatom removal and/or viscosity index uplift can also correspond to an amount of conversion of a feed to lower boiling point products, so the lowest severity conditions suitable for achieving a product quality can be desirable. By improving the aromatics saturation during hydroprocessing, the severity of subsequent aromatics saturation processes can be reduced.
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公开(公告)号：EP3152277A1
公开(公告)日：2017-04-12
申请号：EP15727766.6
申请日：2015-05-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： LANCI, Michael, P. , SOLED, Stuart, L. , GUZMAN, Javier , MISEO, Sabato , GREEN, Thomas, Elmer , BAUMGARTNER, Joseph, Ernest
CPC classification number: C10G45/52 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/468 , B01J31/0241 , B01J31/28 , B01J37/0201 , B01J37/0203 , C10G45/00 , C10G45/34 , C10G45/46 , C10G2300/202
Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
Abstract translation: 提供了用于用另外的氧化铝修饰具有二氧化硅载体（或其它非氧化铝载体）的加氢催化剂的方法，并且使用这样的催化剂实现了出人意料的优异的原料氢化。 改进的氢化催化剂可以具有相对低的裂化活性，同时提供增加的氢化活性。
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Patent Agency Ranking36.发明公开
公开(公告)号：EP2576053A1
公开(公告)日：2013-04-10
申请号：EP11727015.7
申请日：2011-06-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： SOLED, Stuart, L. , MISEO, Sabato , BAUMGARTNER, Joseph, E. , NISTOR, Iulian, G. , VENKATARAMAN, Pallassana, S. , KLIEWER, Chris, E. , CHIMENTI, Robert, J. , GUZMAN, Javier , KENNEDY, Gordon , LEVIN, Doron
CPC classification number: B01J31/04 , B01J23/882 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J31/0237 , B01J31/0247 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0203 , B01J37/08 , B01J37/20 , B01J2231/60 , B01J2523/00 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/06 , C10G45/08 , C10G2300/1074 , C10G2300/202 , C10G2300/703 , C11B3/02 , B01J2523/56 , B01J2523/69 , B01J2523/847 , B01J2523/55 , B01J2523/845 , B01J2523/68
Abstract: Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group and at least 10 carbon atoms or (ii) a second organic compound containing at least one carboxylic acid group and at least 10 carbon atoms, but not both, wherein the reaction product contains additional unsaturated carbon atoms, relative to the first or second organic compound, wherein the metals of the catalyst precursor composition are arranged in a crystal lattice, and wherein the reaction product is not located within the crystal lattice. A process for preparing the catalyst precursor composition is also described, as is sulfiding the catalyst precursor composition to form a hydroprocessing catalyst.
Abstract translation: 本文描述的催化剂前体组合物包含元素周期表第6族中的至少一种金属，元素周期表第8-10族中的至少一种金属和由（i） 含有至少一个胺基和至少10个碳原子的第一有机化合物或（ii）含有至少一个羧酸基团和至少10个碳原子但不包括两者的第二有机化合物，其中反应产物含有额外的不饱和碳原子 相对于第一或第二有机化合物，其中催化剂前体组合物的金属排列在晶格中，并且其中反应产物不位于晶格内。 还描述了制备催化剂前体组合物的方法，因为硫化催化剂前体组合物以形成加氢处理催化剂。
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37.发明公开HYDROPROCESSING USING BULK BIMETALLIC CATALYSTS 审中-公开HYDRIERUNGÜBERUNGETRÄGERTEBIMETALLISCHE KATALYSATOREN
公开(公告)号：EP1951426A2
公开(公告)日：2008-08-06
申请号：EP06844216.9
申请日：2006-10-25
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： SOLED, Stuart, L. , MISEO, Sabato , EIJSBOUTS, Sonja , PLANTENGA, Frans, L.
IPC: B01J23/00 , B01J23/888 , B01J37/00 , B01J37/02 , B01J37/03
CPC classification number: B01J37/10 , B01J23/888 , B01J37/0072 , B01J37/03 , B01J37/08 , B01J37/20 , C10G45/08 , C10G2300/202 , C10G2300/207 , C10G2400/04 , C10G2400/10
Abstract: The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst comprising a Group VIII metal and a Group VIB metal.
Abstract translation: 本发明涉及通过使用大量双金属催化剂的加氢处理来改质烃类原料流的方法。 更具体地说，本发明涉及用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。 催化剂是包含VIII族金属和VIB族金属的本体催化剂。
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公开(公告)号：EP1740677A1
公开(公告)日：2007-01-10
申请号：EP05738108.9
申请日：2005-04-19
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： SHIH, Stuart, S. , SOLED, Stuart, Leon , MISEO, Sabato
IPC: C10G45/08 , B01J23/887 , B01J27/051 , B01J27/049 , B01J23/888
CPC classification number: C10G45/08 , B01J23/8877 , B01J23/888 , C10G45/06 , C10G45/10
Abstract: The instant invention relates to a process for producing low sulfur diesel products through the hydrotreating of diesel boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst comprising Nb, at least one metal selected from Group VIB metals and at least one metal selected from Group VIII metals.
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公开(公告)号：EP1737931A1
公开(公告)日：2007-01-03
申请号：EP05737086.8
申请日：2005-04-19
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： SOLED, Stuart, Leon , MISEO, Sabato , EIJSBOUTS, Sonja
IPC: C10G45/08 , B01J27/049 , B01J23/887
CPC classification number: C10G45/08 , B01J23/8877 , B01J23/888 , B01J37/0009 , B01J37/04 , C10G45/38 , C10G45/50 , C10G45/60 , C10G47/02 , C10G49/04
Abstract: The instant invention relates to a process to produce liquid products through the hydroprocessing of hydrocarbonaceous feedstreams in the presence of a bulk metal hydroprocessing catalyst.
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公开(公告)号：EP1694799A2
公开(公告)日：2006-08-30
申请号：EP04789160.1
申请日：2004-09-28
Applicant: ExxonMobil Research and Engineering Company
Inventor： RILEY, Kenneth, L. , SOLED, Stuart, L. , MISEO, Sabato , PLANTENGA, Frans, L. , CERFONTAIN, Marinus, Bruce , EIJSBOUTS, Sonja , BREVOORD, Eelko
IPC: C10G65/04
CPC classification number: C07D417/14 , B01J23/8885 , C07D403/12 , C07D413/12 , C07D417/12 , C07D487/04 , C07D487/08 , C07D491/08 , C10G2400/02
Abstract: A method for upgrading a naphtha feed to a naphtha product containing less than 10 wppm of nitrogen and less than 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
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