摘要:
The present invention refers to a method of preparing a separator, a separator prepared therefrom and an electrochemical device having the separator. The method of preparing a separator according to the present invention comprises providing a planar and porous substrate having multiple pores; and coating a first slurry on at least one surface of the porous substrate through a slot section to form a porous coating layer, while continuously coating a second slurry on the porous coating layer through a slide section adjacent to the slot section to form a layer for adhesion with an electrode, the first slurry comprising inorganic particles, a first binder polymer and a first solvent, and the second slurry comprising a second binder polymer and a second solvent. In accordance with the present invention, in the preparation of a separator, a second slurry comprising a binder polymer is smoothly discharged through a slide section without an external force to coat a layer for adhesion with an electrode on the top of a porous coating layer which is formed on a porous substrate by discharging a first slurry through a slot section, thereby preventing the inter-mixing of the porous coating layer and the layer for adhesion with an electrode, and eventually improving the adhesiveness of the separator to an electrode and preventing the performance of an electrochemical device from being deteriorated.
摘要:
Disclosed is a slot die, which includes a feed unit for introducing a coating material, a chamber for accommodating a coating material supplied through the feed unit, a slit communicating with the chamber to discharge the coating material, and a die body having die lips which form the slit, wherein the chamber includes a chamber block which has an inner space for accommodating the coating material and is configured so that the entire block is exchangeable with respect to the die body, and wherein a coating width is determined by a width of the inner space of the chamber block.
摘要:
The present invention refers to a separator for an electrochemical device and an electrochemical device having the same. More specifically, the separator of the present invention comprises a porous substrate; a first porous coating layer formed on one surface of the porous substrate and comprising a mixture of inorganic particles and a first binder polymer; and a second porous coating layer formed on the other surface of the porous substrate and comprising a product obtained by drying a mixture of a solvent, a non-solvent and a second binder polymer. Such separator of the present invention can have good thermal safety due to a porous organic-inorganic coating layer formed on one surface thereof, and superior adhesiveness due to a porous coating layer made of a binder thin film formed by applying and drying a mixture of a binder polymer and a non-solvent on the other surface thereof. Also, the separator can have a decreased thickness to reduce the resistance of electrochemical device and improve the capacity thereof
摘要:
An electrode assembly is disclosed. The electrode assembly has a structure in which a plurality of unit cells are bonded to one or both surfaces of a first separator whose length is greater than width and are stacked in a zigzag pattern or wound sequentially. The first separator includes a first porous electrode adhesive layer, to which electrodes of the unit cells are adhered, formed at one surface thereof to which the unit cells are bonded. The first porous electrode adhesive layer includes a mixture of inorganic particles and a binder polymer. Each of the unit cells includes a second separator. The second separator includes second porous electrode adhesive layers, to which electrodes of the unit cell are adhered, formed at both surfaces thereof. Each of the second porous electrode adhesive layers includes a mixture of inorganic particles and a binder polymer. Further disclosed is an electrochemical device including the electrode assembly. The separators, each of which includes the porous electrode adhesive layers, to which electrodes are adhered, formed at both surfaces thereof, and the separator including a porous electrode adhesive layer, to which electrodes are adhered, formed at one surface thereof are separately used in the electrode assembly. This reduces the electrical resistance of the separators, contributing to an improvement in the performance of the electrochemical device.
摘要:
Disclosed is an electrochemical device. The electrochemical device includes: (a) a composite separator including a porous substrate, a first porous coating layer coated on one surface of the porous substrate, and a second porous coating layer coated on the other surface of the porous substrate; (b) an anode disposed to face the first porous coating layer; and (c) a cathode disposed to face the second porous coating layer. The first and second porous coating layers are each independently composed of a mixture including inorganic particles and a binder polymer. The first porous coating layer is thicker than the second porous coating layer. The electrochemical device has good thermal stability and improved cycle characteristics.
摘要:
The present invention relates to a method for manufacturing a cable-type secondary battery comprising an electrode that extends longitudinally in a parallel arrangement and that includes a current collector having a horizontal cross section of a predetermined shape and an active material layer formed on the current collector, and the electrode is formed by putting an electrode slurry including an active material, a polymer binder, and a solvent into an extruder, by extrusion-coating the electrode slurry on the current collector while continuously providing the current collector to the extruder, and by drying the current collector coated with the electrode slurry to form an active material layer.
摘要:
The present disclosure relates to a method for manufacturing a crosslinked structure-containing separator for a lithium secondary battery, including the steps of: supplying polyolefin and a diluting agent to an extruder to extrude a polyolefin composition; molding and orienting the extruded polyolefin composition into the form of a sheet; dipping the oriented sheet in an extraction solution to extract the diluting agent, thereby providing a polyolefin-based porous support; and irradiating ultraviolet rays to the polyolefin-based porous support, wherein the extraction solution has an upper layer and a lower layer, the lower layer includes a photoinitiator and a solvent for the photoinitiator, the upper layer includes a non-solvent for the photoinitiator, and the photoinitiator is present in an amount of 0.01-0.3 parts by weight based on 100 parts by weight of the solvent for the photoinitiator. The present disclosure also relates to a crosslinked structure-containing separator for a lithium secondary battery obtained from the method, and a lithium secondary battery including the crosslinked structure-containing separator for a lithium secondary battery. The crosslinked structure-containing separator for a lithium secondary battery uses a minimized amount of photoinitiator to prevent degradation of the mechanical strength of the separator after crosslinking, while accomplishing crosslinking of the polyolefin porous support.
摘要:
The present disclosure relates to a crosslinked structure-containing separator for a lithium secondary battery, including: a crosslinked structure-containing polyolefin porous support having a crosslinked structure including polymer chains interconnected directly with one another; and a photoinitiator having an oxidation potential at least 0.02 V higher than the fully charged voltage of the lithium secondary battery, a method for manufacturing the same, and a lithium secondary battery including the separator. The lithium secondary battery including the separator has excellent high-temperature safety and can improve the problem of degradation of capacity after high-temperature storage.
摘要:
The present disclosure relates to a crosslinked structure-containing polyolefin porous support which has a number of double bonds present in the polyolefin chains of 0.01-0.6 per 1000 carbon atoms, as determined by 1 H-NMR, and includes a crosslinked structure having polymer chains interconnected directly with one another, a crosslinked structure-containing separator for a lithium secondary battery including the same and a method for manufacturing the same, and a lithium secondary battery including the separator. The crosslinked structure-containing separator for a lithium secondary battery has improved high-temperature safety, and thus can minimize degradation of the performance of a lithium secondary battery including the separator, even after storing the lithium secondary battery at high temperature.
摘要:
The present disclosure relates to a separator having excellent safety and a lithium secondary battery including the same. The separator includes: a porous polymer substrate; and an organic/inorganic composite porous layer disposed on at least one surface of the porous polymer substrate and including inorganic particles and a binder polymer, wherein the inorganic particles have a BET specific surface area of 50-150 m 2 /g, the organic/inorganic composite porous layer has a thickness larger than the thickness of the porous polymer substrate, and the surface of the organic/inorganic composite porous layer has an arithmetic mean roughness of 100-500 nm.