摘要:
The present disclosure relates to a crosslinked structure-containing polyolefin porous support which has a crosslinked structure including polymer chains interconnected directly with one another, wherein a first peak is detected at a g value of 2.010-2.030 as determined by electron spin resonance spectroscopy by irradiating ultraviolet rays thereto at 500 W. The present disclosure also relates to a crosslinked structure-containing separator for a lithium secondary battery including the crosslinked structure-containing polyolefin porous support, and a lithium secondary battery including the separator. The crosslinked structure-containing polyolefin porous support shows excellent heat resistance.
摘要:
Disclosed is a separator for a lithium secondary battery including a porous polyolefin substrate and showing a tan(δ) of 0.3 or less in the storage-loss modulus curve. Also disclosed is an electrochemical device including the separator. The separator shows low viscosity but high elasticity at high temperature. Therefore, the separator maintains its strength at high temperature and ensures resistance against external force in the state of high-temperature exposure, and thus can provide a lithium secondary battery with improved safety. In addition, according to an embodiment of the present disclosure, it is possible to obtain a crosslinked polyolefin separator through a simplified process, unlike the related art.
摘要:
Disclosed is a composite separator for an electrochemical device, including: a porous polymer substrate having a plurality of pores; and a porous coating layer formed on at least one surface of the porous polymer substrate and including a plurality of particles and a binder positioned on the whole or a part of the surface of the particles to connect the particles with one another and fix them, wherein the particles include inorganic particles, organic particles or both, and the composite separator has a melt-down temperature of 170°C or higher. An electrochemical device including the composite separator is also disclosed.
摘要:
Disclosed is a separator for an electrochemical device which comprises: a porous substrate having a plurality of pores; and a porous coating layer positioned on at least one surface of the porous substrate, and including a plurality of inorganic particles and a binder polymer positioned on the whole or a part of the surface of the inorganic particles to connect the inorganic particles with one another and fix them, wherein the binder polymer comprises a first binder polymer and a second binder polymer, the first binder polymer has an electrolyte uptake of 80-165%, and the second binder polymer has an electrolyte uptake of 20-40%. An electrochemical device including the separator is also disclosed.
摘要:
Disclosed are a separator having an electrode adhesive layer and an electrochemical device including the same. The electrode adhesive layer includes organic particles and an acrylic resin binder. Preferably, the acrylic resin binder is present in an amount of 30 wt% or more, so that a film-shaped electrode adhesive layer can be formed even when the organic particles have a particle diameter smaller than that of the pores of the underlying substrate or voids of the underlying porous coating layer.
摘要:
The present disclosure refers to a separator, comprising a microcapsule consisting of core-shell layer-spacer layer and loading a thermal stabilizer, which can release the thermal stabilizer on the overheating of a battery using the same, thereby achieving thermal stability of the battery.
摘要:
The present disclosure provides an organic/inorganic composite porous membrane, comprising: one or more particles selected from inorganic particles and organic particles; and a binder polymer, wherein said one or more particles selected from inorganic particles and organic particles are bonded with each other by the binder polymer surrounding the surface of the particles, and said one or more particles are filled at a rate of 60 to 70% in the membrane.
摘要:
The present disclosure provides a method of preparing a separator for a lithium secondary battery, comprising: (S1) bringing polymer particles into electric charging to obtain electrically charged polymer particles; (S2) transferring the electrically charged polymer particles on at least one surface of a porous polymer substrate to form an electrode-adhesion layer whose area ranges from 1 to 30% based on the total area of the porous polymer substrate; and (S3) fixing the electrode-adhesion layer with heat and pressure. In accordance with the present disclosure, in the preparation of a separator for a lithium secondary battery, an electrode-adhesion layer is applied by using electrostatic charging, more specifically coating polymer particles by way of laser printing, without the addition of a slurry in a solvent, thereby allowing easy handling and storage and needs no drying step of the solvent to provide cost savings effect as well as rapid and efficient preparation of the separator. Further, the electrode-adhesion layer is applied in a certain area, not the whole area in the separator, thereby preventing an excessive resistance rise in a lithium secondary battery using the separator.