摘要:
Silane functional polymers having uniform silane distribution, long chain branching or tertiary silane functionality and conversion thereof through coupling, hydrolysis, hydrolysis and neutralization, condensation, oxidation or hydrosilation are disclosed.
摘要:
A process for preparing titanium or zirconium diene complexes wherein the metal is in the + 2 formal oxidation state comprising contacting a conjugated or nonconjugated C4-40 diene compound with a hydrocarbyloxide containing precursor complex.
摘要:
Catalyst compositions comprising Group 4 metal complexes containing a diene moiety and activating cocatalysts are used as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers. Vinylidene aromatic monomers, particularly styrene are polymerized to form highly syndiotactic polymers.
摘要:
Novel titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, π-bonded, group, said complexes corresponding to formula (I), wherein: M is titanium or zirconium in the +2 formal oxidation state; L is a group containing a cyclic, delocalized, anionic, π-system through which the group is bound to M, and which group is also bound to Z; Z is a moiety bound to M via a σ-bond, comprising boron, or a member of Group 14 of the Periodic Table of the Elements, and also comprising nitrogen, phosphorus, sulfur or oxygen, said moiety having up to 60 non-hydrogen atoms; and X is a neutral, conjugated or nonconjugated diene, optionally substituted with one or more hydrocarbyl groups, said X having up to 40 carbon atoms and forming a π-complex with M; are catalytically activated for use as addition polymerization catalysts. Preferably, L is an optionally substituted cyclopentadienyl or fused ring cyclopentadienyl group.
摘要:
Addition polymerization catalysts comprising a metal complex containing a Group 4 metal in the +3 oxidation state, a delocalized π-bonding moiety, and at least one stabilizing ligand, optionally in combination with an activating cocatalyst.
摘要:
On prépare des complexes de métaux présentant des contraintes géométriques, utiles dans la préparation de catalyseurs de polymérisations oléfiniques par mise en contact de composés de cyclopentadiènyle avec des composés métalliques.