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    THERMOELASTIC BLEND COMPOSITIONS
    5.
    发明授权
    THERMOELASTIC BLEND COMPOSITIONS 失效
    热塑性组合

    公开(公告)号：EP0767814B1

    公开(公告)日：1999-08-25

    申请号：EP95923682.9

    申请日：1995-06-01

    申请人： THE DOW CHEMICAL COMPANY

    发明人： BETSO, Stephen, R. ,  GUEST, Martin, J. ,  VAN DEN BERGHEN, Peter, F., M. ,  BATISTINI, Antonio ,  AHMED, Wasif, K. ,  HO, Thoi, H. ,  KNIGHT, George, W. ,  PARIKH, Deepak, R. ,  PATEL, Rajen, M.

    IPC分类号： C08L53/02 ,  C08L23/16

    CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

    摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having:i. storage moduli throughout the range of -26° C. to 24° C. of less than about 3.5x109 dynes/cm2,ii. a ratio of storage modulus at -26° C. to storage modulus at 24° C. of less than about 4, andiii. storage moduli at -26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at -26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

    AZIDOSILANE-MODIFIED, MOISTURE-CURABLE POLYOLEFIN POLYMERS, PROCESS FOR MAKING, AND ARTICLES OBTAINED THEREFROM
    6.
    发明公开
    AZIDOSILANE-MODIFIED, MOISTURE-CURABLE POLYOLEFIN POLYMERS, PROCESS FOR MAKING, AND ARTICLES OBTAINED THEREFROM 审中-公开
    Azidosilane改进水分烯烃聚合物，方法及其生产和对象由其制

    公开(公告)号：EP1218422A1

    公开(公告)日：2002-07-03

    申请号：EP00952354.9

    申请日：2000-08-01

    申请人： THE DOW CHEMICAL COMPANY

    发明人： DRUMRIGHT, Ray, E. ,  HO, Thoi, H. ,  TERBRUEGGEN, Robert H.

    IPC分类号： C08F8/42

    CPC分类号： C08F8/42 ,  C08F10/00

    摘要： The invention includes a water-curable azidosilane grafted polymer selected from the group consisting of (i) homogeneous ethylene polymers which has a density less than or equal to 0.900 g/cm3, and (ii) interpolymers of at least one ethylene or α-olefin and at least one vinylidene aromatic compound. The water-curable silane-grafted polymer may comprise the reaction product of: at least one first polymer, the first polymer selected from the group consisting of an interpolymer, a substantially linear ethylene polymer, and a mixture thereof; the interpolymer comprising polymer units of at least one ethylene or α-olefin and at least one vinylidene aromatic compound; and at least one monofunctional azidosilane. The invention further includes a process for producing a water-curable silane-grafted polymer. A further embodiment of the process of the invention comprises shaping the water-curable silane-grafted polymer and contacting the shaped water curable silane-grafted polymer to form a moisture-cured polymer. The invention also includes the water curable silane-grafted polymers produced by either of the two processes along with any articles obtainable from that water curable silane-grafted polymer.

    COUPLING OF BLENDS OF $g(a)-OLEFIN/VINYL AROMATIC MONOMER OR HINDERED ALIPHATIC VINYL MONOMER INTERPOLYMERS WITH POLYOLEFINS
    9.
    发明公开
    COUPLING OF BLENDS OF $g(a)-OLEFIN/VINYL AROMATIC MONOMER OR HINDERED ALIPHATIC VINYL MONOMER INTERPOLYMERS WITH POLYOLEFINS 有权
    $ g（a） - 烯烃/乙烯基芳香族单体或加入脂肪族乙烯基单体的聚烯烃与聚烯烃共混物的结合

    公开(公告)号：EP1007589A1

    公开(公告)日：2000-06-14

    申请号：EP98941062.6

    申请日：1998-08-26

    申请人： THE DOW CHEMICAL COMPANY

    发明人： HO, Thoi, H. ,  TERBRUEGGEN, Robert, H. ,  SILVIS, H., Craig ,  CUMMINS, Clark, H. ,  MULLINS, Michael, J.

    IPC分类号： C08K5/43 ,  C08L23/16 ,  C08L23/02

    CPC分类号： C08K5/43 ,  C08G81/02 ,  C08L23/02 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0838 ,  C08L23/0853 ,  C08L2312/00 ,  C08L2314/06 ,  C08L2666/04

    摘要： The invention includes a process of preparing a coupled polymer blend by heating an admixture containing (1) a polymer blend of (A) from 1 to 99 weight percent of one or more α-olefin/hindered vinyl monomer substantially random interpolymers, each having been made from monomer components comprising: (1) from 0.5 to 65 mole percent of either (a) at least one vinyl aromatic monomer, or (b) at least one hindered aliphatic vinyl monomer, or (c) a combination of at least one vinyl aromatic monomer and at least one hindered aliphatic vinyl monomer; and (2) from 35 to 99.5 mole percent of at least one aliphatic α-olefin having from 2 to 20 carbon atoms; and (B) from 99 to 1 weight percent of one or more homopolymers or copolymers made from monomer components comprising aliphatic α-olefins having from 2 to 20 carbon atoms, or aliphatic α-olefins having from 2 to 20 carbon atoms and containing polar groups; and (2) a coupling amount of at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide).

    摘要翻译： 本发明包括通过加热含有（1）（A）1-99重量％的一种或多种α-烯烃/受阻
    的乙烯基单体基本上无规共聚体的聚合物共混物的混合物来制备偶联聚合物共混物的方法， （1）0.5-65％（摩尔）的（a）至少一种乙烯基芳族单体，或（b）至少一种位阻脂族乙烯基单体，或（c）至少一种乙烯基 芳族单体和至少一种受阻脂族乙烯基单体; 和（2）35至99.5摩尔％的至少一种具有2至20个碳原子的脂族α-烯烃; 和（B）99至1重量％的一种或多种由包含具有2至20个碳原子的脂肪族α-烯烃的单体组分或具有2至20个碳原子并且包含极性基团的脂肪族α-烯烃制成的均聚物或共聚物 ; 和（2）至少一个聚（磺酰叠氮化物）的偶联量至少与聚（磺酰叠氮化物）的分解温度相关。

    RHEOLOGY MODIFICATION OF INTERPOLYMERS OF ALPHA-OLEFINS AND VINYL AROMATIC MONOMERS
    10.
    发明公开
    RHEOLOGY MODIFICATION OF INTERPOLYMERS OF ALPHA-OLEFINS AND VINYL AROMATIC MONOMERS 审中-公开
    ALPHA-烯烃和乙烯基芳族单体RHEOLOGIEVERÄNDERUNG共聚物中

    公开(公告)号：EP1007585A1

    公开(公告)日：2000-06-14

    申请号：EP98938336.9

    申请日：1998-08-05

    申请人： THE DOW CHEMICAL COMPANY

    发明人： HO, Thoi, H. ,  DRUMRIGHT, Ray, E. ,  TERBRUEGGEN, Robert, H. ,  CUMMINS, Clark, H. ,  MULLINS, Michael, J. ,  SILVIS, H., Craig

    IPC分类号： C08K5/43

    CPC分类号： C08L23/02 ,  C08G81/02 ,  C08K5/43 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0838 ,  C08L23/0853 ,  C08L23/16 ,  C08L2205/22 ,  C08L2312/00 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/31913 ,  Y10T428/31917 ,  C08L2666/04

    摘要： The invention includes a process of preparing a coupled polymer comprising heating an admixture containing (1) at least one interpolymer of an alpha-olefin and vinyl aromatic monomer and (2) a coupling amount of at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer. The polymer preferably comprises ethylene, and a vinyl aromatic monomer, preferably styrene. The amount of poly(sulfonyl azide) is preferably from 0.01 to 1 weight percent of the interpolymer and the reaction preferably takes place at a temperature greater than 150 °C, more preferably 185 °C. The process optionally and in one preferred embodiment additionally comprises steps (b) fabricating an article from the coupled polymer and (c) cross-linking the fabricated coupled polymer. The invention additionally includes any composition produced by a process of the invention and any article made from the composition, preferably articles formed from a melt of the composition, more preferably by blow molding, blowing a film, foaming, or profile extruding, most preferably to form a coating for wire or cable, a tube, a gasket, a seal, roofing, or fiber. The article is optionally calendared. Additionally, the invention includes the use of compositions of the invention as starting materials for forming processes in which the composition is melted and especially in blow molding, blowing a film, foaming, or profile extruding, most preferably to form a coating for wire or cable, a tube, a gasket, a seal, roofing, or fiber.