Nickel/metal hydride storage battery
    33.
    发明公开
    Nickel/metal hydride storage battery 失效
    镍/ Metalhydrid Speicherbatterie

    公开(公告)号:EP0872904A3

    公开(公告)日:2005-09-28

    申请号:EP98106730.9

    申请日:1998-04-14

    IPC分类号: H01M4/52

    摘要: The present invention provides a nickel/metal hydride storage battery using improved nickel hydroxide with an increased energy density as the active material. This invention is characterized in that the nickel hydroxide as the active material of the positive electrode constituting the battery indispensably contains as a solid solution at least one transition metal selected from the group consisting of Mn, Cr and Co in a proportion of 2 to 20 atomic % based on the amount of the nickel hydroxide in terms of metallic nickel, and that the crystal structure of the nickel hydroxide at charged state is a hexagonal or tetragonal system which has a diffraction peak of 2θ on (00ℓ) plane of β-NiOOH at an angle of approximately 15° to 19° in X-ray diffraction using CuKα as a source and has a regular array with a NaCl type structure.

    摘要翻译: 本发明提供一种镍/金属氢化物蓄电池,其使用具有增加的能量密度的改进的氢氧化镍作为活性材料。 本发明的特征在于,作为构成电池的正极活性物质的氢氧化镍不可缺少地含有选自Mn,Cr和Co中的至少一种过渡金属,比例为2至20原子 基于氢氧化镍的量,以金属镍计,并且充电状态下的氢氧化镍的晶体结构是具有2θ的衍射峰的六方晶系或四方晶系; 在使用CuKα作为源的X射线衍射中,在大约15°至19°的角度处的β-NiOOH的(00l)平面上,并且具有NaCl型结构的规则阵列。

    Nickel-metal hydride storage battery
    36.
    发明公开
    Nickel-metal hydride storage battery 审中-公开
    镍 - 金属球墨铸铁

    公开(公告)号:EP1100141A1

    公开(公告)日:2001-05-16

    申请号:EP00124536.4

    申请日:2000-11-09

    IPC分类号: H01M10/34 H01M4/32 H01M4/24

    摘要: The present invention is to provide a nickel-metal hydride storage battery comprising a positive electrode (1) mainly composed of nickel hydroxide, a negative electrode (2) mainly composed of a hydrogen storage alloy powder electrochemically absorbing and desorbing hydrogen. a separator (3) and an alkaline electrolyte, wherein zinc and rare earth element are contained in at least one selected from the group consisting of the positive electrode, the separator and the electrolyte. Hence, the charge efficiency of nickel hydroxide can be improved at a high ambient temperature, and furthermore, the deterioration of the negative electrode due to oxidation can be suppressed, thereby enabling a provision of a nickel-metal hydride storage battery with a longer cycle life.

    摘要翻译: 本发明提供一种镍氢蓄电池,其特征在于,包括主要由氢氧化镍构成的正极(1),主要由电化学吸收和解吸氢的储氢合金粉末构成的负极(2)。 分离器(3)和碱性电解质,其中在选自正极,隔膜和电解质中的至少一种中含有锌和稀土元素。 因此,可以在高环境温度下提高氢氧化镍的充电效率,此外,可以抑制氧化引起的负极劣化,能够提供循环寿命更长的镍氢蓄电池 。

    Nickel-metal hydride secondary battery
    37.
    发明公开
    Nickel-metal hydride secondary battery 审中-公开
    镍金属网Sekundärbatterie

    公开(公告)号:EP1032067A2

    公开(公告)日:2000-08-30

    申请号:EP00103378.6

    申请日:2000-02-23

    IPC分类号: H01M10/30 H01M10/34

    摘要: A nickel-metal hydride secondary battery comprising electrode group comprising positive electrode comprised mainly of nickel hydroxide, negative electrode comprised mainly of a hydrogen storage alloy, and separator being disposed between the positive electrode and the negative electrode, wherein the electrode group is sealed in battery casing, together with an alkali electrolyte liquid, wherein, in the battery, a W element and an Na element are present simultaneously. The nickel-metal hydride secondary battery of the present invention is advantageous not only in that it exhibits high utilization of the active material and excellent self-discharge characteristics in a high temperature storage as well as high charging efficiency in a high temperature environment, but also in that it has excellent large current discharge characteristics.

    摘要翻译: 一种镍氢二次电池,包括主要由氢氧化镍构成的正极的电极组,主要由储氢合金构成的负极和位于正极和负极之间的隔膜,其中电极组密封在电池 壳体和碱性电解质液体,其中在电池中同时存在W元素和Na元素。 本发明的镍氢二次电池不仅在高温环境中具有高活性物质的利用率和优异的自放电特性以及高温环境下的充电效率高的优点, 因为它具有优异的大电流放电特性。

    SYNERGISTIC ADDITIVES FOR ELECTROCHEMICAL CELLS WITH ELECTRODEPOSITED FUEL

    公开(公告)号:EP2971259B8

    公开(公告)日:2018-11-21

    申请号:EP14774202.7

    申请日:2014-03-13

    申请人: NantEnergy, Inc.

    摘要: An embodiment of the invention provides for an electrochemical cell comprising: a fuel electrode comprising a metal fuel, a second electrode, an ionically conductive medium communicating the electrodes, the ionically conductive medium comprising at least two different additives, wherein at least one additive is selected from the group consisting of: macroheterocyclic compounds, phosphonium salts, hetero-ionic compounds and their derivatives; and, at least one additive is selected from the group consisting of: macroheterocyclic compounds, phosphonium salts, hetero-ionic compounds, and their derivatives. The fuel electrode and the second electrode are operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode functioning as an anode, whereby electrons are generated for conduction from the fuel electrode to the second electrode via a load. An ionically conductive medium and methods of operating an electrochemical cell are also disclosed.