摘要:
To provide an axially asymmetric optically active biarylphosphorus compound that can easily produced without the step of optical resolution which was almost indispensable in conventional methods. Solution: A method for producing an axially asymmetric phosphorus compound represented by the general formula (1), comprising a cycloaddition reaction of a compound having a triple bond with the use of a catalyst containing rhodium metal and an optically active bisphosphine.
(In the formula, J is an oxygen atom, a sulfur atom or BH 3 ; R 1 and R 2 independently are an alkyl, cycloalkyl, aryl, alkoxy and aryloxy group; a1 and a2 independently are 0 or 1; R 3 to R 10 independently are an alkyl, cycloalkyl, aryl, alkoxy and aryloxy group; two among R 3 to R 10 may form a ring; and * is axial asymmetry.)
摘要翻译:提供一种轴向不对称光学活性联芳基磷化合物,其可以容易地制备而无需在常规方法中几乎不可缺少的光学拆分步骤。 溶液:用于制备由通式(1)表示的轴向不对称磷化合物的方法,其包括具有三键的化合物与使用含铑金属和光学活性双膦的催化剂的环加成反应。 (式中,J为氧原子,硫原子或BH 3; R 1和R 2分别为烷基,环烷基,芳基,烷氧基和芳氧基; a1和a2分别为0或1; R 3〜R 10独立地是烷基,环烷基,芳基,烷氧基和芳氧基; R 3至R 10中的两个可以形成环;并且*是轴不对称的)
摘要:
The present invention provides a drill for making a dilled hole having a high circularity. The axial asymmetric edge drill has a chisel portion formed in the tip center so that the chisel portion center matches with the drill shaft center. At least one of the cutting edges is in an axial asymmetric position with another cutting edge across the drill shaft center. The outline of the edges of the drill forms a circular arc.
摘要:
Disclosed is a flame-retardant resin processed article having excellent flame retardance while being free from bleed-out. Specifically, a resin composition containing a cyclic phosphorus compound flame retardant, a hydrophilic silica powder having an average particle diameter of not more than 15 m, and a resin with the total content of the cyclic phosphorus compound and the hydrophilic silica powder being 10-45% by mass is molded into a certain shape or formed into a coating film. The hydrophilic silica powder is preferably composed of porous structures having a pore volume of not more than 1.8 ml/g and a pH of 4-7. More preferably, the hydrophilic silica powder has an oil absorption of not less than 50 ml/100 g in accordance with JIS K5101.
摘要:
The present invention provides a method for producing a biofuel that allows an animal/vegetable fat/oil raw material containing a free fatty acid to react with a lower alcohol in the presence of a solid acid catalyst, in which the consumption of the lower alcohol is reduced and the free fatty acid and the lower alcohol are selectively esterified to reform the animal/vegetable fat/oil. In this method, as a solid acid catalyst is used a catalyst selected from an SiO 2 /Al 2 O 3 solid acid catalyst, an SiO 2 /Al 2 O 3 solid acid catalyst with aluminum being partially introduced into mesoporous silica, an Al 2 O 3 /B 2 O 3 solid acid catalyst, and a sulfated zirconia solid acid catalyst, with a molar ratio of the free fatty acid and the lower alcohol of 1 to 6.
摘要:
An epitaxial growing method in which a crystal of AlxGa1-xN wherein x is a desirable constituent ratio can be grown on an Si substrate or sapphire substrate according to the HVPE process. Crystal of AlxGal-xN is grown according to the HVPE process in which use is made of an aluminum material, a gallium material, an ammonia material and a carrier gas. The carrier gas consists of an inert gas and hydrogen, and the partial pressure of hydrogen is set so as to range from 0 to
摘要:
Problem] To provide a technique whereby, in cultivating a crop, factors relating to differentiation into flower buds and leaf buds, sprouting, flowering and fruiting, growth of young shoots, etc., are regulated. For example, the invention addresses the problem of regulating the growth of a crop so that leaf buds sprout in tandem with the sprouting of flower buds and flowering and fruiting are repeated under fresh foliage. [Solution] A plant cultivation method which comprises environmentally stimulating a plant to regulate differentiation into flower buds and/or differentiation into leaf buds. In a typical embodiment, the plant is held in an environment at a temperature of 16-40°C at a photoperiod of 8-13 hours immediately after harvesting fruits. As another environmental stimulus, the plant is held in, for example, an environment at a temperature of 3-7°C. As still another environmental stimulus, the plant is held in, for example, an environment a temperature of 16-23°C at a photoperiod of 8-11 hours.
摘要:
The present invention relates to vitamin D3 derivatives of the following formula, wherein each symbol has the same meaning as defined herein, and pharmaceutical or medical use thereof for treating metabolic disease, liver disease, obesity, diabetes, cardiovascular disease, or cancer in a patient in need thereof.