Axially asymmetric phosphorus compound and production method thereof
    41.
    发明公开
    Axially asymmetric phosphorus compound and production method thereof 审中-公开
    Achsenasymmetrische Phosphorverbindung und Verfahren zu ihrer Herstellung

    公开(公告)号:EP2098531A1

    公开(公告)日:2009-09-09

    申请号:EP09002595.8

    申请日:2009-02-24

    IPC分类号: C07F9/655 B01J31/26

    摘要: To provide an axially asymmetric optically active biarylphosphorus compound that can easily produced without the step of optical resolution which was almost indispensable in conventional methods.
    Solution:
    A method for producing an axially asymmetric phosphorus compound represented by the general formula (1), comprising a cycloaddition reaction of a compound having a triple bond with the use of a catalyst containing rhodium metal and an optically active bisphosphine.

    (In the formula, J is an oxygen atom, a sulfur atom or BH 3 ; R 1 and R 2 independently are an alkyl, cycloalkyl, aryl, alkoxy and aryloxy group; a1 and a2 independently are 0 or 1; R 3 to R 10 independently are an alkyl, cycloalkyl, aryl, alkoxy and aryloxy group; two among R 3 to R 10 may form a ring; and * is axial asymmetry.)

    摘要翻译: 提供一种轴向不对称光学活性联芳基磷化合物,其可以容易地制备而无需在常规方法中几乎不可缺少的光学拆分步骤。 溶液:用于制备由通式(1)表示的轴向不对称磷化合物的方法,其包括具有三键的化合物与使用含铑金属和光学活性双膦的催化剂的环加成反应。 (式中,J为氧原子,硫原子或BH 3; R 1和R 2分别为烷基,环烷基,芳基,烷氧基和芳氧基; a1和a2分别为0或1; R 3〜R 10独立地是烷基,环烷基,芳基,烷氧基和芳氧基; R 3至R 10中的两个可以形成环;并且*是轴不对称的)

    NONAXISYMMETRICAL BLADE DRILL
    42.
    发明公开
    NONAXISYMMETRICAL BLADE DRILL 审中-公开
    非对称叶片钻

    公开(公告)号:EP1992437A1

    公开(公告)日:2008-11-19

    申请号:EP07715142.1

    申请日:2007-02-23

    IPC分类号: B23B51/00

    摘要: The present invention provides a drill for making a dilled hole having a high circularity. The axial asymmetric edge drill has a chisel portion formed in the tip center so that the chisel portion center matches with the drill shaft center. At least one of the cutting edges is in an axial asymmetric position with another cutting edge across the drill shaft center. The outline of the edges of the drill forms a circular arc.

    摘要翻译: 本发明提供了一种用于制造具有高圆度的镗孔的钻头。 轴向不对称刃钻具有形成在尖端中心的凿形部分,使得凿形部分的中心与钻轴中心匹配。 至少一个切削刃处于轴向非对称位置,其中另一切削刃越过钻轴中心。 钻头边缘的轮廓形成一个圆弧。

    PLANT CULTIVATION METHOD
    49.
    发明授权
    PLANT CULTIVATION METHOD 有权
    植物栽培方法

    公开(公告)号:EP2979539B1

    公开(公告)日:2017-12-20

    申请号:EP14776229.8

    申请日:2014-03-20

    IPC分类号: A01G7/00 A01G1/00

    CPC分类号: A01G1/001 A01G7/00 A01G22/00

    摘要: Problem] To provide a technique whereby, in cultivating a crop, factors relating to differentiation into flower buds and leaf buds, sprouting, flowering and fruiting, growth of young shoots, etc., are regulated. For example, the invention addresses the problem of regulating the growth of a crop so that leaf buds sprout in tandem with the sprouting of flower buds and flowering and fruiting are repeated under fresh foliage. [Solution] A plant cultivation method which comprises environmentally stimulating a plant to regulate differentiation into flower buds and/or differentiation into leaf buds. In a typical embodiment, the plant is held in an environment at a temperature of 16-40°C at a photoperiod of 8-13 hours immediately after harvesting fruits. As another environmental stimulus, the plant is held in, for example, an environment at a temperature of 3-7°C. As still another environmental stimulus, the plant is held in, for example, an environment a temperature of 16-23°C at a photoperiod of 8-11 hours.