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    POLY(MERCAPTOPROPYLARYL) CURATIVES
    41.
    发明公开
    POLY(MERCAPTOPROPYLARYL) CURATIVES 审中-公开
    聚（MERCAPTOPROPYLARYL）CURATIVES

    公开(公告)号：EP1185574A2

    公开(公告)日：2002-03-13

    申请号：EP00971971.7

    申请日：2000-03-20

    申请人： LORD CORPORATION

    发明人： ABBEY, Kirk, J.

    IPC分类号： C08G59/66 ,  C08F8/34 ,  C09J163/00 ,  C07C323/12

    CPC分类号： C08G59/66 ,  B33Y70/00 ,  C08F8/12 ,  C08F8/34 ,  C08G59/56 ,  C08L2666/04 ,  C09J163/00 ,  C08F257/00

    摘要： Polyfunctional mercaptoalkyl-substituted aryl compounds, one and two-part adhesive compositions including the compounds, and methods of making and using the compounds are disclosed. The compounds include one or more aromatic rings, wherein at least one, and in one embodiment, only one aromatic ring is substituted with at least one alkylthio group and at least one oxyalkylthio group, and preferably do not include hydrolyzable linkages. The aromatic nucleus can provide the cured products with higher glass transition temperatures (Tg's) than are available from most commercially available polymercaptans. The adhesive systems include an epoxy resin or other compounds such as terminal olefins which are known to react with thiols (polymerizable material). Preferably, the compounds are used in combination with amine curatives as a two-component curing system for epoxy resins. Such a composition provides a two-stage cure which enables very quick achievement of bonded parts with handleable strength at room temperature or below, or with relatively low bake temperatures. The materials can be used for coatings, adhesives, sealants, potting compounds, and the like.

    摘要翻译： 公开了多官能巯基烷基取代的芳基化合物，包含该化合物的一种和两部分粘合剂组合物，以及制备和使用该化合物的方法。 所述化合物包括一个或多个芳环，其中至少一个，并且在一个实施方案中，仅一个芳环被至少一个烷硫基和至少一个氧烷硫基取代，并且优选不包括可水解的键。 芳香核能够为固化产品提供比大多数市售聚硫醇可获得的更高的玻璃化转变温度（Tg's）。 粘合剂体系包括环氧树脂或其他化合物，例如已知与硫醇（可聚合材料）反应的端烯烃。 优选地，这些化合物与胺固化剂一起用作环氧树脂的双组分固化体系。 这样的组合物提供了两阶段固化，其能够在室温或更低的温度下或在相对较低的烘烤温度下非常快速地获得具有可处理强度的粘合部分。 这些材料可用于涂料，粘合剂，密封剂，灌封化合物等。

    CURATIVES FOR EPOXY RESIN, CURING ACCELERATOR, AND EPOXY RESIN COMPOSITION
    43.
    发明公开
    CURATIVES FOR EPOXY RESIN, CURING ACCELERATOR, AND EPOXY RESIN COMPOSITION 失效
    EPOXIDHARZHÄRTER，HÄRTUNGSBESCHLEUNIGERUND EPOXIDHARZZUSAMMENSETZUNG

    公开(公告)号：EP0949286A1

    公开(公告)日：1999-10-13

    申请号：EP97950428.9

    申请日：1997-12-26

    申请人： NIPPON SODA CO., LTD.

    发明人： SUZUKI, Hiroshi Nippon Soda Co., Ltd. ,  AOKI, Izuo Nippon S. Co.,Ltd. ,  ABE, Satoru Nippon S. Co.,Ltd.

    IPC分类号： C08G59/62 ,  C08L63/00

    CPC分类号： C08G59/68 ,  C08G59/18 ,  C08G59/5093 ,  C08G59/56 ,  C08G59/621

    摘要： The present invention has an object to provide curatives for epoxy resins and curing accelerators for epoxy resins, which both have improved subliming and decomposing properties and which, when mixed with an epoxy resin, enable the mixture to be greatly improved in thermal stability that is extremely important for the control of a curing reaction and to have a prolonged pot life (stability as a one-pack mixture comprising the epoxy resin, curative, etc.) and improved curability at low temperatures.
    The curative is characterized by being a clathrate comprising a tetrakisphenol compound represented by a general formula [I];
    wherein X represents (CH 2 )n, wherein n is 0, 1, 2 or 3, and R 1 to R 8 each represents hydrogen, a lower alkyl, optionally-substituted phenyl, halogeno or a lower alkoxy, and the curing accelerator is characterized by being a clathrate comprising a tetrakisphenol compound represented by the general formula [I] shown above and a compound accelerating the curing of a compound which reacts with the epoxy group of an epoxy resin to cure the resin.

    摘要翻译： 本发明的目的是提供用于环氧树脂的固化剂和用于环氧树脂的固化促进剂，它们都具有改进的升华和分解性能，并且当与环氧树脂混合时，能够使混合物的热稳定性大大提高 对于固化反应的控制是重要的，并且具有延长的适用期（作为包含环氧树脂的单组分混合物的稳定性，固化剂等）和在低温下提高的固化性。 固化剂的特征在于包含由通式ÄIÜ表示的四苯酚化合物的包合物; 其中X表示（CH 2）n，其中n为0,1,2或3，R 1至R 8各自表示氢，低级烷基，任选取代的苯基，卤代或低级烷氧基 固化促进剂的特征在于包含由上述通式Ⅳ所示的四苯酚化合物和包含与环氧树脂的环氧基反应的化合物固化以使树脂固化的化合物的包合物。

    Cathodic electrocoat compositions containing self-crosslinking polymers
    47.
    发明公开
    Cathodic electrocoat compositions containing self-crosslinking polymers 失效
    阴极电泳组合物中，含有自交联的聚合物

    公开(公告)号：EP0774497A3

    公开(公告)日：1997-12-10

    申请号：EP96118079.1

    申请日：1996-11-12

    申请人： BASF CORPORATION

    发明人： Harris, Paul J. ,  December, Timothy S.

    IPC分类号： C09D5/44

    CPC分类号： C09D5/4434 ,  C08G59/56

    摘要： Cathodic electrocoat compositions containing self-crosslinking polymers are described. The polymers of the invention are formed from an epoxide-functional prepolymer having polyepoxide and extender segments. Each extender segment has at least one pendant hydroxyalkyl carbamate group. The prepolymer is reacted with an amine compound having at least one blocked primary amine group and at least one epoxide-reactive group. The primary amine group is unblocked and the resultant polymer is dispersed in water with the aid of a neutralizing acid.