摘要:
A binder is described which comprises A) a hydrolysate or heterocondensate of at least one hydrolysable silicon compound and at least one metallic compound, phosphorous compound or boron compound, where the metal is selected from Al, Ge, Sn, Pb, Ti, Mg, Li, V, Nb, Ta, Zr and Hf, B) an organic polymerisable or polycondensable monomer or oligomer and C) a buffer, such that the pH of the buffered binder is in the range from 2 to 7, and optionally a complexing agent, where optionally the at least one hydrolysable silicon compound comprises one or more hydrolysable silicon compounds with at least one non-hydrolysable group or oligomers thereof. The binder is suitable for consolidating loose or unconsolidated substrates.
摘要:
The invention relates to a method for the treatment of rock formations which may or may not be underground and, more particularly, of oil or gas production wells, water-injection wells intended to flood hydrocarbon (oil or gas) reservoirs or gas mines or gas storage wells. The invention is characterized in that it includes a step comprising the injection, into said rock formation or well, of a microgel obtained by dilution in water of a self-invertible inverse latex or of a self-invertible inverse microlatex of a crosslinked polyelectrolyte, obtained by copolymerization, in the presence of a crosslinking agent of partially- or totally-salified free 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid, with at least one cationic monomer chosen from: 2,N,N,N-tetramethyl-2-[(1-oxo-2-propenyl)amino]propanammonium chloride; N,N,N-trimethyl-3-[(1-oxo-2-propenyl)amino]propanammonium chloride; diallyldimethylammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-propenyl)]ethanammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-methyl-2-propenyl)]ethanammonium chloride; or N,N,N-trimethyl-3-[(1-oxo-2-methyl-2-propenyl)amino]propanammonium chloride; and with at least one neutral monomer chosen from: acrylamide; N,N-dimethylacrylamide; N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]propenamide; or 2-hydroxyethyl acrylate.
摘要:
Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.
摘要:
Particulate material eg. sand (20) is continuously coated with a consolidatable resin composition (26) and formed as a suspension in a gelled aqueous carrier liquid (10) for transport (42) to a subterranean zone in which the sand is consolidated. In the method, substantially continuous streams of a gelled aqueous carrier liquid (10), uncoated particulate material (20), a resin composition (24) which will subsequently harden, and a surface active agent (16), are mixed (14) whereby the particulate material is continuously coated with the resin composition and simultaneously suspended in the gelled aqueous carrier liquid.
摘要:
A method of preventing or reducing the migration of fines in a permeable subterranean formation, comprising: contacting said fines in said subterranean formation with an effective amount of an organic copolymer having recurring structural monomer units formed in a random fashion of the formula:
wherein R' and R 4 are independently each an alkylene group having 1 to about 4 carbon atoms; R 2 , R 3 , R 5 , R 6 , and R 7 are independently each either methyl or ethyl; A is chloride, bromide, iodine, hydroxide or methyl sulfate; s is an integer equal to the number of anions required to maintain electronic neutrality; x, y, and z are integers, the sum of which equals the total number of monomer units in the copolymer required to give a molecular weight in the range of from about 100,000 to about 1,500,000; and monomer unit I is present in the range of from about 80 to about 98 percent by weight of the copolymer; monomer unit II is present in the range of from about 2 to about 20 percent by weight of the copolymer; and, monomer unit III is present in the range of from about 0 to about 20 percent by weight of the copolymer.
摘要:
The instant invention relates to a process allowing the encapsulation of a polymerization accelerator, said process comprising the steps of: a) providing an reverse emulsion containing, in an oil phase, a water solution/dispersion containing the polymerisation activator, the oil phase including a heat curable mixture of an isocyanate and a polyalkyldiene hydroxylated or polyol, b) pouring the reverse emulsion in a water phase to make a multiple emulsion water/oil/water, containing drops of activators as the internal water phase, and then, c) heating the multiple emulsion obtained in step b) at a temperature of between 50 and 95°C, in order to cure the polyisocyanate in polyurethane and obtain drops of activator enclosed in shells of polyurethane dispersed in water. The invention also relates to aqueous gelling systems comprising the encapsulated polymerization accelerator with water soluble or dispersable monomers and a polymerization initiator dispersed in said monomers, usefull i.a. for sealing subterranean environments or consolidation of a soil or sealing of a subterranean structure.
摘要:
An aggregating composition for altering surface properties including reaction products of amines, polyamines, and/or amine polymers and acidic hydroxyl containing compounds and/or Lewis acids, or mixtures and combinations thereof, where the compositions form partial or complete coatings on solid materials altering an aggregating propensity and/or zeta portion of the surfaces for downhole operations. A method for treating solid materials including contacting the materials with the aggregating composition in downhole operations. Treated solid materials including partial or complete coating comprising the aggregating composition for use in downhole operations.
摘要:
Systems and methods for treating formation intervals including forming a low permeability layer on a surface of the interval and pumping a sand control treating solution through the layer, which diverts the flow into the formation permitting improved treatment uniformity and improved overall internal treatment.