PROCESS FOR PRODUCING 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE AND 1,1,1,4,4,4,-HEXAFLUOROBUTANE
    52.
    发明公开
    PROCESS FOR PRODUCING 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE AND 1,1,1,4,4,4,-HEXAFLUOROBUTANE 失效
    生产1,1,1,4,4,4-六氟-2-丁烯和1,1,1,4,4,4, - 六氟丁烷的方法

    公开(公告)号:EP0670295A1

    公开(公告)日:1995-09-06

    申请号:EP94900280.2

    申请日:1993-11-18

    摘要: 1,1,1-Trifluoro-2,2-dichloroethane is reacted with metallic copper and an amine to give 1,1,1,4,4,4-hexafluoro-2-butene, which is further reacted with hydrogen to give 1,1,1,4,4,4,-hexafluorobutane. This process facilitates the production of not only 1,1,1,4,4,4-hexafluorobutane which is used as a refrigerant, blowing agent or cleaning agent and contributes to the environmental protection, but also 1,1,1,4,4,4-hexafluoro-2-butene which is useful as an intermediate for the above butane and as a monomer of a fluoropolymer in a high yield.

    摘要翻译: 使1,1,1-三氟-2,2-二氯乙烷与金属铜和胺反应,得到1,1,1,4,4,4-六氟-2-丁烯,将其进一步与氢反应,得到1 ,-1,1,4,4,4-,-hexafluorobutane。 这种方法不仅有利于生产用作制冷剂,发泡剂或清洁剂并有助于环境保护的1,1,1,4,4,4-六氟丁烷,而且还有助于1,1,1,4,4,4-六氟丁烷, 作为上述丁烷的中间体和作为含氟聚合物的单体高收率地使用的4,4-六氟-2-丁烯。

    Halocarbon hydrogenolysis
    54.
    发明授权
    Halocarbon hydrogenolysis 失效
    一种卤烃的氢解过程。

    公开(公告)号:EP0495892B1

    公开(公告)日:1995-07-19

    申请号:EP90915920.4

    申请日:1990-10-09

    IPC分类号: C07C17/00

    CPC分类号: C07C17/23

    摘要: Halocarbons such as CCl2F2, CF3CFHCl or CF3CFCl2 which contain chlorine and/or bromine are contacted with hydrogen in the presence of silicon carbide and/or a metal selected from aluminum, molybdenum, titanium, nickel, iron or cobalt (or their alloys) at temperatures of 350° to 700 °C and pressures of 0 to 1000 psig to obtain a product wherein at least one chlorine or bromine in the starting material has been replaced by hydrogen.

    PROCESS FOR PRODUCING 1,1,1,2,3-PENTAFLUOROPROPANE
    55.
    发明公开
    PROCESS FOR PRODUCING 1,1,1,2,3-PENTAFLUOROPROPANE 失效
    VERFAHREN ZUR HERSTELLUNG VON 1,1,1,2,3,-PENTAFLUORPROPAN。

    公开(公告)号:EP0658531A1

    公开(公告)日:1995-06-21

    申请号:EP94908814.0

    申请日:1993-08-09

    IPC分类号: C07C19/08 C07C17/00 B01J23/40

    CPC分类号: C07C17/00 C07C19/08

    摘要: A process for producing 1,1,1,2,3-pentafluoropropane which comprises hydrogenating 1,2,3,3,3-pentafluoro-1-chloropropene with hydrogen in vapor phase in the presence of a noble metal catalyst. This process serves to produce readily at a low cost 1,1,1,2,3-pentafluoropropane, which is useful and does not cause environmental destruction (i.e. is capable of environmental protection), from an inexpensive starting material in one stage.

    摘要翻译: 一种生产1,1,1,2,3-五氟丙烷的方法,该方法包括在贵金属催化剂存在下,使氢气在氢气中氢化为1,2,3,3,3-五氟-1-氯代丙烯。 该方法易于以低成本生产1,1,1,2,3-五氟丙烷,其在一个阶段从廉价的起始材料是有用的并且不引起环境破坏(即能够环境保护)。