Abstract:
Disclosed are a silicate-based foamed material which has a density of less than 25 kg/m3, an SiO2:Al2O3 molar ratio of more than 20:1, and an SiO2:Me2O molar ratio of more than 50:1, wherein Me represents an alkali metal, the use thereof for heat insulation or sound-proofing purposes, and methods for the production thereof by mixing a dispersion of SiO2 particles that have an average diameter ranging from 1 to 100 nm with a surfactant and a foaming agent at temperatures below 50 °C and expanding said mixture by heating the same to a temperature ranging from 60 to 100 °C or by relieving the pressure.
Abstract translation:公开了密度小于25kg / m 3,SiO 2 :Al 2 O 3摩尔比大于20:1,SiO 2 :Me 2 O摩尔比大于50:1的硅酸盐基发泡材料,其中Me代表 碱金属,其用于隔热或隔音的目的,以及通过将平均直径为1-100nm的SiO 2颗粒的分散体与表面活性剂和发泡剂在低于200℃的温度下混合来生产它们的方法 50℃并且通过将所述混合物加热至60至100℃的温度或通过释放压力来膨胀所述混合物。
Abstract:
The present invention relates to a process for the preparation of compounds of general Formula (I) Li a-b M 1 b Fe 1-c M 2 c P d-e M 3 e O x (I), wherein Fe has the oxidation state +2 and M 1 , M 2 , M 3 , a, b, c, d, e and x are: M 1 :Na, K, Rb and/or Cs, M 2 :Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M 3 :Si, S, F a:0.8 - 1.9, b:0 - 0.3, c:0 - 0.9, 15 d:0.8 - 1.9, e:0 - 0.5, x:1.0 - 8, depending on the amount and oxidation state of Li, M 1 , M 2 , P, M 3 , wherein compounds of general Formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M 1 -comprising compound, if present, and/or at least one M 2 -comprising compound, if present, and/or least one M 3 -comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500 °C and at an autogeneous pressure to reduce Fe to oxidation state +2 and to obtain a compound of general Formula (I).
Abstract:
The present invention relates to a method for separating an at least one first substance from a mixture containing said first substance and at least a second substance, comprising the steps of: (A) bringing at least one magnetic particle and at least one bifunctional molecule, or an adduct of the two, into contact with the mixture containing the at least one first substance and at least a second substance so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first substance, (B) suspending the adduct obtained in step (A) in a suitable suspension agent, (C) separating the adduct present in the suspension of step (B) by applying a magnetic field, (D) optionally splitting the adduct separated in step (C) to obtain the at least one first substance, a corresponding adduct and the use of such an adduct for separating mixtures of substances.
Abstract:
The present invention relates to processes for producing surface-modified nanoparticulate copper compounds and also for producing aqueous suspensions containing surface-modified nanoparticulate copper compounds. The invention further relates to the surface-modified nanoparticulate copper compounds which can be obtained by these processes and aqueous suspensions of these copper compounds and also their use as antimicrobial agent or catalyst.
Abstract:
The present invention relates to a Process for the preparation of compounds of general formula (I), Li a-b M 1 bFe 1-c M 2 c P d-e M 3 e O x , wherein M 1 , M 2 , M 3 , a, b, c, d and e: M 1 : Na, K, Rb and/or Cs, M 2 : Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M 3 : Si, S, a: 0.8 - 1.9, b: 0 - 0.3, c: 0 - 0.9, d: 0.8 - 1.9, e: 0 - 0.5, x: 1.0 - 8, depending on the amount and oxidation state of Li, M 1 , Fe, M 2 , P, M 3 , wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M 1 -comprising compound, if present, and/or at least one M 2 -comprising compound, if present, and/or least one M 3 -comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, (B) optionally drying the mixture provided in step (A), in order to obtain a solid compound and (C) calcining the solid compound obtained from step (A) or (B) at a temperature of 300 to 1000° C.
Abstract:
The present invention relates to a method for producing cosmetic preparations containing metal oxide, wherein the reaction mixture developing during the production of the particulate metal oxide is added to the cosmetic preparations substantially without further processing.
Abstract:
The invention relates to a novel polynary metal oxide phosphate of general formula MaV4-aOb(PO4)c (I), wherein M represents one or more metals selected from the group including Ti, Zr, Hf,Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, B, Al, Ga and In, a has a value of 0 to 2.0, b has a value of 2.0 to 4.0, c has a value of 2.0 to 4.0, said novel compound having a crystal structure and being characterized by defined diffraction reflexes in powder X-ray diffraction. Preferred representatives are V4O3(PO4)3, CrV3O3(PO4)3, FeV3O3(PO4)3 and TiV3O3(PO4)3. The metal oxide phosphates are suitable as gas phase oxidation catalysts, e.g. for producing maleic anhydride from a hydrocarbon with at least four carbon atoms.
Abstract:
The invention relates to a novel polynary vanadyl pyrophosphate of general formula (VO)a(M1-bVb)2(P2O7)c (I), wherein M represents one or more metals selected from the group including Ti, Zr, Hf, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, B, Al, Ga and In, a has a value of 0.5 to 1.5, b has a value of 0 to 0.9, c has a value of 1.5 to 2.5, said novel compound having a crystal structure and being characterized by defined diffraction reflexes in powder X-ray diffraction. A preferred representative is (VO)Fe2(P2O7)2. The vanadyl pyrophosphates are suitable as gas phase oxidation catalysts, e.g. for producing maleic anhydride from a hydrocarbon with at least four carbon atoms.
Abstract:
The invention relates to a novel polynary metal oxide phosphate of general formula Ma(VO)(P2O7)b(PO4)c (I), wherein M represents one or more metals selected from the group including V, Ti, Zr, Hf, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, Cd, Hg, B, Be, Mg, Ca, Sr and Ba, a has a value of 1.5 to 2.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, said novel compound having a crystal structure and being characterized by defined diffraction reflexes in powder X-ray diffraction. A preferred representative is Fe2VO(P2O7)(PO4). The metal oxide phosphates are suitable as gas phase oxidation catalysts, e.g. for producing maleic anhydride from a hydrocarbon with at least four carbon atoms.