摘要:
The present invention provides a novel modified stannic oxide - zirconium oxide complex sol and a preparation method thereof, particularly a stable sol which contains 2-50% by weight of total metal oxides comprising modified colloidal particles of a stannic oxide - zirconium oxide complex having a particle diameter having 4.5-60 nm, wherein the particles are formed by coating complex colloidal particles of a stannic oxide - zirconium oxide having a bonded structure of stannic oxide colloidal particles and zirconium oxide colloidal particles at a ZrO2/SnO2 ratio of 0.02-1.0 based on weights of these oxides and having a particle diameter of 4-50 nm as nuclei, with colloidal particles of a tungsten oxide - stannic oxide - silicon dioxide complex having such a constitution that a WO3/SnO2 weight ratio is 0.1-100, that a SiO2/SnO2 weight ratio is 0.1-100 and having a particle diameter of 2-7 nm, and preparation method thereof.
摘要:
A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.
摘要:
The invention relates to a method for forming a transparent conductive thin film of In 2 O 3 -SnO 2 on a surface of a plastics substrate of less heat resistance other than that of glass, ceramics, etc. When an In 2 O 3 -SnO 2 precursor sol is produced by hydrolyzing and polymerizing a solution containing indium alkoxide and tin alkoxide, either tri-s-butoxyindium or tri-t-butoxyindium is used as the indium alkoxide. water is added to the solution containing indium alkoxide and tin alkoxide at a temperature of not higher than -20°C. The obtained In 2 O 3 -SnO 2 precursor sol is applied to a surface of a substrate to form a gel film, then the gel film is either irradiated with an ultraviolet beam of which wave length is not longer than 360 nm, or irradiated with an ultraviolet beam of which wave length is not longer than 260 nm and further irradiated with a laser beam of which wave length is not longer than 360 nm, to crystallize the gel forming the thin film, whereby an In 2 O 3 -SnO 2 thin film having a conductivity is formed on the surface of the substrate.
摘要:
A gas phase process for the production of titanium dioxide powders having well-controlled crystalline and surface area characteristics is disclosed. In this process, which is preferably carried out in a laminar diffusion flame reactor, vapor phase TiCl4 and oxygen are mixed in a reaction area which is heated externally. The titanium dioxide powder formed is then collected. It is preferred that the heat source used be a hydrocarbon fueled (e.g., methane) flame. Optionally, a vapor phase dopant (such as SiCl4) may be added to the reaction mixture to desirably affect the physical properties of the titanium dioxide produced. In a particularly preferred embodiment, a corona electric field is positioned across the area where the combustion reaction takes place (i.e., the reaction area). High anatase, high surface area titanium dioxide powders made by this process are excellent photocatalysts. The products of this process and the use of those products as photocatalysts are also disclosed. This process is also useful for producing other ceramic powders (such as silicon dioxide and tin oxide), as well as pure metallic or alloy powders.
摘要:
In this process, high-purity tin tetrachloride is produced from metallic tin and chlorine in a single reaction chamber. This is done by dissolving gaseous or liquid chlorine in circulating liquid tin tetrachloride. This solution is then passed into the bottom of a vertical tubular reactor containing loosely packed granulated tin. About half-way up the granulated-tin column, the tin tetrachloride is taken out of the reactor in order to increase the chlorine concentration and recycle it into the reactor. At the same time, the heat of reaction contained in the liquid tin tetrachloride can be extracted using a heat exchanger.
摘要:
The invention relates to a method for preparing particles of metal oxide, as well as particles obtained by such method. The method consists in: precipitating a hydroxide, adding an inorganic compound such as a salt having a melting point lower than the oxide crystallization temperature, and heating the hydroxide and the salt at a high temperature. An oxide in the form of a fine powder is obtained, thus particularly allowing to perform thin conductive layers.
摘要:
Herstellung von feinteiligen Zinndioxidpulvern durch Gasphasenzersetzung von flüchtigen Zinnverbindungen, indem man zinnorganische Verbindungen oxidativ zersetzt.