摘要:
A thermoplastic elastomer composition which comprises a mixture (F) comprising 100 parts by weight of a mixture (C) essentially consisting of 24 - 80 parts by weight of an oil-extended olefinic copolymer rubber (A) and 20 - 76 parts by weight of an olefinic plastic (B); said oil-extended olefinic copolymer rubber (A) comprising 100 parts by weight of an olefinic copolymer rubber (a) having a Mooney viscosity (ML₁₊₄ 100°C) of 90 - 200 and a propylene content of 10 - 60 % by weight and 20 - 60 parts by weight of a mineral oil softener (b), and 0.1 - 3 parts by weight of a bismaleimide compound (D), said mixture (F) being dynamically heat-treated in the presence of an organic peroxide (E). The thermoplastic elastomer composition has excellent injection moldability and mat appearance. In the production of the thermoplastic elastomer composition, kneading is easy to carry out and a time required for the kneading is considerably reduced.
摘要:
An amorphous copolymer which has at least constituting units derived from ethylene and alpha-olefin and an average particle size of 0.2 to 50 mum, and in which 15 wt % or more crosslinking bonds are formed as hot toluene insolubles.
摘要:
A fine particulate crosslinked amorphous copolymer comprising an amorphous copolymer having a constituent unit originating at least from ethylene and a-olefin, and having an average particle diameter of 0.2 to 50 µm and a hot toluene insolubles content of 15% by weight or more.
摘要:
An olefin copolymer rubber graft composition having a viscoelastic performance index of not greater than 100 as defined by the expression where DS is the die swell of the composition, MV is the melt viscosity of the composition and i.v. is the intrinsic viscosity of a resinous portion extracted from the composition.
摘要:
The present invention relates to a process for modifying a post-consumer recycled polyolefin composition comprising the steps of (A) providing a post-consumer recycled polyolefin composition having a starting melt flow rate MFR 2 (1), determined according to ISO 1133 at 2.16 kg load, 230 °C, in the range of from 1.0 to 100 g/10 min, and comprising, based on the total weight of the post-consumer recycled polyolefin composition, determined by FTIR spectroscopy, (a) at least 50 wt.-% of one or more propylene (co)polymer component(s) and (b) up to 50 wt.-% of one or more ethylene (co)polymer component(s); (B) adding 0.10 to 1.50 wt.-%, based on the total weight of the post-consumer recycled polyolefin composition, of a radical initiator to the post-consumer recycled polyolefin composition and optionally mixing the components to form a mixture (1); (C) adding 0.05 to 0.50 wt.-%, based on the total weight of the post-consumer recycled polyolefin composition, of a twofold unsaturated hydrocarbon compound having the general formula (1) CH 2 =CH-(R)-CH=CH 2 , wherein R may be present or absent, and if being present, R is an aliphatic or aromatic hydrocarbon group comprising from 1 to 6 carbon atoms, and mixing the components to form a mixture (2); and (D) extruding the mixture (2) at a temperature in the range of from 180 to 300 °C to obtain a modified polyolefin composition having a final melt flow rate MFR 2 (2), determined according to ISO 1133 at 2.16 kg load, 230 °C; wherein the ratio of MFR 2 (2) : MFR 2 (1) is below 1.00. The present invention also relates to a modified polyolefin composition obtained by the process, as well as to the use of the modified polyolefin composition in the manufacture of an article, and to a respective article.