POLYMERPULVER MIT COPOLYMER, VERWENDUNG IN EINEM FORMGEBENDEN VERFAHREN MIT NICHT FOKUSSIERTEM ENERGIEEINTRAG UND FORMKÖRPER, HERGESTELLT AUS DIESEM POLYMERPULVER
    61.
    发明公开

    公开(公告)号:EP1720930A1

    公开(公告)日:2006-11-15

    申请号:EP04804856.5

    申请日:2004-12-15

    Applicant: DEGUSSA AG

    Abstract: The invention relates to a polymer powder comprising a copolymer, to the use of said powder in a shaping method and to moulded bodies that are produced from said polymer powder. The shaping methods are methods that operate layer by layer using a powder and during said methods areas of each layer are fused by the non-focussed application of electromagnetic energy. Selectivity can be achieved in a masking process, by the application of inhibitors, absorbers, or susceptors, without restricting the invention to the use of these substances. The inventive powder is preferably used in methods, in which selectivity is achieved by the application of inhibitors or susceptors or in a masking method. Once cooled, the solidified moulded bodies can be removed from the powder bed. The component characteristics of the moulded bodies that have been produced using the inventive powder according to the inventive method, in particular the mechanical and thermal component characteristics, can be varied within a wide range, depending on their composition, in comparison to moulded bodies produced from conventional powders. For amorphous copolymers in particular, the flow behaviour for the shaping method can be optimised by the skilful selection of comonomers. An additional advantage is that processing can also be simplified by the skilful composition of the copolymer. It is possible to conduct the processing at lower temperatures, which simplifies the temperature control and accelerates said processing. The slower crystallisation of semi-crystalline polymers in comparison to semi-crystalline homopolymers promotes the coalescence of the fused particles and leads to improved shrinkage behaviour in the moulded bodies.

    Abstract translation: 本发明涉及通过一层接一层的过程包括通过非聚焦引入电磁能的respectivement粉状层的选择性地熔融区域生产模制品,使用聚合物粉末的方法,worin所述粉末包括至少一种热塑性无规共聚物 用在从12到1克/ 10分钟的ISO 1133 MFR值。

    POLYMERIZATION CATALYSTS FOR POLYESTERS
    65.
    发明授权
    POLYMERIZATION CATALYSTS FOR POLYESTERS 有权
    该聚酯聚合催化剂

    公开(公告)号:EP1060207B1

    公开(公告)日:2004-08-11

    申请号:EP99909773.6

    申请日:1999-03-02

    CPC classification number: B01J31/0212 C08G63/83 C08G63/84 C08G63/85 C08G63/87

    Abstract: The application provides polymerization catalysts for the condensation of polyesters. The catalyst is in the form of a clear chlorine and/or bromine containing solution of a metal glycoxide and a metal glycolate having a pH in the range of from 0 to about 1, and containing chlorine and/or bromine atoms at a number ratio of chlorine and/or bromine to total metal cations in the catalyst ranging from about 0.5:1 to about 3:1. Polyesters produced with this catalyst have good melt elasticity, and good melt viscosity. The former property is desirable for the preparation of large and complex shaped polyester containers, and the latter property is desirable for melt spinning of industrial grade fibers and tire cords.

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