ESTERQUAT ACIDIC SUBTERRANEAN TREATMENT FLUIDS AND METHODS OF USING ESTERQUATS ACIDIC SUBTERRANEAN TREATMENT FLUIDS
    73.
    发明公开

    公开(公告)号:EP1718713A2

    公开(公告)日:2006-11-08

    申请号:EP05708363.6

    申请日:2005-02-15

    IPC分类号: C09K3/00

    摘要: The present invention relates to acidic treatment fluids that comprise an acid fluid and an ester-containing quaternary ammonium compound ('esterquat') and methods of their use. One embodiment of the present invention provides a method of inhibiting metal corrosion during a subterranean treatment operation comprising using an acidic treatment fluid comprising an acidic fluid and an esterquat. Another embodiment of the present invention provides a method of reducing sludge formation during a subterranean treatment operation formation comprising the step of using an acidic treatment fluid comprising an acidic fluid and an esterquat. Another embodiment of the present invention provides a method of inhibiting the formation of emulsions during a subterranean treatment operation comprising using an acidic treatment fluid comprising an acidic fluid and an esterquat. Another embodiment of the present invention provides an acidic subterranean treatment fluid comprising an acidic fluid and an esterquat.

    IMPROVED ELECTRON TRANSFER AGENTS IN WELL ACIDIZING COMPOSITIONS AND METHODS
    74.
    发明授权
    IMPROVED ELECTRON TRANSFER AGENTS IN WELL ACIDIZING COMPOSITIONS AND METHODS 有权
    改进的电子转移剂组合物中的酸性孔多相关方法的治疗

    公开(公告)号:EP1366269B1

    公开(公告)日:2006-07-12

    申请号:EP02702557.6

    申请日:2002-03-07

    IPC分类号: E21B43/27 E21B41/02 C23F11/04

    摘要: An acidizing composition and a method of acidizing a hydrocarbon bearing subterranean formation in the presence of ferric ions are provided. The acidizing composition includes a strong mineral acid solution, an electron donor agent, a primary electron transfer agent and a secondary electron transfer agent. The primary electron agent is a source of rhenium ions. The secondary electron transfer agent is a source of iodide ion or iodine. The electron donor agent and primary and secondary electron transfer agents function together to reduce ferric ion present in the mineral acid solution to ferrous ion which in turn prevents ferric hydroxide and/or free sulfur from precipitating out of the solution and reduces the formation of sludge in crude oil in the formation. The particular electron transfer agents used in connection with the invention function with virtually all known electron donor agents.