公开(公告)号：EP2285455A2

公开(公告)日：2011-02-23

申请号：EP09750046.6

申请日：2009-05-06

申请人： Institut National Polytechnique De Toulouse (INPT)

发明人： DENIS, Ghislain ,  DELMAS, Michel

IPC分类号： A62D3/36

CPC分类号： A62D3/36 ,  A62D2101/41 ,  C22B3/10 ,  C22B3/44 ,  C22B7/007 ,  Y02P10/234

摘要： The invention relates to a method for treating an asbestos solid (1), said method comprising at least one hot acid treatment step (4) for treating the asbestos (3) of the asbestos solid (1) at atmospheric pressure with an aqueous solution (5) of hydrochloric acid at a temperature close to the boiling temperature of the aqueous solution (5) of hydrochloric acid, in such a way as to obtain a so-called non-silicic solution (8) of at least one non-silicic constituent of the asbestos (3) in the aqueous solution (5) of hydrochloric acid and a so-called silicic solid (9). Said method is characterised in that the non-silicic solution (8) is subjected to a so-called precipitation treatment (13), wherein a selective precipitation (13) of the cationic species of iron present in said non-silicic solution (8) is carried out.

公开(公告)号：EP1375432A4

公开(公告)日：2004-12-15

申请号：EP02713224

申请日：2002-03-28

申请人： FUJI ELECTRIC CO LTD

发明人： KAWAKAMI KOUJI ,  KITAIDE YUJIRO ,  KATO NOBUHISA

IPC分类号： A62D3/00 ,  A62D3/13 ,  A62D3/176 ,  A62D3/34 ,  A62D3/36 ,  A62D3/38 ,  A62D101/22 ,  A62D101/28 ,  B01J19/10 ,  B01J19/12 ,  C02F1/32 ,  C02F1/36 ,  C02F1/66 ,  C02F1/72 ,  D06F43/08

CPC分类号： B01J19/123 ,  A62D2203/10 ,  B01J19/10 ,  B01J2219/00015 ,  B01J2219/00038 ,  B01J2219/0004 ,  B01J2219/00137 ,  B01J2219/0877 ,  C02F1/325 ,  C02F1/36 ,  C02F1/66 ,  C02F1/722 ,  C02F2101/322 ,  C02F2101/36 ,  C02F2101/363 ,  C02F2101/366 ,  C02F2103/06 ,  C02F2201/3227 ,  C02F2201/3228 ,  C02F2209/02 ,  C02F2209/06

摘要： The invention provides a method and device for decomposing environmental pollutants, capable of decomposing organic halogen compounds, etc., which are environmental pollutants in a short time and in large quantities to such a low concentration degree that allows them to be discharged as drainage into a sewage pipe or the like and also capable of decomposing organic substances, nitrogen, phosphorous, etc., which are hard to oxidation-decompose. To a sample solution (20) in a reaction vessel (10a) storing an aqueous solution containing environmental pollutants, a vibrator (30a) placed on the central bottom of the reaction vessel (10a), for example, radiates ultrasonic waves (50), and at the same time, ultraviolet lamps (40a) disposed on the peripheral edge within the reaction vessel (10a) radiate ultraviolet rays. On this occasion, the ultraviolet lamps (40a) are disposed at positions where they substantially do not interfere with the path of travel of ultrasonic waves (50).

公开(公告)号：EP0946446A4

公开(公告)日：2000-11-15

申请号：EP97932336

申请日：1997-07-07

申请人： GRACE W R & CO

发明人： BLOCK JACOB

IPC分类号： E04G23/02 ,  A62D3/00 ,  A62D3/35 ,  A62D3/36 ,  A62D101/41 ,  B09B3/00 ,  C04B14/40 ,  C04B41/45 ,  C04B41/60 ,  C01B33/22 ,  C01B33/24 ,  C01F5/00 ,  C01F11/00

CPC分类号： A62D3/36 ,  A62D2101/41 ,  B09B3/0066 ,  C04B14/40 ,  C04B41/4556 ,  Y10S588/901

摘要： A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30 % by weight of an inorganic acid, and from about 0.1 to about 4 % by weight of a tetrafluoroborate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition is also disclosed.

公开(公告)号：EP0914877A4

公开(公告)日：1999-09-08

申请号：EP98901491

申请日：1998-01-29

申请人： KURITA WATER IND LTD

发明人： MIYATA HIROSHI ,  FUJIYOSHI NAOAKI ,  IZUMIKAWA HIROFUMI ,  MASHIKO MITSUHIRO ,  FUJIWARA NOBORU

IPC分类号： A62D3/36 ,  A62D101/08 ,  A62D101/22 ,  A62D101/28 ,  B01D53/70 ,  B09B3/00 ,  A62D3/00 ,  B01D53/34

CPC分类号： A62D3/36 ,  A62D2101/08 ,  A62D2101/22 ,  A62D2101/28 ,  B01D53/70

摘要： A method of decomposing and removing dioxins from fly ash at a lower temperature in a short time, which comprises contacting the dioxins or the substance containing the dioxins with an amine compound and/or an ammonium compound at a temperature below 300 DEG C. Since the chlorine in the dioxins reacts with the amine compound and/or ammonium compound, the dechlorination of the dioxins proceeds rapidly at a lower temperature. Thus, dioxins can be decomposed and removed in a short time at a low temperature at which dioxins have not been thought to be decomposable.

公开(公告)号：EP0880378A4

公开(公告)日：1999-03-24

申请号：EP96945920

申请日：1996-10-10

申请人： COMMODORE APPLIED TECHNOLOGIES

发明人： ABEL ALBERT E ,  MOUK ROBERT W ,  HEYDUK ALAN F ,  BLUM BENTLEY J ,  GETMAN GERRY D ,  STESKAL MARK D

IPC分类号： A62D3/00 ,  A62D3/36 ,  A62D3/37 ,  A62D3/38 ,  A62D101/02 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/28 ,  A62D101/45 ,  B01J19/00 ,  B01J14/00 ,  C02F1/76

CPC分类号： A62D3/38 ,  A62D3/37 ,  A62D2101/02 ,  A62D2101/22 ,  A62D2101/24 ,  A62D2101/26 ,  A62D2101/28 ,  A62D2101/45 ,  A62D2203/02 ,  A62D2203/10 ,  Y10S149/124 ,  Y10S588/90

摘要： Chemical warfare agents are destroyed when chemically reacted with nitrogenous base, optionally containing solvated electrons which are conveniently produced by dissolving an active metal like sodium in a nitrogenous base such as anhydrous liquid ammonia. A reactor system (10) used to carry out the process comprises reaction vessel (20) adapted to receive either nitrogenous base or a solution of solvated electrons from solvator (30) and CWA from storage vessel (40). The reactor system also incorporates condenser (50) for treating gas evolved from the reaction vessel (20), decanter (60) for receiving slurried reaction products from the reaction vessel and separate the reaction products into a liquid fraction and a solid fraction, dissolver (70) for contacting the solid fraction with water to produce a fluid mixture and oxidizer (80) for oxidizing the fluid mixture.

摘要翻译： 分散在世界各地的化学战剂，包括发泡剂和神经药剂在根据本发明的方法化学反应并利用本发明的装置时被破坏。 该方法包括使化学战剂与含氮碱反应，任选地含有溶剂化电子，其通过将诸如钠的活性金属溶解在诸如无水液氨的含氮碱中方便地制备。

公开(公告)号：EP0781174A4

公开(公告)日：1999-01-20

申请号：EP95934971

申请日：1995-09-12

申请人： COMMODORE APPLIED TECHNOLOGIES

发明人： MOUK ROBERT W ,  HEYDUK ALAN F ,  ABEL ALBERT E

IPC分类号： A62D3/34 ,  A62D3/36 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/28 ,  A62D101/43 ,  B09C1/00 ,  B09C1/02 ,  B09C1/08 ,  C22B7/00 ,  C22B43/00 ,  C22B60/02 ,  G21F9/00 ,  G21F9/08 ,  G21F9/12 ,  G21F9/28 ,  G21F9/30 ,  B08B3/04

CPC分类号： C22B60/0247 ,  B09C1/02 ,  C22B7/008 ,  C22B17/04 ,  C22B43/00 ,  G21F9/002 ,  G21F9/30 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/234

摘要： Soil including sand and clays contaminated with nuclear waste materials and/or ions of hazardous non-radioactive metals or metalloids are decontaminated by treating with anhydrous liquid ammonia alone or in combination with solvated electrons. Methods include removing ions of hazardous metals or metalloids by mixing with ammoniacal solutions to provide an ammoniacal liquid-containing product with coordination complexes. Methods also comprise concentrating contaminants, such as plutonium, uranium and thorium, for example, in the fines of soil and clay to yield residual soil products which are sufficiently free of contaminants to allow reclamation. Economics are improved over aqueous systems since ammonia canbe recovered and recycled. By concentrating nuclear and non-nuclear wastes in soil fines space requirements ordinarily needed for storage of untreated soil and handling costs can be significantly reduced.

公开(公告)号：EP0799079A4

公开(公告)日：1998-03-18

申请号：EP95944504

申请日：1995-12-19

申请人： COMMODORE LAB INC

发明人： ABEL MARC W ,  MOUK ROBERT W ,  HEYDUCK ALAN F ,  ABEL ALBERT E

IPC分类号： A62D3/00 ,  A62D3/34 ,  A62D3/35 ,  A62D3/36 ,  A62D101/22 ,  A62D101/26 ,  A62D101/45 ,  B01J19/00 ,  C07C17/23 ,  C07C17/395 ,  C09K5/04 ,  A63D3/00

CPC分类号： A62D3/34 ,  A62D3/35 ,  A62D3/36 ,  A62D2101/22 ,  A62D2101/45 ,  A62D2203/02 ,  C07C17/23 ,  C07C17/395 ,  C09K5/044

摘要： Ozone depleting fluorocarbon compounds (18) are dehalogenated through more economic reduction reaction with solvated electrons formed from lower equivalents of reactive metals (14) than previously used by reacting the partial reduction products with nitrogen-containing bases, such as ammonia (12) or alternatively, without any reactive metal by reacting with the base alone. Mixtures of fluorocarbon refrigerants including difficult-to-separate azeotropes of dichlorodifluoromethane contaminated with clorodifluoromethane are reclaimed by treating only with weak non-aqueous nitrogen-containing bases to provide essentially chemically pure dichlorodifluoromethanerefrigerant suitable for recycling/reuse. Hazardous cyanides which may develop are converted to relatively benign products during the process by introducing a base (22) to convert volatile cyanides to more stable salts which in turn are converted to useful compounds of lesser toxicity.

摘要翻译： 消耗臭氧的碳氟化合物通过更多的经济还原反应被脱卤反应，与由反应性金属的较低当量形成的溶剂化电子比先前通过使部分还原产物与含氮碱（例如氨）反应所使用，或者通过与 单独的基地。 包括难以分离被二氯二氟甲烷污染的氯代二氟甲烷共沸物的氟碳制冷剂的混合物只能用弱的非水性含氮碱处理，以提供基本上化学纯的二氯二氟甲烷制冷剂，适用于再循环/再利用。 通过引入碱将挥发性氰化物转化为更稳定的盐，而这些盐转化成毒性较小的有用化合物，可能会在生产过程中将有害的氰化物转化成相对良性的产物。

公开(公告)号：EP0749339A4

公开(公告)日：1998-03-18

申请号：EP95911876

申请日：1995-02-22

申请人： COMMODORE LAB INC

发明人： MOUK ROBERT W ,  ABEL ALBERT E

IPC分类号： A62D3/00 ,  A62D3/34 ,  A62D3/35 ,  A62D3/36 ,  A62D3/38 ,  A62D101/22 ,  A62D101/26 ,  A62D101/45 ,  B01J19/00 ,  C07C17/23 ,  C07C17/395 ,  C09K5/04

CPC分类号： A62D3/36 ,  A62D3/34 ,  A62D3/35 ,  A62D2101/22 ,  A62D2101/45 ,  A62D2203/02 ,  C07C17/23 ,  C07C17/395 ,  C09K5/044

摘要： Ozone depleting fluorocarbon compounds are dehalogenated through more economic partial reduction reactions with solvated electrons formed from lower equivalents of reactive metals than previously employed. The partially reduced products are further dehalogenated with non-aqueous liquid nitrogen-containing bases, such as ammonia in the same reaction mixture, or alternatively, in an independent reaction by treating with ammonia or other base alone. In other embodiments, mixtures of fluorocarbon refrigerants including difficult to separate azeotropes of dichlorodifluoromethane contaminated with chlorodifluoromethane are reclaimed by treating only with weak non-aqueous nitrogen-containing bases to provide essentially chemically pure dichlorodifluoromethane refrigerant suitable for recycling/reuse.

公开(公告)号：EP0657189A4

公开(公告)日：1995-08-23

申请号：EP94918552

申请日：1994-06-23

申请人： PROD DEV RES INST ,  MITSUI BUSSAN ,  NEOS KK

发明人： TANIMOTO FUMIO MUROMACHI-SUKAI ,  YANO TSUNEO

IPC分类号： A62D3/36 ,  A62D101/22 ,  C07B35/06 ,  C07B63/02 ,  A62D3/00 ,  B09B3/00

CPC分类号： A62D3/36 ,  A62D2101/22

摘要： A method of decomposing halogenated aromatic compounds safely without fail, which comprises bringing a solution of a halogenated aromatic compound in a hot-alkali-resistant polar solvent into contact with an alkaline substance at about 100 to about 300 DEG C to decompose the aromatic compound and removing the salt and alkaline substance precipitated in the solvent to recycle the used solvent.

摘要翻译： 一种安全可靠地分解卤代芳香族化合物的方法，其包括使卤代芳香族化合物在耐热碱性极性溶剂中的溶液与碱性物质在约100〜约300℃下接触，分解芳香族化合物， 除去在溶剂中沉淀的盐和碱性物质以循环使用的溶剂。

公开(公告)号：EP0372084A4

公开(公告)日：1990-09-26

申请号：EP89904234

申请日：1989-04-11

申请人： NIPPON STEEL CHEMICAL CO. LTD. ,  NIPPON STEEL CORPORATION

发明人： KAWASAKI, HIRONOBU ,  INAGAKI, HATSUO ,  KIYOMOTO, YASUO ,  YAMAGUCHI, TANEMI

IPC分类号： A62D3/36 ,  A62D101/41 ,  B09B3/00 ,  C04B14/40 ,  C04B41/65 ,  C04B41/67

CPC分类号： A62D3/36 ,  A62D2101/41 ,  B09B3/0066 ,  C04B14/40 ,  C04B20/1055