SEPARATION OF OLEFINS FROM OLEFINS/PARAFFINS MIXED GAS
    83.
    发明公开
    SEPARATION OF OLEFINS FROM OLEFINS/PARAFFINS MIXED GAS 有权
    烯烃从混合气体分离与烯烃/构烷烃

    公开(公告)号:EP2134667A1

    公开(公告)日:2009-12-23

    申请号:EP08741021.3

    申请日:2008-03-28

    IPC分类号: C07C7/12

    摘要: The present invention relates to a method and an apparatus for the separation of C4 olefins (butene-1, trans-2-butene, cis-2-butene, etc.) and C4 paraffins (normal butane, isobutane, etc.) from a C4 hydrocarbon mixed gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The method of the present invention produces C4 olefins with high purity by introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbent selectively adsorbing olefins to adsorb C4 olefins and to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins adsorbed on the adsorption tower with a desorbent (C5 hydrocarbon, C6 hydrocarbon, etc.), and then separating the C4 olefin and the desorbent by a distillation process. The apparatus of the present invention is composed of several adsorption towers loaded with an adsorbent which selectively adsorb olefins and two distillation towers for the separation of the mixture gases of olefins/desorbents and paraffins/desorbents respectively, The basic operating process of the adsorption tower comprises a adsorption step of selectively adsorbing C4 olefin from the feeding mixture, a C4 olefin rinse step of removing a small amount of C4 paraffins adsorbed together with C4 olefins, and a desorption step of desorbing C4 olefins by using a desorbent, and further comprises a pressure equalization step, a cocurrent depressurization step, and a accumulation pressure step in order to increase the yield and concentration of olefins depending on the operation pressure of the adsorption tower. The desorbent discharged from the process together with olefins or paraffins is separated in the distillation tower and then recycled.

    Carbon material having graphite nanolayer and synthesis method thereof
    84.
    发明公开
    Carbon material having graphite nanolayer and synthesis method thereof 有权
    Syntheseverfahren von karbonisiertem Cellulosematerialien mitoberflächlicherGraphitnanoschicht

    公开(公告)号:EP2105406A1

    公开(公告)日:2009-09-30

    申请号:EP08168851.7

    申请日:2008-11-11

    IPC分类号: C01B31/02 D01F9/16

    摘要: Disclosed herein is a carbon material having a graphite nanosized surface layer, and a method of synthesizing a carbon material having a graphite nanolayer on a surface thereof, including: i) heating a cellulose fiber in a reactor; ii) forming a first carbon material while maintaining temperature of the reactor; iii) cooling the formed first carbon material; iv) heating the cooled first carbon material; v) forming a second carbon material while maintaining temperature of the reactor; vi) cooling the formed second carbon material.

    摘要翻译: 本发明公开了具有石墨纳米表面层的碳材料及其表面上合成具有石墨纳米层的碳材料的方法,包括:i)在反应器中加热纤维素纤维; ii)在保持反应器的温度的同时形成第一碳材料; iii)冷却形成的第一碳材料; iv)加热冷却的第一碳材料; v)在保持反应器的温度的同时形成第二碳材料; vi)冷却形成的第二碳材料。