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    HYDROCONVERSION CATALYSTS AND METHODS OF MAKING AND USING SAME
    4.
    发明公开
    HYDROCONVERSION CATALYSTS AND METHODS OF MAKING AND USING SAME 审中-公开
    HYDRO转换催化剂及方法进行生产及其用途

    公开(公告)号：EP1684899A1

    公开(公告)日：2006-08-02

    申请号：EP04811291.6

    申请日：2004-11-18

    申请人： Advanced Refining Technologies, LLC

    发明人： KLEIN, Darryl, P.

    IPC分类号： B01J27/19 ,  B01J37/02

    摘要： Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks. High conversion can be achieved at reduced levels of sediment, especially in comparison to standard commercial catalysts.

    SPHEROIDAL RESID HYDRODEMETALLATION CATALYST
    8.
    发明公开
    SPHEROIDAL RESID HYDRODEMETALLATION CATALYST 审中-公开
    加氢脱金属球形催化剂残留物

    公开(公告)号：EP2814603A1

    公开(公告)日：2014-12-24

    申请号：EP13749889.5

    申请日：2013-02-15

    申请人： Advanced Refining Technologies, LLC

    发明人： PLECHA, Stanislaw ,  KAGAMI, Narinobu ,  DUMA, Viorel ,  CREIGHTON, John Everett

    IPC分类号： B01J23/00

    摘要： Spheroidal catalyst support, supported catalyst, and method of preparing and using the catalyst for hydrodemetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 30% percent of their pore volume in pores having a diameter of between 200 and 500 Å. Catalysts prepared from the supports contain Group 6, 9 and 10 metals or metal compounds supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydrotreating process. The catalysts also provide increased sulfur and MCR conversion during a hydrotreating process.