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    CATALYTIC PROCESS
    1.
    发明授权
    CATALYTIC PROCESS 有权
    催化方法

    公开(公告)号：EP1567616B2

    公开(公告)日：2010-08-18

    申请号：EP03778556.5

    申请日：2003-11-27

    申请人： CompactGTL plc

    发明人： BOWE, Michael Joseph ,  LEE-TUFFNELL, Clive Derek

    IPC分类号： C10G2/00

    CPC分类号： C10G2/341 ,  B01J19/249 ,  B01J19/2495 ,  B01J2219/2465 ,  B01J2219/247 ,  B01J2219/2477

    摘要： Fischer-Tropsch synthesis is performed using a compact catalytic reactor unit (10) defining channels in which is a gas-permeable catalyst structure (16), the channels extending between headers (18). The synthesis occurs in at least two stages, as the reactor unit provides at least two successive channels (14, 14a) for the Fischer-Tropsch synthesis connected by a header, the gas flow velocity through the first channel being sufficiently high that no more than 65% of the carbon monoxide undergoes conversion. The gases are cooled (25) in the header between the two stages, so as to condense water vapour, and then pass through the second channel at a sufficiently high gas flow velocity that no more than 65% of the remaining carbon monoxide undergoes conversion. This lowers the partial pressure of water vapour and so suppresses oxidation of the catalyst.

    APPARATUS AND PROCESS FOR THE PRODUCTION OF HYDROGEN
    7.
    发明公开
    APPARATUS AND PROCESS FOR THE PRODUCTION OF HYDROGEN 审中-公开
    装置和生产氢气的方法

    公开(公告)号：EP1812338A1

    公开(公告)日：2007-08-01

    申请号：EP05791679.3

    申请日：2005-10-05

    申请人： CompactGTL plc

    发明人： BOWE, Michael Joseph

    IPC分类号： C01B3/48 ,  B01J19/24 ,  C01B3/38

    CPC分类号： B01J19/249 ,  B01J2219/2453 ,  B01J2219/2465 ,  B01J2219/2466 ,  B01J2219/2472 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0888 ,  C01B2203/0894 ,  C01B2203/1241 ,  C01B2203/82 ,  Y02P20/128

    摘要： A plant (10) for producing hydrogen from a feed gas comprising short chain hydrocarbons, the plant comprising reactor means (14) defining channels for treating the feed gas in three successive stages, the channels for treating the feed gas in each case being adjacent to respective heat transfer channels, and the successive treatment stages being as follows: (a) pre-heating the feed gas (16b); (b) subjecting a mixture of steam and the heated feed gas to reforming (18b) in the presence of a reforming catalyst, while providing heat from adjacent channels (18a) in which catalytic combustion occurs; and (c) subjecting the gases produced by reforming to the water gas shift reaction (20b) in the presence of a shift catalyst, whilst removing heat into adjacent channels (20a) to generate steam. Preferably the reactor means is a single integrated reactor (14) in which all three of the successive treatment stages (16, 18, 20) occur, so that the heat transfers between the various fluids are also integrated. Such a reactor may be formed by a stack of plates between which the treatment channels and heat transfer channels are defined alternately in the stack.

    摘要翻译： 一种用于从包含短链烃的原料气生产氢气的设备（10），所述设备包括反应器装置（14），所述反应器装置限定用于以三个连续阶段处理所述原料气体的通道，用于处理所述原料气体的通道分别与 （a）预热所述进料气体（16b）;以及（b）将所述进料气体（16b）预热。 （b）在重整催化剂存在下，将蒸汽和加热的原料气体的混合物进行重整（18b），同时从其中发生催化燃烧的相邻通道（18a）提供热量; 和（c）在变换催化剂存在下，通过重整产生的气体进入水煤气变换反应（20b），同时将热量排入相邻通道（20a）以产生蒸汽。 优选地，反应器装置是其中发生所有三个连续处理阶段（16,18,20）的单个集成反应器（14），使得各种流体之间的热传递也被整合。 这样的反应器可以由一叠板形成，处理通道和传热通道交替地定义在堆叠中。