摘要:
A multistage tubular reaction system and method for preparing methylol derivatives of an aldehyde includes a tubular reaction system with a plurality of successive reactor stages provided with a formaldehyde containing feed stream. The system includes multiple feed ports for the staged addition of C2 or higher condensible aldehyde and/or base to the formaldehyde containing stream at a plurality of successive feed points to provide a production stream, which is progressively provided with additional reactants as the production stream advances through the successive reaction stages. Advantages include better temperature control and reduced byproduct formation.
摘要:
A liquid fuel catalytic partial oxidation (CPOX) reformer can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. At least the exterior surface of the CPOX reaction zone can include a hydrogen barrier. The liquid fuel CPOX reformer can include a vaporizer, one or more igniters, and a source of liquid reformable fuel.
摘要:
Integrated gaseous fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the gaseous fuel CPOX reformer.
摘要:
A multistage tubular reaction system and method for preparing methylol derivatives of an aldehyde includes a tubular reaction system with a plurality of successive reactor stages provided with a formaldehyde containing feed stream. The system includes multiple feed ports for the staged addition of C2 or higher condensible aldehyde and/or base to the formaldehyde containing stream at a plurality of successive feed points to provide a production stream, which is progressively provided with additional reactants as the production stream advances through the successive reaction stages. Advantages include better temperature control and reduced byproduct formation.
摘要:
A gasification reactor (1) for the partial combustion of a carbonaceous feed comprising a gasifier (3) having a gasifier wall (4), and a method for monitoring temperature development in the gasifier. the gasifier wall comprises coolant lines. At least one of the coolant lines (12) is a temperature monitoring line connected to a supply of a liquid coolant, in particular water. The temperature monitoring line comprises temperature measuring units for measuring temperature change over at least a section of the temperature monitoring line, where the coolant temperature is below the coolant boiling point.
摘要:
Material withdrawal apparatus and methods and systems of regulating material inventory in one or more units are provided. A material withdrawal apparatus includes a heat exchanger and a sensor. The heat exchanger includes a material inlet, material outlet, cooling fluid inlet, and cooling fluid outlet. The material inlet is coupled to the unit and the sensor is coupled to the heat exchanger to provide a metric indicative of the temperature at the material inlet; material outlet; cooling fluid inlet and cooling fluid outlet. Another embodiment of a material withdrawal apparatus includes a vessel having an outer wall, liner, fill port, and a discharge port. The liner at least partially covers the inner surface of the outer wall. The fill port and discharge port are defined in the vessel and the fill port is configured to receive withdrawn material from at least a unit. Other embodiments provide methods of withdrawing or regulating material in a unit.
摘要:
A process for producing polymer and more particularly adhesive using a recirculating loop reactor. In one embodiment the reactor includes one or more mixers to mix feed stock with the polymerized material recirculating in the reactor. In another embodiment a planetary roller extruder (PRE) may be used for this purpose. In still another embodiment, a combination of one or more static mixers and one or more PREs may be used.
摘要:
A process for producing polymer and more particularly adhesive using a recirculating loop reactor. In one embodiment the reactor includes one or more mixers to mix feed stock with the polymerized material recirculating in the reactor. In another embodiment a planetary roller extruder (PRE) may be used for this purpose. In still another embodiment, a combination of one or more static mixers and one or more PREs may be used.