摘要:
The method of making a pyrrolo bisthiazole homopolymer starts with dissolving a dibrominated pyrrolo[3,2-d:4,5-d']bisthiazole monomer having the formula:
where R is an alkyl group, in anhydrous tetrahydrofuran (THF). Then, the solvated monomer is treated with 1 equivalent of a Turbo-Grignard reagent complex having the formula i PrMgCl·LiCl at 0°C to form a reaction mixture. The reaction mixture is stirred for 1 hour at room temperature, and after stirring, the reaction mixture is refluxed for 24 hours. A conjugated homopolymer product having the formula:
where n is the number of repeating units of pyrrolo[3,2-d:4,5-d']bisthiazole, is recovered from the reaction mixture. The PBTz-based homopolymers showed broad absorption from 450 to 850 nm in thin film and excellent photochemical and thermal stability, making the polymers suitable for lightweight, low cost plastic electronic devices.
摘要:
The flow battery utilizing caustic waste includes at least one battery cell (100), which is formed from an ion-exchange membrane (106) disposed between porous anode and cathode electrode layers (108, 104). A cathode bipolar plate (102) is positioned adjacent the porous cathode electrode layer (104) and, similarly, an anode bipolar plate (110) is positioned adjacent the porous anode electrode layer (108). The anode bipolar plate (110) is adapted for receiving spent caustic waste and transporting the spent caustic waste to the anode electrode layer (108), and the cathode bipolar plate (102) is adapted for receiving an oxidant and transporting the oxidant to the porous cathode electrode layer (104) for generation of electricity while converting the spent caustic waste (303) into fresh caustic (306).
摘要:
The hybrid organic-inorganic perovskite-based solar cell with copper oxide as a hole transport material includes a transparent conducting film layer (12) sandwiched between a glass substrate (11) and a titanium dioxide layer (14). The transparent conducting film layer (12) can be fluorine-doped tin oxide. A lead methylammonium tri-iodide perovskite layer (16) is formed on the titanium dioxide layer (14), such that the titanium dioxide layer (14) is sandwiched between the lead methylammonium tri-iodide perovskite layer (16) and the transparent conducting film layer (12). A layer of copper oxide (Cu2O) (18), as a hole transport material, is formed on the lead methylammonium tri-iodide perovskite layer (16). The lead methylammonium tri-iodide perovskite layer (16) is sandwiched between the layer of hole transport material (18) and the titanium dioxide layer (14). A gold contact (20) is formed on the layer of hole transport material (18).
摘要:
A method for removing arsenic from a liquid includes adding a two-dimensional metal carbide adsorbent to the liquid to adsorb the arsenic from the liquid. The two-dimensional metal carbide adsorbent can include at least one MXene, having the formula M n+1 X n , where n = 1, 2 or 3, where M is an early transition metal, such as scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo) or the like, and X is either carbon or nitrogen. The MXene may be Ti 3 C 2 .
摘要:
The orthophosphate electrodes for rechargeable batteries include an anode and a cathode, each formed from an orthophosphate material, for use in a conventional electrolytic cell-type rechargeable battery. The orthophosphate anode is an anode formed from an orthophosphate material having the formula A2T2B(PO4)3, and the orthophosphate cathode is a cathode formed from an orthophosphate material having the formula A3T2B(PO4)3, where A represents an alkali metal and T and B each represent a transition metal. The alkali metal may be lithium (Li) sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), monovalent cations thereof, or combinations thereof and each transition metal may be titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), or combinations thereof. The transition metal may be a divalent or trivalent transition metal