OPTOELECTRONIC DEVICES WITH ORGANOMETAL PEROVSKITES WITH MIXED ANIONS
    2.
    发明公开
    OPTOELECTRONIC DEVICES WITH ORGANOMETAL PEROVSKITES WITH MIXED ANIONS 有权
    用混合的阴离子金属有机钙钛矿亚光电子器件

    公开(公告)号:EP2850626A1

    公开(公告)日:2015-03-25

    申请号:EP13723943.0

    申请日:2013-05-20

    IPC分类号: H01G9/20 H01L51/42 H01L51/00

    摘要: The invention provides an optoelectronic device comprising a mixed-anion perovskite, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.The invention further provides a mixed-halide perovskite of the formula (I) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ [A][B][X] 3 €ƒ€ƒ€ƒ€ƒ€ƒ(I) wherein: [A] is at least one organic cation; [B] is at least one divalent metal cation; and [X] is said two or more different halide anions. In another aspect, the invention provides the use of a mixed-anion perovskite as a sensitizer in an optoelectronic device, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention also provides a photosensitizing material for an optoelectronic device comprising a mixed-anion perovskite wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.

    COMPLEX AND PEROVSKITE MATERIAL, AND PEROVSKITE-TYPE SOLAR CELL USING COMPLEX OR PEROVSKITE MATERIAL

    公开(公告)号:EP3392256A1

    公开(公告)日:2018-10-24

    申请号:EP16875766.4

    申请日:2016-12-16

    申请人: Kyoto University

    IPC分类号: C07F7/24 H01L51/44

    摘要: The complex comprising one or more of the compound represented by general formula: RPb n1 X m1 (wherein R is a cation represented by R 1 NH 3 + (wherein R 1 represents a univalent substituted or unsubstituted hydrocarbon group), or the following formula:

    (wherein R 2 represents a hydrogen atom, or a univalent substituted or unsubstituted hydrocarbon group); X is the same or different, and each represents a halogen atom; n1 is 0.8 to 1.2; and m1 is 2.8 to 3.2, or the compound represented by general formula: R 2 Pb n2 X m2 wherein R and X are as defined above; n2 is 2.8 to 3.2; and m2 is 7.7 to 8.3; and one or more dimethylformamide molecules is capable of decreasing the stirring time upon dissolution in an organic solvent such as DMSO, as well as decreasing the hysteresis and improving the solar cell characteristics (in particular, photoelectric conversion efficiency) when the complex is applied to a perovskite layer. Further, by using a perovskite material substantially free from lead halide, it is possible to improve the power conversion efficiency (PCE) and the internal quantum efficiency (IQE).

    OPTOELECTRONIC DEVICE
    5.
    发明公开

    公开(公告)号:EP3336866A1

    公开(公告)日:2018-06-20

    申请号:EP18155003.9

    申请日:2013-05-20

    IPC分类号: H01G9/20 H01L51/42 H01L51/00

    摘要: The invention provides an optoelectronic device comprising a mixed-anion perovskite, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.The invention further provides a mixed-halide perovskite of the formula (I)

            [A][B][X] 3      (I)

    wherein: [A] is at least one amidinium based cation; [B] is at least one divalent metal cation; and [X] is said two or more different halide anions. In another aspect, the invention provides the use of a mixed-anion perovskite as a sensitizer in an optoelectronic device, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention also provides a photosensitizing material for an optoelectronic device comprising a mixed-anion perovskite wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.

    SYSTEM AND METHOD BASED ON MULTI-SOURCE DEPOSITION FOR FABRICATING PEROVSKITE FILM
    8.
    发明公开
    SYSTEM AND METHOD BASED ON MULTI-SOURCE DEPOSITION FOR FABRICATING PEROVSKITE FILM 审中-公开
    系统和方法基于分离从几个来源用于生产PEROWSKITFILMS

    公开(公告)号:EP3177753A1

    公开(公告)日:2017-06-14

    申请号:EP15828966.0

    申请日:2015-07-08

    摘要: A system and method for fabricating a perovskite film is provided, the system including a substrate stage configured to rotate around its central axis at a rotation speed, a first set of evaporation units, each coupled to the side section or the bottom section of the chamber, a second set of evaporation units coupled to the bottom section, and a shield defining two or more zones having respective horizontal cross-sectional areas, which are open and facing the substrate, designated for the two or more evaporation units in the second set. The resultant perovskite film includes multiple unit layers, wherein each unit layer is formed by one rotation of the substrate stage, and the composition and thickness of the unit layer are controlled by adjusting at least the evaporation rates, the rotation speed and the horizontal cross-sectional areas.

    摘要翻译: 一种用于制造钙钛矿电影的系统和方法被提供,该系统包括被配置为在旋转速度中,第一组的蒸发装置,每个都耦合到所述侧部或该腔室的底部区段绕其中心轴线旋转的基片台 ,第二组耦合到底部蒸发单元和屏蔽限定具有respectivement水平横截面区域的两个或更多个区,其是开放的,面向所述基板,指定为在第二组中的两个或更多个蒸发单元。 所得钙钛矿电影包括多个单元层,每个单元worin层通过衬底台的一个旋转而形成,并且该层单元的组成和厚度是由蒸发速率,旋转速度和所述水平横调整至少控制 截面积。