POLYMER DISPERSED LIQUID CRYSTALS IN ELECTRON-RICH ALKENE-THIOL POLYMERS
    1.
    发明公开
    POLYMER DISPERSED LIQUID CRYSTALS IN ELECTRON-RICH ALKENE-THIOL POLYMERS 失效
    聚合物分散的液晶在电子富集的烯烃 - 硫醇聚合物中的应用

    公开(公告)号:EP0649444A1

    公开(公告)日:1995-04-26

    申请号:EP94915979.0

    申请日:1994-04-29

    IPC分类号: G02F1 C08G75 C08L81 C09K19

    摘要: A polymer dispersed liquid crystal composite prepared from: (1) at least one multifunctional electron-rich alkene that does not undergo appreciable homopolymerization and is selected from the group consisting of (a) vinyl ethers and vinyl sulfides; (b) keteneacetals, ketenethioacetals and methylene oxathiolanes, wherein the carbon of the carbon-carbon double bond not bearing the electron donating group has bonded to it H or a combination of H and a C1 to C6 alkyl, preferably a methyl group; (c) ortho or para vinyl phenyl ethers or thioethers (also known as styryloxy or styrylthio ether monomers); or (d) bicyclic alkenes which have, as a result of their stereoelectronic configuration, unequal π-electron density above and below the plane of the carbon-carbon double bond axis; (2) a multifunctional thiol; (3) a photoinitiator; and (4) liquid crystal material.

    摘要翻译: 一种聚合物分散的液晶复合物,其由以下组分制备:(1)至少一种不发生明显均聚并且选自(a)乙烯基醚和乙烯基硫化物的多官能富电子烯烃; (b)乙烯酮缩乙醛,烯酮硫代缩醛和亚甲基氧硫杂环戊烷,其中不带给电子基团的碳 - 碳双键的碳与其键合H或H与C1-C6烷基,优选甲基的组合; (c)邻或对乙烯基苯基醚或硫醚(也称为苯乙烯基氧基或苯乙烯基硫醚单体); 或(d)作为其立体电子构型的结果,在碳 - 碳双键轴的平面之上和之下不等的π电子密度的双环烯烃; (2)多官能硫醇; (3)光引发剂; 和(4)液晶材料。

    CONSUMER POLYOLEFIN PRIMER
    2.
    发明公开
    CONSUMER POLYOLEFIN PRIMER 失效
    消费者聚烯烃底漆

    公开(公告)号:EP0559835A1

    公开(公告)日:1993-09-15

    申请号:EP92903820.0

    申请日:1991-11-27

    IPC分类号: C09J4 C08J5 C09D5 C09J5

    CPC分类号: C08J5/124

    摘要: Procédé de collage d'un substrat en plastique à l'aide d'un adhésif constitué d'alpha-cyanoacrylate, selon lequel on utilise un accélérateur d'adhésion contenant une diamine d'éthylène. Ce procédé convient particulièrement au collage de polyoléfines par des consommateurs courants.

    摘要翻译: 一种将塑料基材与α-氰基丙烯酸酯粘合剂粘合的方法,其中使用含乙二胺的粘合加速剂。 这个过程特别适合普通消费者粘合聚烯烃。

    Microwaveable adhesive dispenser and microwaveable adhesive charge therefor
    4.
    发明公开
    Microwaveable adhesive dispenser and microwaveable adhesive charge therefor 失效
    可加热的微波炉加油机胶粘剂及其粘接股票

    公开(公告)号:EP0696481A1

    公开(公告)日:1996-02-14

    申请号:EP95305541.5

    申请日:1995-08-09

    IPC分类号: B05C17/00 B65D81/34

    CPC分类号: B05C17/00546 B65D81/3461

    摘要: A dispensing assembly (10) for heating and subsequent dispensing of a microwaveable adhesive material (22) , comprising: a dispenser housing (12) having a microwaveable adhesive charge-receiving cavity therein; a microwave susceptor member (44) in the cavity, constructed and arranged to receive microwave energy when the dispensing assembly is exposed to microwave radiation and to responsively generate heat; and a microwaveable adhesive charge (20) of a size and shape for insertion into and retention in the cavity including said microwave receptor. The housing may comprise a seamless, resiliently deformable, unitary thermally insulating sleeve, and the microwaveable adhesive charge advantageously is devoid of susceptor materials and susceptor structure. The adhesive charge article may comprise a container (24) having disposed therein a solid body of hot melt adhesive material having a cross-sectional shape differing from the cross-sectional shape of the container in which the hot melt adhesive material is disposed for microwave heating.

    摘要翻译: 用于加热和可微波粘合材料的随后的分配(22)包括分配组件(10):具有可微波粘合剂电荷接收空腔在其中的分配器壳体(12); 在所述腔中的微波感受器部件(44),构造并布置成接收微波能量。当分配组件暴露于微波辐射,并响应性地产生热量; 和尺寸的可微波粘合剂电荷(20)和形状,用于插入和保持在所述空腔包括所述微波受体。 壳体可包括一个无缝,可弹性变形的,整体的热绝缘套管,并且微波粘合剂电荷有利地不含感受器材料和基座结构的。 粘合剂批料制品可包括容器(24),其具有设置在其中具有横截面形状从将热熔粘接剂材料被设置在微波加热的容器的横截面形状不同的热熔粘接剂材料的实心体 ,

    POLYMERIC CARRIERS FOR RELEASE OF COVALENTLY LINKED AGENTS
    6.
    发明授权
    POLYMERIC CARRIERS FOR RELEASE OF COVALENTLY LINKED AGENTS 失效
    FOR RELEASE聚合物载体共价键合ACTIVE

    公开(公告)号:EP0510132B1

    公开(公告)日:1997-05-14

    申请号:EP91918218.8

    申请日:1991-09-27

    申请人: NEORX CORPORATION

    IPC分类号: A61K47/48

    摘要: A chemically defined polymeric carrier comprising a series of α-amino acids in any combination containing side chains to which diagnostic/therapeutic and chelating agents can be covalently joined through cleavable linkers either directly or covalently joined through cleavable linkers after chemical modification of the side chains. Hydrazone, disulfide, and ester linkages in any combination can be present in the polymeric carrier between the side chains of the α-amino acids and the agents. The presence of a particular covalent linkage between the side chain and the agent in the carrier is determined by the functional group present in the side chain of the α-amino acid and the functional group present in the agent. The α-amino acids with side chains to which agents do not covalently join can function as spacers to minimize interaction between bulky molecules attached to the polymeric carrier. In addition, those α-amino acids with charge or hydrophilic side chains to which agents do not covalently join can provide increased solubility to the polymeric carrier.

    Synthesis of cyanoacrylate esters by oxidation of aromatic selenyl cyanopropionates
    7.
    发明公开
    Synthesis of cyanoacrylate esters by oxidation of aromatic selenyl cyanopropionates 失效
    Herstellung vonCyanacrylsäureesterndurch氧化薰香素Selenylcyanpropionaten

    公开(公告)号:EP0741127A1

    公开(公告)日:1996-11-06

    申请号:EP96302976.4

    申请日:1996-04-26

    CPC分类号: C07C253/30

    摘要: A method of preparing an α-cyanoacrylate ester of a desired alcohol includes the steps of
       preparing a compound which is an α-selenoaryl-α-cyanopropionate ester of the desired alcohol,
       oxidizing said α-selenoaryl-α-cyanopropionate ester to the corresponding selenoxide,
       eliminating arylselenic acid from the selenoxide to produce said α-cyanoacrylate ester, and
       separating said α-cyanoacrylate ester from the selenic acid.
    At temperatures of about 0°C or higher, the elimination step occurs concurrently with the oxidizing step using a peroxide or ozone oxidizing agent. The desired cyanoacrylate ester is obtained in good yield and very high purity. The method can be used to prepare difficult to synthesize plural functional cyanoacrylate monomers and mono-cyanoacrylate monomers regardless of alcohol chain length.

    摘要翻译: 制备方法。 的预选醇的α-氰基丙烯酸酯包括:(i)制备醇的α-硒代芳基-α-氰基丙酸酯; (ii)将酯氧化成相应的硒化物; (iii)除去芳基硒酸,得到α-氰基丙烯酸酯; 和(iv) 来自芳基硒酸。

    Low viscosity self-toughening acrylate composition
    8.
    发明公开
    Low viscosity self-toughening acrylate composition 失效
    SelbsthärtendeAcrylatzusammensetzung mit niedrigerViskosität。

    公开(公告)号:EP0562826A1

    公开(公告)日:1993-09-29

    申请号:EP93302207.1

    申请日:1993-03-23

    IPC分类号: G03F7/027 C08F299/06

    摘要: Compositions comprising:

    A) A mixture of acrylate functional prepolymers in the total amount of between about 50% and 80% by weight of the composition, said prepolymer mixture comprising a first prepolymer which is a urethane diacrylate resin, suitably a polyether urethane diacrylate, having a viscosity of at least 500,000 mPa.sec at 25°C in an amount of between 10 and 40% by weight of the composition, and a second multi-acrylate prepolymer having a viscosity of between about 500 and 50,000 mPa.sec in an amount of at least 15 % by weight of the composition;
    B) A monoacrylate diluent monomer selected from the group consisting of isobornyl acrylate, β-carboxyethyl acrylate and mixtures thereof in an amount of at least 5 % by weight of the composition; and,
    C) An effective amount for cure initiation of a free radical initiator, the composition having a viscosity of less than 10,000 mPa.sec at 25°C, give unusual self-toughened cured properties. Such compositions, where the free radical initiator is a free radical photoinitiator, are particularly useful in rapid prototyping applications where the requirement for low viscosity and optical clarity of the liquid formulation has heretofore limited use of the formulations to ones giving undesirably brittle or soft properties.

    摘要翻译: 组合物,其包含:A)丙烯酸酯官能预聚物的混合物,其总量为组合物重量的约50%至80%,所述预聚物混合物包含第一预聚物,其为聚氨酯二丙烯酸酯树脂, 25℃时粘度至少为500,000mPa.sec,其量为组合物重量的10至40%,第二种多丙烯酸酯预聚物的粘度为约500至50,000mPa.sec,其量为 至少为组合物重量的15%; B)选自丙烯酸异冰片酯,丙烯酸β-羧基乙酯及其混合物的单丙烯酸酯稀释剂单体的量为组合物重量的至少5重量% 和C)自由基引发剂的固化起始的有效量,该组合物在25℃下的粘度小于10,000mPa.sec,具有不寻常的自增韧固化性能。 其中自由基引发剂是自由基光引发剂的这种组合物在快速成型应用中特别有用,其中液体制剂的低粘度和光学透明度的要求至今限制了给予不希望的脆性或软性质的制剂的使用。 ,

    Air-activable polymerizable compositions containing tetrazoles
    10.
    发明公开
    Air-activable polymerizable compositions containing tetrazoles 失效
    四氯化are are ten ten ten ten ten ten ten ten ten ten ten ten

    公开(公告)号:EP0718386A1

    公开(公告)日:1996-06-26

    申请号:EP95309320.0

    申请日:1995-12-20

    IPC分类号: C09J4/00

    CPC分类号: C09J4/00 C08F220/00

    摘要: A one-component air-activatable polymerisable adhesive composition comprising:

    (a) a free-radically polymerisable monomer, and
    an activator system for effective polymerisation of the free-radically polymerisable monomer, said activator system comprising:
    (b) an autoxidisable compound which is a dihydropyridine (other than a stabilised 1,4-dihydropyridine)
    (c) a tetrazole having the formula III
    wherein R 8 is selected from hydrogen and hydrocarbyl groups, and
    (d) a soluble ionic salt,
    with the proviso that the composition does not contain a peroxide, or a peroxide precursor which produces peroxide in the absence of air or any ingredient which is a significant source of radicals in the absence of air,
    the composition having been prepared under anaerobic conditions and stored under anaerobic conditions.

    摘要翻译: 一种单组分可空气活化的可聚合粘合剂组合物,其包含:(a)可自由基聚合的单体和用于有效聚合可自由基聚合的单体的活化剂体系,所述活化剂体系包含:(b)可自动氧化的化合物, 二氢吡啶(不同于稳定的1,4-二氢吡啶)(c)具有式III 的四唑,其中R 8选自氢和烃基,和(d)可溶性离子盐,条件是 该组合物不含有过氧化物或在不存在空气的情况下产生过氧化物的过氧化物前体,或在不存在空气的情况下是重要的自由基来源的任何成分,该组合物已经在厌氧条件下制备并在厌氧条件下储存 。