公开(公告)号：EP2668136B1

公开(公告)日：2018-04-11

申请号：EP12739986.3

申请日：2012-01-27

申请人： Honeywell International Inc. ,  Werner, Christian ,  Steinberg, Christoph ,  Maurer, Jessica

发明人： WERNER, Christian ,  STEINBERG, Christoph ,  MAURER, Jessica ,  ZUMAQUE, Harry

IPC分类号： C01G19/02 ,  B01D37/02

CPC分类号： C01G19/02 ,  C01P2006/80

摘要： Provided herein are methods for the preparation of high purity stannous oxide comprising: (a) reacting a Sn salt with a C2-12 dicarboxylic acid in the aqueous phase to form a suspension comprising a Sn-dicarboxylate complex; (b) washing the Sn-dicarboxylate complex with water to obtain a wash solution comprising a washed Sn-dicarboxylate complex essentially free of the anion of the Sn salt; and (c) reacting the washed Sn-dicarboxylate complex with a base to form high purity SnO, wherein the high purity SnO has an alpha radiation count of less than about 0.002 cph/cm2.

公开(公告)号：EP2668136A4

公开(公告)日：2016-07-06

申请号：EP12739986

申请日：2012-01-27

申请人： HONEYWELL INT INC ,  WERNER CHRISTIAN ,  STEINBERG CHRISTOPH ,  MAURER JESSICA

发明人： WERNER CHRISTIAN ,  STEINBERG CHRISTOPH ,  MAURER JESSICA ,  ZUMAQUE HARRY

IPC分类号： C01G19/02 ,  B01D37/02

CPC分类号： C01G19/02 ,  C01P2006/80

摘要： Provided herein are methods for the preparation of high purity stannous oxide comprising: (a) reacting a Sn salt with a C2-12 dicarboxylic acid in the aqueous phase to form a suspension comprising a Sn-dicarboxylate complex; (b) washing the Sn-dicarboxylate complex with water to obtain a wash solution comprising a washed Sn-dicarboxylate complex essentially free of the anion of the Sn salt; and (c) reacting the washed Sn-dicarboxylate complex with a base to form high purity SnO, wherein the high purity SnO has an alpha radiation count of less than about 0.002 cph/cm2.

摘要翻译： 本文提供了制备高纯度氧化亚锡的方法，包括：（a）在水相中使Sn盐与C 2-12二羧酸反应以形成包含Sn-二羧酸络合物的悬浮液; （b）用水洗涤所述Sn-二羧酸络合物，得到包含基本上不含Sn盐的阴离子的经洗涤的Sn-二羧酸盐络合物的洗涤溶液; 和（c）使经洗涤的Sn-二羧酸酯配合物与碱反应以形成高纯度SnO，其中高纯度SnO具有小于约0.002cph / cm 2的α辐射计数。

公开(公告)号：EP2668136A2

公开(公告)日：2013-12-04

申请号：EP12739986.3

申请日：2012-01-27

申请人： Honeywell International, Inc. ,  Werner, Christian ,  Steinberg, Christoph ,  Maurer, Jessica

发明人： WERNER, Christian ,  STEINBERG, Christoph ,  MAURER, Jessica ,  ZUMAQUE, Harry

IPC分类号： C01G19/02 ,  B01D37/02

CPC分类号： C01G19/02 ,  C01P2006/80

摘要： Provided herein are methods for the preparation of high purity stannous oxide comprising: (a) reacting a Sn salt with a C2-12 dicarboxylic acid in the aqueous phase to form a suspension comprising a Sn-dicarboxylate complex; (b) washing the Sn-dicarboxylate complex with water to obtain a wash solution comprising a washed Sn-dicarboxylate complex essentially free of the anion of the Sn salt; and (c) reacting the washed Sn-dicarboxylate complex with a base to form high purity SnO, wherein the high purity SnO has an alpha radiation count of less than about 0.002 cph/cm2.