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    Apparatus for surface treatment of synthetic organic polymer mouldings
    2.
    发明公开
    Apparatus for surface treatment of synthetic organic polymer mouldings 失效
    装置模制的合成有机聚合物的表面处理。

    公开(公告)号：EP0285446A2

    公开(公告)日：1988-10-05

    申请号：EP88302960.5

    申请日：1988-03-31

    申请人： AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY ,  LAN TECHNICAL SERVICE CO., LTD. ,  SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Katoh, Koichiroh Industrial Products Research Ins. ,  Matsumoto, Yoshiie Lan Technical Service Co., Ltd. ,  Shinonaga, Hideo

    IPC分类号： B29C59/16

    CPC分类号： B29C59/16 ,  B29C2035/0827 ,  B29K2023/12 ,  B29K2995/0041

    摘要： Apparatus for surface treatment of a synthetic organic polymer moulding includes a preliminary heating chamber (11) for heating a synthetic organic polymer moulding as a preliminary step, a solvent treatment chamber (21) for contacting the surface of the preliminarily-heated moulding with an ultraviolet light absorbing solvent provided in a solvent tank (25), an irradiation chamber (31) including low pressure mercury lamps (35) for irradiating the surface of the moulding with ultraviolet light having a main wavelength of 184.9 nm, and a transfer mechanism such as a belt conveyor (41) for transferring the moulding through the chambers. The apparatus can alternatively dispense with the preliminary heating chamber, in which case the solvent treatment chamber is arranged to contact the surface of the moulding with the ultraviolet light absorbing solvent having been heated to a predetermined temperature.
    A polypropylene type resin is preferably used as the synthetic organic polymer. The surface of the synthetic organic polymer moulding is easily modified and hence coating, printing, adhesion, or similar treatment of the moulding can be effected with high adherence.

    摘要翻译： 一种用于合成有机聚合物模制的表面处理包括用于加热的合成有机聚合物成型作为预先加热的成型体的表面与紫外线接触的预备步骤，溶剂处理室（21）的预备加热室（11） 光吸收溶剂中，在溶剂罐（25）设置，以照射室（31）包括低压汞灯（35），用于照射具有184.9纳米的主波长的紫外线灯，和一个传送机构在模制的表面：如 带式传送器（41），用于传递环通过腔室中的成型。 该装置可任选被预备加热室分配，在这种情况下，溶剂处理室被布置成与所述紫外线吸收溶剂已被加热到预定温度的模制品的表面接触。 聚丙烯类树脂，优选使用作为合成有机聚合物。 该合成的有机聚合物成型体的表面被容易地修改和因此涂布，印刷，粘附，或模制品的类似的处理可以以高的粘附来进行。

    Method of treating surface of molded article of thermoplastic elastomer composition
    4.
    发明公开
    Method of treating surface of molded article of thermoplastic elastomer composition 失效
    一种用于治疗的热塑性弹性体的模塑Ständes的表面的方法。

    公开(公告)号：EP0452132A2

    公开(公告)日：1991-10-16

    申请号：EP91303219.9

    申请日：1991-04-11

    申请人： DIRECTOR-GENERAL OF THE AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY ,  SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Katoh, Kohichiroh ,  Suzuki, Kyoji ,  Shinonaga, Hideo ,  Sogabe, Satoru

    IPC分类号： C08J7/06 ,  C08J7/04 ,  C08L23/16 ,  C08L23/10

    CPC分类号： C08L23/16 ,  C08J7/065 ,  C08K5/14 ,  C08L91/00 ,  C08L2312/00 ,  C08L2666/04 ,  C08L2666/02

    摘要： A method for treating the surface of a molded article, which comprises a combination of the steps of:
       providing a molded article made of a thermoplastic elastomer composition obtained by a thermal treatment of a mixture in the presence of an organic peroxide, which mixture is comprised of (A) an oil-extended olefinic copolymer rubber of an olefinic copolymer rubber having a Mooney viscosity (ML₁₊₄100°C) of 90-200 and a mineral oil type softening agent, (B) an olefinic plastic, and (C) a bismaleimide compound, the ratio by weight of (A) the oil-extended olefinic copolymer rubber to (B) the olefinic plastic, A/B, being 24/76 - 80/20, the content of (C) the bismaleimide compound being 0.1-3 parts by weight based on 100 parts by weight of the total amount of (A) the oil-extended olefinic copolymer rubber and (B) the olefinic plastic,
       contacting the surface of the molded article with a UV-rays absorbing liquid, and
       irradiating the surface of the molded article with UV-rays having main wave lengths of 300 nm, or less. According to the surface treatment of the present invention, the olefinic thermoplastic elastomer to which paints can hardly be applied hitherto shows good paintability and printability in addition to the inherent useful properties. Paint-coated molded articles obtained by the method of this invention find wide utility in the fields of various industries, especially in the field of automobile industry as exterior or interior parts.

    摘要翻译： 提供由通过混合物的热处理在有机过氧化物的存在下得到的热塑性弹性体组合物，其混合物是由成型品：一种用于治疗的模塑制品，该方法包括以下步骤的组合的表面的方法 的（A）具有90-200的门尼粘度（ML1 + 4100℃）和一种矿物油型软化剂的烯烃共聚物橡胶的充油烯烃共聚物橡胶，（B）烯烃系塑料，和（C） 双马来酰亚胺化合物，以重量计的比率（A）中的充油烯类共聚物橡胶（B）的烯烃类塑料，A / B，是24/76 - 80/20，（C）的含量的双马来酰亚胺化合物是 0.1-3重量份，基于100重量份（A）中的充油烯类共聚物橡胶和（B）的烯烃类塑料，接触所述模制制品的表面用UV射线吸收液的总量的， 和照射具有主瓦特紫外线模塑制品的表面 为300nm或更小AVE长度。 。根据本发明的表面处理时，烯烃类热塑性弹性体，以哪个油漆几乎不能应用迄今显示除了固有的有用性质良好的油漆能力和适印性。 本发明的方法得到的油漆涂层的模制品发现在各行业得到广泛的实用工具，在汽车产业领域作为外部或内部零件尤其是爱情。

    Method of treating surface of molded article of thermoplastic elastomer composition
    5.
    发明授权
    Method of treating surface of molded article of thermoplastic elastomer composition 失效
    治疗由热塑性弹性体的模塑制品的表面的方法Ständes

    公开(公告)号：EP0452132B1

    公开(公告)日：1996-03-06

    申请号：EP91303219.9

    申请日：1991-04-11

    申请人： DIRECTOR-GENERAL OF THE AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY ,  SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Katoh, Kohichiroh ,  Suzuki, Kyoji ,  Shinonaga, Hideo ,  Sogabe, Satoru

    IPC分类号： C08J7/06 ,  C08J7/04 ,  C08L23/16 ,  C08L23/10

    CPC分类号： C08L23/16 ,  C08J7/065 ,  C08K5/14 ,  C08L91/00 ,  C08L2312/00 ,  C08L2666/04 ,  C08L2666/02

    摘要： A method for treating the surface of a molded article, which comprises a combination of the steps of: providing a molded article made of a thermoplastic elastomer composition obtained by a thermal treatment of a mixture in the presence of an organic peroxide, which mixture is comprised of (A) an oil-extended olefinic copolymer rubber of an olefinic copolymer rubber having a Mooney viscosity (ML1+4100 DEG C) of 90-200 and a mineral oil type softening agent, (B) an olefinic plastic, and (C) a bismaleimide compound, the ratio by weight of (A) the oil-extended olefinic copolymer rubber to (B) the olefinic plastic, A/B, being 24/76 - 80/20, the content of (C) the bismaleimide compound being 0.1-3 parts by weight based on 100 parts by weight of the total amount of (A) the oil-extended olefinic copolymer rubber and (B) the olefinic plastic, contacting the surface of the molded article with a UV-rays absorbing liquid, and irradiating the surface of the molded article with UV-rays having main wave lengths of 300 nm, or less. According to the surface treatment of the present invention, the olefinic thermoplastic elastomer to which paints can hardly be applied hitherto shows good paintability and printability in addition to the inherent useful properties. Paint-coated molded articles obtained by the method of this invention find wide utility in the fields of various industries, especially in the field of automobile industry as exterior or interior parts.

    Method of treating surface of molded article of thermoplastic elastomer composition
    6.
    发明公开
    Method of treating surface of molded article of thermoplastic elastomer composition 失效
    热塑性弹性体组合物成型制品表面处理方法

    公开(公告)号：EP0452132A3

    公开(公告)日：1992-07-15

    申请号：EP91303219.9

    申请日：1991-04-11

    申请人： DIRECTOR-GENERAL OF THE AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY ,  SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Katoh, Kohichiroh ,  Suzuki, Kyoji ,  Shinonaga, Hideo ,  Sogabe, Satoru

    IPC分类号： C08J7/06 ,  C08J7/04 ,  C08L23/16 ,  C08L23/10

    CPC分类号： C08L23/16 ,  C08J7/065 ,  C08K5/14 ,  C08L91/00 ,  C08L2312/00 ,  C08L2666/04 ,  C08L2666/02

    摘要： A method for treating the surface of a molded article, which comprises a combination of the steps of:
       providing a molded article made of a thermoplastic elastomer composition obtained by a thermal treatment of a mixture in the presence of an organic peroxide, which mixture is comprised of (A) an oil-extended olefinic copolymer rubber of an olefinic copolymer rubber having a Mooney viscosity (ML₁₊₄100°C) of 90-200 and a mineral oil type softening agent, (B) an olefinic plastic, and (C) a bismaleimide compound, the ratio by weight of (A) the oil-extended olefinic copolymer rubber to (B) the olefinic plastic, A/B, being 24/76 - 80/20, the content of (C) the bismaleimide compound being 0.1-3 parts by weight based on 100 parts by weight of the total amount of (A) the oil-extended olefinic copolymer rubber and (B) the olefinic plastic,
       contacting the surface of the molded article with a UV-rays absorbing liquid, and
       irradiating the surface of the molded article with UV-rays having main wave lengths of 300 nm, or less. According to the surface treatment of the present invention, the olefinic thermoplastic elastomer to which paints can hardly be applied hitherto shows good paintability and printability in addition to the inherent useful properties. Paint-coated molded articles obtained by the method of this invention find wide utility in the fields of various industries, especially in the field of automobile industry as exterior or interior parts.

    Surface treating of polyphenylene ether thermoplastic shaped articles
    10.
    发明公开
    Surface treating of polyphenylene ether thermoplastic shaped articles 失效
    Oberflächenbehandlungeines geformten thermoplastischenPolyphenenäthergegenstandstand。

    公开(公告)号：EP0447239A2

    公开(公告)日：1991-09-18

    申请号：EP91302177.0

    申请日：1991-03-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Abe, Hiroomi ,  Shinonaga, Hideo ,  Kitadono, Kaoru ,  Suzuki, Yasuro ,  Sogabe, Satoru

    IPC分类号： B29C59/16 ,  C08L71/00

    CPC分类号： B29C59/16 ,  B05D3/063 ,  B29C59/005 ,  B29K2071/00 ,  C08L67/00 ,  C08L71/123 ,  C08L77/00 ,  C08L2666/02

    摘要： A composition is prepared of, by wt, (I) 100 parts of a mixture of 5 to 100% of a polyphenylene ether or a mixture thereof with a styrene polyester, or a graft copolymer thereof and styrene and (b) 95 to 0% of a thermoplastic polyamide and/or saturated polyester resin; and optionally (II) 0 to 50 parts of a rubbery substance; (III) 0 to 50 parts of inorganic filler and/or glass fibers; and (IV) 0 to 10 parts of at least one of seven types of compatibilizer which improves compatibility of the polymers (I) (a) and (b).
    The production of these components is described.
    The components are mixed in any order and molded. The surface of the molded article, e.g. a film, plate or fibers, may be degreased and is irradiated with ultraviolet light of wavelength less than 300 nm, preferably 185 and 254 nm as main wavelengths, for 20 seconds to 10 minutes: The irradiation improves the coatability of the surface, which may then be coated with a coating of an alkyd-melamine or an acrylic urethane.

    摘要翻译： 制备（I）100份5-100％聚苯醚或其与苯乙烯聚酯或其接枝共聚物和苯乙烯的混合物的混合物的组合物，和（b）95至0％ 的热塑性聚酰胺和/或饱和聚酯树脂; 和任选的（II）0至50份橡胶状物质; （III）0〜50份无机填料和/或玻璃纤维; 和（IV）0至10份改善聚合物（I）（a）和（b）的相容性的七种增容剂中的至少一种。 描述了这些部件的生产。 组分以任何顺序混合并成型。 模制品的表面，例如， 薄膜，板或纤维可以脱脂，并用波长小于300nm，优选185和254nm的紫外线作为主要波长照射20秒至10分钟。照射改善了表面的可涂覆性， 然后涂覆醇酸三聚氰胺或丙烯酸聚氨酯的涂层。