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1.发明公开Polysubstituted butanoic acids, esters and derivatives thereof useful as herbicides, Compositions containing them and their use 失效多取代的丁酸，酯和衍生物作为除草剂，含有它们和它们的用途的组合物是有用的。
公开(公告)号：EP0005341A2
公开(公告)日：1979-11-14
申请号：EP79300688.3
申请日：1979-04-24
IPC分类号： A01N9/22 , A01N9/20 , A01N9/12 , C07C121/68 , C07C121/75 , C07C121/78 , C07C149/415 , C07D213/57 , C07D317/60
CPC分类号： C07C255/00 , A01N37/34 , A01N37/38 , A01N37/44 , A01N37/48 , A01N41/10 , A01N43/10 , A01N43/30 , A01N43/40 , A01N47/02
摘要： The invention relates to polysubstituted butanoic acids, esters and derivatives thereof which have been found to be useful as herbicides in the control of undesirable mono- and di-cotyledonous plants. The active compounds have the formula:
wherein R, is OH, OR 4 , NR 5 R 6 or OM; R 2 and R 3 each represent a member selected from the group consisting
pyridyl and thienyl; R 4 is alkyl C 1 -C 8 , monohaloalkyl C 1 -C 4 , monohaloalkynyl C 3 -C 4 , monohaloalkenyl C 3 -C 4 , alkoxy C 1 -C 4 alkyl C 1 -C 4 or hydroxyalkynyl C 2 -C 4 ; R 5 and R 6 each independently represent members selected from the group consisting of H and alkyl C 1 -C 2 ; M is an alkali metal, ammonium, C 1 -C 8 mono or di-alkylammonium or hydroxyethylammonium; and X and Y each independently represent members selected from the group consisting of hydrogen, halogen, alkyl C 1 -C 4 ; alkoxy C 1 -C 4 , OCF 3 , OCHF 2 , CF 3 , CN, COOH, NO2, OH, SCH 3 , NR 7 R 8 , CH 3 SO 2 , and when X and Y are taken together they may represent -OCH 2 O- jointed to adjacent positions of the benzene ring and R 7 and R 8 are each hydrogen or alkyl (C 1 -C 2 ). Compounds of formula (I) exist in threo and erythro stereoisomeric forms, and in general the threo isomers (many of which are novel compounds) are the more active herbicidal agents. Accordingly it is generally preferred to employ the threo stereoisomers and threo-erythro mixtures.摘要翻译： 本发明涉及到其已被发现是在不希望的单 - 和二 - 子叶植物的控制除草剂有用取代基丁酸，酯和衍生物。 的活性化合物具有下式：...
... worin R1为OH，OR 4，NR 5 R 6或OM; R2和R3各自代表选自下组的成员：... ...吡啶基和噻吩基; R 4是烷基C1-C8，单卤代烷基C1-C4，C3-C4 monohaloalkynyl，monohaloalkenyl C3-C4烷氧基C1-C4烷基C1-C4或C2-C4羟基炔; R5和R6各自代表unabhängig选自H和C1-C2烷基选定成员; M是碱金属，铵，C1-C8单或二烷基铵或羟乙基; 和X和Y各自代表unabhängig选自氢，卤素，烷基C 1 -C 4的选择的成员; 烷氧基C1-C4，OCF 3，OCHF 2，CF 3，CN，COOH，NO 2，OH，SCH 3，NR 7 R 8，CH 3 SO 2，当X和Y一起他们可能代表-OCH2O-接合到苯环和R 7与相邻的位置 R8各自为氢或烷基（C1-C2）。 式（I）的化合物中存在苏和红立体异构形式，和一般的苏式异构体（其中有许多是新的化合物）是更具活性的除草剂。 因此，最好采用苏式立体式和苏式赤混合基因的反弹。 -
2.发明公开Polysubstituted butanoic acids, esters and derivatives thereof useful as herbicides 失效多糖类，其衍生物及其衍生物作为除草剂有用
公开(公告)号：EP0005341A3
公开(公告)日：1979-11-28
申请号：EP79300688
申请日：1979-04-24
IPC分类号： A01N09/22 , A01N09/20 , A01N09/12 , C07C121/68 , C07C121/75 , C07C121/78 , C07C149/415 , C07D213/57 , C07D317/60
CPC分类号： C07C255/00 , A01N37/34 , A01N37/38 , A01N37/44 , A01N37/48 , A01N41/10 , A01N43/10 , A01N43/30 , A01N43/40 , A01N47/02
摘要： The invention relates to polysubstituted butanoic acids, esters and derivatives thereof which have been found to be useful as herbicides in the control of undesirable mono- and di-cotyledonous plants. The active compounds have the formula:
wherein R, is OH, OR 4 , NR 5 R 6 or OM; R 2 and R 3 each represent a member selected from the group consisting
pyridyl and thienyl; R 4 is alkyl C 1 -C 8 , monohaloalkyl C 1 -C 4 , monohaloalkynyl C 3 -C 4 , monohaloalkenyl C 3 -C 4 , alkoxy C 1 -C 4 alkyl C 1 -C 4 or hydroxyalkynyl C 2 -C 4 ; R 5 and R 6 each independently represent members selected from the group consisting of H and alkyl C 1 -C 2 ; M is an alkali metal, ammonium, C 1 -C 8 mono or di-alkylammonium or hydroxyethylammonium; and X and Y each independently represent members selected from the group consisting of hydrogen, halogen, alkyl C 1 -C 4 ; alkoxy C 1 -C 4 , OCF 3 , OCHF 2 , CF 3 , CN, COOH, NO2, OH, SCH 3 , NR 7 R 8 , CH 3 SO 2 , and when X and Y are taken together they may represent -OCH 2 O- jointed to adjacent positions of the benzene ring and R 7 and R 8 are each hydrogen or alkyl (C 1 -C 2 ). Compounds of formula (I) exist in threo and erythro stereoisomeric forms, and in general the threo isomers (many of which are novel compounds) are the more active herbicidal agents. Accordingly it is generally preferred to employ the threo stereoisomers and threo-erythro mixtures.
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