摘要:
An insecticidal composition containing more than one active ingredients which comprises as active ingredient in an amount of 0.001-99% by weight a synthetic pyrethroide of general Formula (I), (wherein X stands for chlorine or bromine) - namely out of the eight possible isomers at least 95% of a 55:45 - 25:75 mixture of the enantiomer-pairs Ia:Ib, wherein Ia is 1RcisS + 1ScisR and Ib is 1RtransS + 1StransR - if desired, in admixture with an activator and/or with an amount of up to 100% of an auxiliary agent, preferably an antioxidant, stabilizer, wetting agent, emulsifiying agent, dispersing agent, antifoam agent, diluent, carrier, and/or filler. The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.
摘要:
The invention provides insecticidal and acaricidal compounds of formula (I) : wherein X is selected from hydrogen, halo, hydroxy, alkoxy and acyloxy, Z represents a fluoroalkyl group of one or two carbon atoms, Y represents a substituted aryl group where each substituent is selected from halo, alkyl of up to six carbon atoms, aryl, aralkyl of up to four carbon atoms in the alkyl moiety, aryloxy and arylamino, and either (i) R represents hydrogen, and W, W 2 and W 3 are independently selected from halo, alkyl of up to six carbon atoms, alkoxy of up to six carbon atoms, alkoxyalkyl of up to a total of six carbon atoms, haloalkyl of up to six carbon atoms, and haloalkoxy of up to six carbon atoms, or (ii) R is selected from methyl, trifluoromethyl, cyano and ethynyl, and W', W 2 and W 3 are independently selected from hydrogen, halo, alkyl of up to six carbon atoms, alkoxy of up to six carbon atoms, alkoxyalkyl of up to a total of six carbon atoms, haloalkyl of up to six carbon atoms, and haloalkoxy of up to six carbon atoms. The invention also provides processes and intermediates for the preparation of the compounds of formula (I), compositions comprising them and methods of combating and controlling insect and acarine pests therewith.
摘要:
The present invention relates to 3-(4-fluoro- phenoxy)propionitrile having the formula (I):
a process for preparing 3-(4-fluorophenoxy)propionitrile having the formula (I) which comprises reacting 4-fluorophenol and acrylonitrile in the presence of tertiary amine, a process for preparing 6-fluoro-4-chromanone having the formula (II): which comprises reacting 3-(4-fluorophenoxy)propionitrile having the formula (I) with acid, and a process for preparing 6-fluoro-4-chromanone having the formula (II) which comprises reacting 4-fluorophenol with acrylonitrile in the presence of a catalyst to give 3-(4-fluorophenoxy)propionitrile having the formula (I), which is then reacted with acid. 6-Fluoro-4-chromanone is an important intermediate for a synthesis of (S)-2,3-dihydro-6-fluoro-spiro[4H-1-benzopyran-4,4'-imidazolidine]-2',5'dione (USAN: sorbinil).