公开(公告)号：EP2382182A1

公开(公告)日：2011-11-02

申请号：EP10707592.1

申请日：2010-01-27

申请人： Arkema France

发明人： PAUL, Jean-Michel ,  GRAIRE, Coralie ,  RIEHL, Audrey

IPC分类号： C07C213/06

CPC分类号： C07C213/10 ,  C07C219/20

摘要： The invention relates to a method for producing N,N-dimethylaminoethyl acrylate by the transesterification reaction of an alykl acrylate by N1N-dimethylaminoethanol, and more particularly relates to a method for purifying the azeotropic fraction generated during said reaction, thereby enabling the recycling thereof on the alkyl acrylate production unit. The aim of the method of the invention is in particular to remove the acetaidehyde and the dialkoxyethane contained in the azeotropic fraction, either by the direct distillation of the azeotropic fraction or by the distillation of the aqueous phase resulting from the water scrubbing of the azeotropic fraction.

公开(公告)号：EP1871736A1

公开(公告)日：2008-01-02

申请号：EP06743642.8

申请日：2006-04-06

申请人： Arkema France

发明人： PAUL, Jean-Michel ,  BESSALEM, Jacqueline

IPC分类号： C07C67/08 ,  C07C69/54

CPC分类号： C07C67/08 ,  C07C69/54

摘要： The invention concerns a improved method for making linear, branched or cyclic C1-C15 alkyl (meth)acrylates, by direct esterification of (meth)acrylic acid with a corresponding alcohol, said reaction being catalyzed by sulfuric acid. The method includes a step of hydrolyzing (11) the neutralizing aqueous flow (9) followed by extraction (13) of the residual (meth)acrylic acid with a solvent (15) consisting entirely or partly of the alcohol used in the reaction. The invention enables organic pollution (COD) released in the final aqueous effluents (24) of the process to be reduced, as well as productivity to be increased.

公开(公告)号：EP1976831B1

公开(公告)日：2010-10-27

申请号：EP07712654.8

申请日：2007-01-03

申请人： ARKEMA FRANCE

发明人： PAUL, Jean-Michel

IPC分类号： C09D4/00 ,  C09J4/00 ,  C09J133/04 ,  C09D133/04

CPC分类号： C07D233/32 ,  C08F220/14 ,  C08F220/36 ,  C09D4/00

摘要： The invention relates to special (meth)acrylic monomers, more particularly to solutions of alkylimidazolidone (meth)acrylates in heavy (meth)acrylic esters, and also to the preparation thereof from solutions of alkylimidazolidone (meth)acrylates in water or in light (meth)acrylic esters. The solutions of the invention are particularly advantageous in UV-radiation-polymerizing or electron-beam-polymerizing paint or varnish applications.

公开(公告)号：EP1805128A1

公开(公告)日：2007-07-11

申请号：EP05809097.8

申请日：2005-10-18

申请人： ARKEMA France

发明人： PAUL, Jean-Michel

IPC分类号： C07C57/075

CPC分类号： C07C51/56 ,  C07C51/573 ,  C07C57/04

摘要： The invention relates to an improved method for the production of (meth)acrylic anhydride by transanhydrification between (meth)acrylic acid and acetic anhydride in the presence of air and presence of at least one polymerization inhibitor, characterized in that the polymerization inhibitor is chosen from the group consisting of (a) metallic salts of thiocarbamic acid or dithiocarbamic acid and mixtures thereof with a phenol derivative or phenothiazine and the derivatives thereof, and (b) N-oxyl compounds mixed with 2,6-diterbutyl 4-methyl phenol taken on its own in the presence of 2,4-dimethyl 6-terbutyl phenol.

公开(公告)号：EP2262779B1

公开(公告)日：2012-12-05

申请号：EP09742271.1

申请日：2009-04-08

申请人： ARKEMA FRANCE

发明人： RIONDEL, Alain ,  PAUL, Jean-Michel

IPC分类号： C07D233/34

CPC分类号： C07D233/34

公开(公告)号：EP2382182B1

公开(公告)日：2012-11-14

申请号：EP10707592.1

申请日：2010-01-27

申请人： Arkema France

发明人： PAUL, Jean-Michel ,  GRAIRE, Coralie ,  RIEHL, Audrey

IPC分类号： C07C213/06 ,  C07C213/10

CPC分类号： C07C213/10 ,  C07C219/20

公开(公告)号：EP2084122A1

公开(公告)日：2009-08-05

申请号：EP07858510.6

申请日：2007-10-04

申请人： ARKEMA FRANCE

发明人： PAUL, Jean-Michel ,  COCHET, Françoise ,  VERGE, Christophe

IPC分类号： C07C69/54 ,  C07C67/03 ,  C07C67/08 ,  C07C67/62 ,  C10L1/19 ,  C10M129/70 ,  C10N30/02

CPC分类号： C07C69/54 ,  C07C67/03 ,  C07C67/62 ,  C10L1/1963 ,  C10L10/14 ,  C10M145/14 ,  C10M2209/084 ,  C10N2230/02 ,  Y02E50/13

摘要： The invention relates to alkyl (meth)acrylates comprising a long linear chain bearing alkyl ramifications corresponding to general formula (I); in which R1 is a hydrogen atom or a methyl radical and R2 is a long alkyl chain of formula (II): R(CH2-CH2)n(CH2-CH(R3))m- in which R is a methyl or ethyl radical, R3 is an linear- or branched-chain alkyl radical containing from 1 to 6 carbon atoms, n = 9 to 20, m = 1 to 5, wherein it is possible for the -CH2-CH2- and -CH2-CH(R3)- units to be distributed in block or random form. These compounds can in particular be used for the production of additives intended to lower the setting point of paraffinic oils or fuels (diesel oils or fuel oils), and for the production of additives for lubricants.

公开(公告)号：EP1802564A1

公开(公告)日：2007-07-04

申请号：EP05809243.8

申请日：2005-10-07

申请人： Arkema France

发明人： CROIZY, Jean-François ,  FAUCONET, Michel ,  PAUL, Jean-Michel ,  BONNAZ, René

IPC分类号： C07C57/04 ,  C07C51/50 ,  C07C69/54 ,  C07C67/62 ,  B01F17/00

CPC分类号： B01F17/0064

摘要： The compounds of formula (I) are suggested for use as deposit control agents preventing the deposit of polymeric compounds or resulting in addition reactions on the (meth)acrylic double bonds during synthesis, purification, or regeneration of (meth)acrylic monomers operations. R1 represents a C3-C30 alkyl radical, an aryl radical or an alkylaryl radical, these radicals being able to be interrupted or bound to the oxygen of the molecule by a chain -(OR4)o- or the R4's, independent of one another, represent an ethylene, propylene or butylene chain and, o is an integer from 1 to 50; R2 represents R1, a hydrogen atom or a counterion, and; R3 represents a hydrogen atom or a counterion.

公开(公告)号：EP3174844A1

公开(公告)日：2017-06-07

申请号：EP15735994.4

申请日：2015-06-22

申请人： Arkema France

发明人： MORELIERE, Anne ,  FRIMOUR, Gilles ,  PAUL, Jean-Michel ,  DENIS, Stephane

IPC分类号： C07C67/08 ,  C07C69/54

CPC分类号： C07C67/08 ,  C07C67/54 ,  Y02P20/582 ,  C07C69/54

摘要： The present invention relates to a method for producing a C
4 -C
10 alkyl (meth)acrylate, by direct esterification of (meth)acrylic acid by the corresponding alcohol, the reaction water being removed in the form of an azeotrope with the esterification alcohol from a distillation column mounted over the esterification reactor comprising a cationic resin as a catalyst. Said method is characterized in that the molar ratio of alcohol to acid at the inlet of the reactor is between 1.4 and 3, and in that the crude reaction mixture circulates in a recirculation loop joining the reactor and the water removal column, at a recirculation rate of between 6 and 25, expressed by the mass ratio between the flow fed into the loop and the flow sent to a purification treatment.

摘要翻译： （甲基）丙烯酸直接酯化制备（甲基）丙烯酸C 4 -C 10烷基酯的方法本发明涉及通过用相应的醇直接酯化（甲基）丙烯酸来制备（甲基）丙烯酸C 4 -C 10烷基酯的方法，反应水以与酯化醇形成共沸物的形式从 安装在包含阳离子树脂作为催化剂的酯化反应器上的蒸馏塔。 所述方法的特征在于，反应器入口处的醇与酸的摩尔比在1.4和3之间，并且粗反应混合物在连接反应器和脱水塔的再循环回路中以再循环率 在6和25之间，由送入回路的流量与送至净化处理的流量之间的质量比表示。

公开(公告)号：EP2435180A1

公开(公告)日：2012-04-04

申请号：EP10728769.0

申请日：2010-05-18

申请人： Arkema France

发明人： PAUL, Jean-Michel ,  TONNELIER, Boris ,  AUGUSTIN, Francis

IPC分类号： B01J23/14 ,  C07C67/03

CPC分类号： B01J31/122 ,  B01J31/12 ,  B01J2231/49 ,  B01J2531/42 ,  C07C67/03 ,  C07C69/54

摘要： The present invention relates to a composition including a dialkyl tin oxide, such as DBTO, which can be used as a transesterification catalyst for the synthesis of (meth)acrylic esters. The invention also relates to a method for the synthesis of (meth)acrylic esters by transesterification in the presence of said composition. The composition of the invention is a solution with a concentration of dialkyl tin oxide. The composition is easy to implement in a continuous process and results in an enhanced selectivity in relation to solid DBTO or the homolog thereof. Advantageously, the compounds used for producing the solution of dialkyl tin oxide are the reagents used in the transesterification reaction and with or without the product of said reaction.