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1.发明授权REINFORCED SILICON CARBOXIDE COMPOSITE WITH BORON NITRIDE COATED CERAMIC FIBERS 失效加固SILIZIUMCARBOXID叠合氮化硼陶瓷涂层纤维，其含有
公开(公告)号：EP0688307B1
公开(公告)日：1996-11-06
申请号：EP93907444.9
申请日：1993-03-12
申请人： AlliedSignal Inc.
CPC分类号： C04B35/62868 , B32B18/00 , C03C14/002 , C03C2214/03 , C03C2214/20 , C04B35/5603 , C04B35/571 , C04B35/62863 , C04B35/62884 , C04B35/62897 , C04B35/806 , C04B35/82 , C04B2235/5224 , C04B2235/5228 , C04B2235/5232 , C04B2235/5236 , C04B2235/524 , C04B2235/5244 , C04B2235/5248 , C04B2235/5264 , C04B2235/5268 , C04B2235/612 , C04B2235/616 , C04B2235/77 , C04B2235/96 , C04B2237/365 , C04B2237/38
摘要： An improved fiber reinforced glass composite includes a boron nitride-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. Graceful failure can be obtained after exposure of the composites to temperatures up to 600-700 °C in air.
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2.发明授权SILICON OXYCARBONITRIDE BY PYROLYSIS OF POLYCYCLOSILOXANES IN AMMONIA 失效SILIZIUMOXYCARBONITRID法制备热解氨的POLYCYCLOSILOXANEN
公开(公告)号：EP0642474B1
公开(公告)日：1996-06-19
申请号：EP93901115.1
申请日：1992-12-22
申请人： AlliedSignal Inc.
CPC分类号： C03C14/002 , C03C10/0009 , C03C2214/02 , C03C2214/03 , C03C2214/20 , C04B35/806
摘要： An improved fiber reinforced glass composite includes a refractory fiber in a matrix of a nitrogen-containing black glass ceramic having the empirical formula SiNzCxOy where x ranges from greater than zero up to about 2.0, preferably 0.1 to 1.0, y ranges from 0.5 up to about 3.0, preferably 0.7 to 1.8, and z ranges from above zero up to about 1.5, preferably 0.2 to 1.0. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The cyclosiloxane monomers are polymerized and then pyrolyzed in an ammonia-containing atmosphere to produce the nitrogen-containing black glass (silicon oxycarbonitride).
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3.发明授权
公开(公告)号：EP0680461B1
公开(公告)日：1996-12-18
申请号：EP93904563.9
申请日：1993-01-21
申请人： AlliedSignal Inc.
摘要： An improved protective layer for ceramic insulating bodies comprises a composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.
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4.发明公开REINFORCED SILICON CARBOXIDE COMPOSITE WITH BORON NITRIDE COATED CERAMIC FIBERS 失效加固SILIZIUMCARBOXID复合材料与氮化硼陶瓷纤维BESCHTET
公开(公告)号：EP0688307A1
公开(公告)日：1995-12-27
申请号：EP93907444.0
申请日：1993-03-12
申请人： AlliedSignal Inc.
CPC分类号： C04B35/62868 , B32B18/00 , C03C14/002 , C03C2214/03 , C03C2214/20 , C04B35/5603 , C04B35/571 , C04B35/62863 , C04B35/62884 , C04B35/62897 , C04B35/806 , C04B35/82 , C04B2235/5224 , C04B2235/5228 , C04B2235/5232 , C04B2235/5236 , C04B2235/524 , C04B2235/5244 , C04B2235/5248 , C04B2235/5264 , C04B2235/5268 , C04B2235/612 , C04B2235/616 , C04B2235/77 , C04B2235/96 , C04B2237/365 , C04B2237/38
摘要： An improved fiber reinforced glass composite includes a boron nitride-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. Graceful failure can be obtained after exposure of the composites to temperatures up to 600-700 °C in air.
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公开(公告)号：EP0642474A1
公开(公告)日：1995-03-15
申请号：EP93901115.0
申请日：1992-12-22
申请人： AlliedSignal Inc.
CPC分类号： C03C14/002 , C03C10/0009 , C03C2214/02 , C03C2214/03 , C03C2214/20 , C04B35/806
摘要： An improved fiber reinforced glass composite includes a refractory fiber in a matrix of a nitrogen-containing black glass ceramic having the empirical formula SiNzCxOy where x ranges from greater than zero up to about 2.0, preferably 0.1 to 1.0, y ranges from 0.5 up to about 3.0, preferably 0.7 to 1.8, and z ranges from above zero up to about 1.5, preferably 0.2 to 1.0. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The cyclosiloxane monomers are polymerized and then pyrolyzed in an ammonia-containing atmosphere to produce the nitrogen-containing black glass (silicon oxycarbonitride).
摘要翻译： 一种改进的纤维增强玻璃复合材料包括在具有经验式SiNzCxOy的含氮黑色玻璃陶瓷基体中的耐火纤维，其中x的范围从大于零直到约2.0，优选0.1到1.0，y的范围从0.5直到约 3.0，优选0.7-1.8，z的范围从0以上至约1.5，优选0.2至1.0。 优选黑色玻璃陶瓷衍生自含有与硅和/或氢化物 - 硅基团连接的乙烯基的环硅氧烷单体。 将环硅氧烷单体聚合，然后在含氨的气氛中热解以生成含氮黑玻璃（碳氧氮化硅）。
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6.发明授权
公开(公告)号：EP0654016B1
公开(公告)日：1997-10-29
申请号：EP92917769.9
申请日：1992-08-07
申请人： AlliedSignal Inc.
CPC分类号： C03C3/045 , C03C10/0009 , C03C14/002 , C03C2214/02 , C03C2214/03 , C03C2214/20
摘要： A black glass having the empirical formula SiCxOy where x is greater than zero and up to about 2.0 and y is greater than zero and up to about 2.2 is produced from a cyclosiloxane polymer precursor by pyrolysis in the presence of oxygen by heating at a rate exceeding about 5 °C/min.
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7.发明授权
公开(公告)号：EP0688306B1
公开(公告)日：1997-08-13
申请号：EP93908316.8
申请日：1993-03-12
申请人： AlliedSignal Inc.
CPC分类号： C03C14/002 , C03C2214/02 , C03C2214/03 , C03C2214/20 , Y10S428/902 , Y10T428/249928 , Y10T428/30 , Y10T428/31663
摘要： A protective layer for polymeric composite substrates comprises a fiber-reinforced glass composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.
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8.发明公开
公开(公告)号：EP0688306A1
公开(公告)日：1995-12-27
申请号：EP93908316.0
申请日：1993-03-12
申请人： AlliedSignal Inc.
CPC分类号： C03C14/002 , C03C2214/02 , C03C2214/03 , C03C2214/20 , Y10S428/902 , Y10T428/249928 , Y10T428/30 , Y10T428/31663
摘要： A protective layer for polymeric composite substrates comprises a fiber-reinforced glass composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.
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9.发明授权REINFORCED SILICON CARBOXIDE COMPOSITE WITH BORON NITRIDE COATED CERAMIC FIBERS 失效加固SILIZIUMCARBOXID叠合氮化硼陶瓷涂层纤维，其含有
公开(公告)号：EP0688307B2
公开(公告)日：2000-06-14
申请号：EP93907444.9
申请日：1993-03-12
申请人： AlliedSignal Inc.
CPC分类号： C04B35/62868 , B32B18/00 , C03C14/002 , C03C2214/03 , C03C2214/20 , C04B35/5603 , C04B35/571 , C04B35/62863 , C04B35/62884 , C04B35/62897 , C04B35/806 , C04B35/82 , C04B2235/5224 , C04B2235/5228 , C04B2235/5232 , C04B2235/5236 , C04B2235/524 , C04B2235/5244 , C04B2235/5248 , C04B2235/5264 , C04B2235/5268 , C04B2235/612 , C04B2235/616 , C04B2235/77 , C04B2235/96 , C04B2237/365 , C04B2237/38
摘要： An improved fiber reinforced glass composite includes a boron nitride-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. Graceful failure can be obtained after exposure of the composites to temperatures up to 600-700 °C in air.
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10.发明公开
公开(公告)号：EP0680461A1
公开(公告)日：1995-11-08
申请号：EP93904563.0
申请日：1993-01-21
申请人： AlliedSignal Inc.
IPC分类号： C04B41
摘要： An improved protective layer for ceramic insulating bodies comprises a composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.
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