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公开(公告)号:EP3974459A1
公开(公告)日:2022-03-30
申请号:EP20810655.9
申请日:2020-05-18
发明人: ICHINO, Hiroyuki , KUSANOSE, Yasuhiro , HOSHINA, Toshikazu , TSUJI, Takahiro , HISASUE, Takahiro
IPC分类号: C08F297/04 , C08L23/12 , C08L53/02 , C09J123/10 , C09J153/02 , C09J7/38
摘要: A hydrogenated copolymer containing
a hydrogenated copolymer (a) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, and
a hydrogenated copolymer (b) prepared by hydrogenating a copolymer of a vinyl aromatic compound and a conjugated diene compound, wherein
a mass ratio (a)/(b) of a content of the hydrogenated copolymer (a) to a content of the hydrogenated copolymer (b) is 5/95 to 95/5,
the hydrogenated copolymer (a) has a hydrogenated polymer block (B1) and a hydrogenated polymer block (B2),
the hydrogenated polymer block (B1) consists of a vinyl aromatic compound and a conjugated diene compound and has a content of the vinyl aromatic compound of 40 to 80 mass%,
the hydrogenated polymer block (B2) mainly contains a conjugated diene compound and has a vinyl bond content of 60 to 100 mol% before hydrogenation,
the hydrogenated copolymer (b) has a hydrogenated polymer block (B3) consisting of a vinyl aromatic compound and a conjugated diene compound, and a content of the vinyl aromatic compound in the hydrogenated polymer block (B3) is 20 to 90 mass%.-
公开(公告)号:EP3770210A1
公开(公告)日:2021-01-27
申请号:EP20190030.5
申请日:2017-04-24
摘要: The resin composition according to the present invention comprises a polypropylene resin (a), a hydrogenated block copolymer (b), and a hydrogenated block copolymer (c), wherein the hydrogenated block copolymers (b) and (c) comprise, in each molecule, a vinyl aromatic compound unit and a conjugated diene compound unit; a total amount of the vinyl aromatic compound unit in the hydrogenated block copolymers (b) and (c) is 1 to 15 mass%; degrees of hydrogenation of the hydrogenated block copolymers (b) and (c) are each 80 mol% or more; a butylene content and/or a propylene content in the hydrogenated block copolymers (b) and (c) is specified; a tan δ peak obtained by a dynamic viscoelasticity measurement (1 Hz) of the hydrogenated block copolymers (b) and (c) are each in a specified range; the hydrogenated block copolymer (b) and/or (c) has a crystallization peak at -20 to 80°C and has a heat of crystallization of 0.1 to 10 J/g; the hydrogenated block copolymers (b) and (c) neither have a crystallization peak at a position other than -20 to 80°C nor have a heat of crystallization of less than 0.1 J/g and more than 10 J/g;a mass ratio of a content of the hydrogenated block copolymer (b) to a content of the hydrogenated block copolymer (c), (b)/(c), is 90/10 to 10/90; and
a mass ratio of a content of the polypropylene resin (a) to a total content of the hydrogenated block copolymer (b) and the hydrogenated block copolymer (c), (a)/((b) + (c)), is 10/90 to 90/10.-
3.
公开(公告)号:EP3342793A1
公开(公告)日:2018-07-04
申请号:EP16839334.6
申请日:2016-08-24
IPC分类号: C08F297/04 , C08F8/04 , C08L23/10 , C08L53/02
CPC分类号: C08F8/04 , C08F297/044 , C08J5/18 , C08J2323/12 , C08J2323/14 , C08J2353/02 , C08J2423/14 , C08J2453/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L53/025 , C08L2201/10 , C08L2203/16 , C08L2205/025 , C08L2205/06 , C08F297/04
摘要: The present invention provides a hydrogenated block copolymer: having a polymer block (S) containing an aromatic vinyl compound unit as a main constituent; and a polymer block (B) containing a conjugated diene compound unit as a main constituent, in a molecule, in which
a content of the polymer block (S) is 5 to 20% by mass and a content of the polymer block (B) is 80 to 95% by mass, in the hydrogenated block copolymer;
the polymer block (B) contains a polymer block (B1) and a polymer block (B2); an amount of a vinyl bond of the polymer block (B1) before hydrogenation is 30 to 60 mol% and an amount of a vinyl bond of the polymer block (B2) before hydrogenation is more than 60 to 100 mol%;
a content of the polymer block (B1) is 5 to 60% by mass and a content of the polymer block (B2) is 30 to 85% by mass, in the hydrogenated block copolymer;
a content of a structure represented by following Formula (1) in the hydrogenated block copolymer is 40 to 100% by mass; and
a hydrogenation rate of the hydrogenated block copolymer is 70 mol% or more:
(S-B) ... Formula (1)
[wherein, S represents the polymer block (S) and B represents the polymer block (B)].-
4.
公开(公告)号:EP2865717B1
公开(公告)日:2018-05-23
申请号:EP13810220.7
申请日:2013-06-25
发明人: KUSANOSE, Yasuhiro , HORIUCHI, Mika , YAGI, Noriko
CPC分类号: C08L53/025 , C08F297/04 , C08J3/124 , C08J2323/04 , C08J2353/02 , C08L23/04 , C08L23/06 , C08L23/12 , C08L2205/03 , C08L53/00
摘要: It is an object of the present invention to provide a hydrogenated block copolymer pellet, which has the ability to become a molded product that is excellent in transparency, flexibility, bleeding resistance, and low combustion ash content, without causing blocking among pellets. A hydrogenated block copolymer pellet having 100 parts by mass of a pellet molded product of hydrogenated block copolymer A and 0.01 to 1.5 parts by mass of a dusting agent of polyethylene powder B, wherein the hydrogenated block copolymer A has at least one polymeric block a mainly including a vinyl aromatic monomer unit and at least one polymeric block b mainly including a conjugated diene monomer unit, in which a total of a 1,2-bond content and a 3,4-bond content in the polymeric block b before hydrogenation is 40% to 90%, the hydrogenated block copolymer A has a hardness of 30° to 67°, a content of the polymeric block a in the hydrogenated block copolymer A is 5% to 30% by mass, and the polyethylene powder B has a number average molecular weight of 15,000 or less, an average particle diameter of 1 to 15 µm, and an angle of repose of 45° to 70°.
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公开(公告)号:EP4169959A1
公开(公告)日:2023-04-26
申请号:EP21828414.9
申请日:2021-06-08
IPC分类号: C08F297/04 , C08L53/02 , C09J7/30
摘要: Provided is a hydrogenated copolymer (X) comprising: a hydrogenated copolymer (A); and a hydrogenated copolymer (B), wherein the hydrogenated copolymer (X) satisfies the following (1) to (4): (1): the hydrogenated copolymer (A) has a random copolymer structure comprising a conjugated diene monomer unit and a vinyl aromatic monomer unit, and a content of the vinyl aromatic monomer unit in (A) is 10 to 80 mass%; (2): the hydrogenated copolymer (B) has a random copolymer structure comprising a conjugated diene monomer unit and a vinyl aromatic monomer unit, and a content of the vinyl aromatic monomer unit in (B) is 10 to 80 mass%; (3): a ratio (Mn1/Mn2) of (Mn1) of the hydrogenated copolymer (A) to (Mn2) of the hydrogenated copolymer (B) is less than 0.25, and 1000 ≤ Mn1 ≤ 40000; and (4): a mass ratio (A)/(B) of a content of the hydrogenated copolymer (A) to a content of the hydrogenated copolymer (B) is 5/95 to 50/50.
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公开(公告)号:EP3088464B1
公开(公告)日:2020-11-18
申请号:EP14875422.9
申请日:2014-12-17
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公开(公告)号:EP3118254B1
公开(公告)日:2020-07-29
申请号:EP15761061.9
申请日:2015-03-10
IPC分类号: C08L23/10 , B65D65/02 , C08F297/04 , C08L53/02
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公开(公告)号:EP3450496A1
公开(公告)日:2019-03-06
申请号:EP17789466.4
申请日:2017-04-24
摘要: The resin composition according to the present invention contains a polypropylene resin (a), a hydrogenated block copolymer (b), and a hydrogenated block copolymer (c), wherein: a mass ratio of a content of the hydrogenated block copolymer (b) to a content of the hydrogenated block copolymer (c), (b)/(c), is 90/10 to 10/90; a mass ratio of a content of the polypropylene resin (a) to a total content of the hydrogenated block copolymer (b) and the hydrogenated block copolymer (c), (a)/((b) + (c)), is 10/90 to 90/10; and specific polymer blocks (C), (B1), and (B2) differing in amount of vinyl bond before hydrogenation are contained at a specific ratio.
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公开(公告)号:EP3450474A1
公开(公告)日:2019-03-06
申请号:EP17789472.2
申请日:2017-04-24
摘要: The hydrogenated block copolymer according to the present invention is a hydrogenated block copolymer containing, in the molecule, a polymer block (C) having a conjugated diene compound as a main component, a polymer block (B) having a conjugated diene compound as a main component, and a polymer block (S) having a vinyl aromatic compound as a main component, wherein:
the polymer block (B) contains polymer blocks (B1) and (B2);
in the hydrogenated block copolymer, a content of the polymer block (C) is 1 to 20 mass%, a content of the polymer block (B) is 73 to 97 mass%, and a content of the polymer block (S) is 1 to 15 mass%;
an amount of vinyl bond before hydrogenation of the polymer block (C) is 1 to 25 mol%, an amount of vinyl bond of the polymer block (B1) is 40 to 60 mol%, and an amount of vinyl bond of the polymer block (B2) is 60 to 100 mol%; and
a degree of hydrogenation is 80 mol% or more.-
公开(公告)号:EP3348586A1
公开(公告)日:2018-07-18
申请号:EP16844403.2
申请日:2016-09-07
IPC分类号: C08F8/04 , B32B1/08 , B32B27/00 , B32B27/32 , C08F297/04 , C08L15/00 , C08L23/10 , C08L53/02
CPC分类号: C08F297/04 , B32B1/08 , B32B27/00 , B32B27/08 , B32B27/302 , B32B27/32 , B32B2270/00 , B32B2597/00 , C08F8/04 , C08L15/00 , C08L23/14 , C08L53/02 , C08L53/025 , F16L11/04
摘要: A tube including a hydrogenated block copolymer (a), wherein
the hydrogenated block copolymer (a) includes, in a molecule, a polymer block mainly including a conjugated diene compound (C), a polymer block mainly including a conjugated diene compound (B), and a polymer block mainly including a vinyl aromatic compound (S),
a content of the polymer block mainly including the conjugated diene compound (C) is 1 to 30% by mass, a content of the polymer block mainly including the conjugated diene compound (B) is 69 to 98% by mass, and a content of the polymer block mainly including the vinyl aromatic compound (S) is 1 to 20% by mass in the hydrogenated block copolymer (a), and
the polymer block mainly including a conjugated diene compound (C) has a vinyl bond content before hydrogenation of 1 to 25 mol%, the polymer block mainly including the conjugated diene compound (B) has a vinyl bond content before hydrogenation of 60 to 100 mol%, and the hydrogenated block copolymer (a) has a ratio of hydrogenation of 80 mol% or more.
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