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1.发明公开
公开(公告)号：EP1682471A1
公开(公告)日：2006-07-26
申请号：EP04797622.0
申请日：2004-11-04
IPC分类号： C07C23/16 , C07C69/14 , C07C43/184 , C08F10/10 , C08F110/10
CPC分类号： C07C17/08 , C07C23/16 , C07C43/184 , C07C69/013 , C07C2601/18 , C08F110/10 , C08F4/00 , C08F4/06
摘要： Disclosed are substituted 7-membered to 12-membered cycloalkanes comprising terminal groups, especially chloride atoms, on tertiary ring carbon atoms, a method for the production thereof, and the use thereof as cationic polymerization initiators, particularly for cationically polymerizing isobutene. Preferred compounds are 1,4-dichloro-1,4-dimethylcyclooctane, 1,5-dichloro-1,5-dimethylcyclooctane, and mixtures thereof. Said compounds are produced by adding hydrocarbon to adequately substituted cycloalkapolyenes.
摘要翻译： 描述了在叔环碳上具有离去基团，特别是氯原子的取代的7至12元环烷烃，其制备方法及其作为阳离子聚合引发剂，特别是异丁烯的阳离子聚合的用途。 优选的化合物是1,4-二氯-1,4-二甲基环辛烷，1,5-二氯-1,5-二甲基环辛烷及其混合物。 它们通过在适当取代的环烷多烯上加入氯化氢来制备。
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公开(公告)号：EP1546213B1
公开(公告)日：2006-05-31
申请号：EP03798168.5
申请日：2003-09-18
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F2500/03 , C08F2500/02
摘要： Disclosed is a method for producing polyisobutene containing at least 75 mole percent of terminal vinylidene groupings. According to the inventive method, isobutene or hydrocarbon mixtures containing isobutene is/are polymerized in a liquid phase in the presence of a boron trifluoride complex catalyst having the composition a(BF3): b(Co1): c(Co2), wherein Co1 represents at least one tertiary alcohol, Co2 represents a compound selected among water, primary alcohols, secondary alcohol, dialkyl ethers, alkanecarboxylic acids, and phenols, the ratio c:b ranges from 0.9 to 1.8, and the ratio (b+c):a ranges from 0.9 to 3.0.
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3.发明公开
公开(公告)号：EP1480930A1
公开(公告)日：2004-12-01
申请号：EP03706566.1
申请日：2003-02-24
发明人： LANG, Gabriele , HÜFFER, Stefan , LANGE, Arno , RATH, Hans, Peter
摘要： α-Chloroisopropyl substituted aromatics are obtained in high yield by treatment of isopropenyl substituted aromatics with hydrogen chloride gas in the absence of a solvent. The α-chloroisopropyl substituted aromatics serve as initiators for the cationic polymerisation of isobutene.
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公开(公告)号：EP1347995A2
公开(公告)日：2003-10-01
申请号：EP01994776.1
申请日：2001-12-11
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F4/44 , C08F4/00 , C08F2/002 , C08F2/38 , C08F2500/02 , C08F2500/03
摘要： The invention relates to a polymerization method for isobutene or mixtures of isobutene with ethylenically unsaturated comonomers under the conditions of a living cationic polymerization . According to the invention, the initiator system additionally comprises at least one non-polymerizable aprotic silicon-organic compound having at least one Si-O bond.
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5.发明授权POLYMERZUSAMMENSETZUNG, ENTHALTEND WENIGSTENS EIN MITTELMOLEKULARES REAKTIVES POLYISOBUTEN 有权聚合物组合至少包含一个中心分子活性聚异丁烯
公开(公告)号：EP1423474B1
公开(公告)日：2006-08-16
申请号：EP02772220.6
申请日：2002-08-28
发明人： LANGE, Arno , HÜFFER, Stefan , LANG, Gabriele , MACH, Helmut , RATH, Hans, Peter , SCHAUSS, Eckard
CPC分类号： C08L51/06 , C08L21/00 , C08L23/22 , C08L23/26 , C08L2666/04
摘要： The invention relates to a polymer composition containing at component that contains at least one polyisobutene based on one middle molecular weight polyisobutene and at least another polymer different therefrom.
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公开(公告)号：EP1546213A1
公开(公告)日：2005-06-29
申请号：EP03798168.5
申请日：2003-09-18
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F2500/03 , C08F2500/02
摘要： Disclosed is a method for producing polyisobutene containing at least 75 mole percent of terminal vinylidene groupings. According to the inventive method, isobutene or hydrocarbon mixtures containing isobutene is/are polymerized in a liquid phase in the presence of a boron trifluoride complex catalyst having the composition a(BF3): b(Co1): c(Co2), wherein Co1 represents at least one tertiary alcohol, Co2 represents a compound selected among water, primary alcohols, secondary alcohol, dialkyl ethers, alkanecarboxylic acids, and phenols, the ratio c:b ranges from 0.9 to 1.8, and the ratio (b+c):a ranges from 0.9 to 3.0.
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公开(公告)号：EP1395620A2
公开(公告)日：2004-03-10
申请号：EP02747321.4
申请日：2002-05-24
CPC分类号： C08F110/10 , C08F10/00 , C08F110/06 , Y10S526/918 , C08F2/38 , C08F4/00 , C08F2/01 , C08F4/16 , C08F2500/02 , C08F2500/03
摘要： The invention relates to a method for producing homopolymers and copolymers of isobutene by the continuous cationic polymerization of isobutene or mixtures of isobutene with ethylenically unsaturated comonomers in the presence of an initiator system comprising: i) a Lewis acid selected among covalent metal-halogen compounds and covalent semimetal-halogen compounds; ii) at least one aprotic organic compound (I) having at least one functional group (FG) which, under polymerization conditions, forms a carbocation or a cationogenic complex with the Lewis acid, in an organic solvent that is inert to the Lewis acid. The inventive method is characterized in that the polymerization is carried out in a tubular continuous flow reactor that has a number of bends with an alternating bending direction.
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公开(公告)号：EP1395620B1
公开(公告)日：2007-08-15
申请号：EP02747321.4
申请日：2002-05-24
CPC分类号： C08F110/10 , C08F10/00 , C08F110/06 , Y10S526/918 , C08F2/38 , C08F4/00 , C08F2/01 , C08F4/16 , C08F2500/02 , C08F2500/03
摘要： The invention relates to a method for producing homopolymers and copolymers of isobutene by the continuous cationic polymerization of isobutene or mixtures of isobutene with ethylenically unsaturated comonomers in the presence of an initiator system comprising: i) a Lewis acid selected among covalent metal-halogen compounds and covalent semimetal-halogen compounds; ii) at least one aprotic organic compound (I) having at least one functional group (FG) which, under polymerization conditions, forms a carbocation or a cationogenic complex with the Lewis acid, in an organic solvent that is inert to the Lewis acid. The inventive method is characterized in that the polymerization is carried out in a tubular continuous flow reactor that has a number of bends with an alternating bending direction.
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公开(公告)号：EP1590379A1
公开(公告)日：2005-11-02
申请号：EP04705417.6
申请日：2004-01-27
发明人： LANG, Gabriele , RATH, Hans, Peter , MACH, Helmut
摘要： Disclosed is a method for functionalizing isobutene polymers with terminal olefinic unsaturation by means of a treatment with the reaction product of a borane source having 0.5 to 1.8 equivalents per mol of borane and an alkene having a molecular weight of less than 250, or by treating the isobutene polymer with the borane source in the presence of the alkene. The reaction mixtures maintain a low viscosity and are easy to stir.
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公开(公告)号：EP1483303A1
公开(公告)日：2004-12-08
申请号：EP03711904.7
申请日：2003-02-27
发明人： LANG, Gabriele , LANGE, Arno , RATH, Hans, Peter , MACH, Helmut
IPC分类号： C08F110/10 , C08F2/38 , C08F4/00 , C08F4/06 , C08F8/00
CPC分类号： C08F110/10 , C08F8/00 , Y10S525/918 , C08F10/10 , C08F2/38 , C08F2/06 , C08F4/00 , C08F2500/03 , C08F2500/02
摘要： The invention relates to a method for producing an isobutene polymer by using a cyclopentene derivative as initiator, the isobutene polymer which is obtained by the inventive method, and certain functionalization products thereof.
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