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公开(公告)号：EP1324826B1
公开(公告)日：2004-09-01
申请号：EP01982272.5
申请日：2001-09-11
发明人： MÜLLER, Ulrich , TELES, Joaquim, Henrique , BERG, Anne , HARDER, Wolfgang , RUDOLF, Peter , REHFINGER, Alwin , BASSLER, Peter , RIEBER, Norbert
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , B01J29/89 , B01J29/90 , Y02P20/584
摘要： The invention relates to a method for regenerating a zeolite catalyst, comprising the thermal treatment of the catalyst in the presence of a gas stream at temperatures above 120 °C, said gas stream containing hydrogen. The regenerated zeolite catalyst can be used in an integrated method for oxidising an alkene using a hydroperoxide.
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公开(公告)号：EP1296968A1
公开(公告)日：2003-04-02
申请号：EP01969340.7
申请日：2001-07-05
发明人： TELES, Joaquim, Henrique , REHFINGER, Alwin , BASSLER, Peter , WENZEL, Anne , RIEBER, Norbert , RUDOLF, Peter
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
摘要： The invention relates to a method for the production of propylene oxide, whereby (i) propylene is reacted with hydrogen peroxide in the presence of methanol to form propylene oxide, resulting in a mixture (Gi), comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) from mixture (Gi) a mixture (Gii), comprising methanol, water and hydrogen peroxide is separated off, yielding a mixture (Ga), comprising propylene oxide. Water is separated off from mixture (Gii) to give a mixture (Giii), comprising methanol and methyl formate.
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公开(公告)号：EP1058677B1
公开(公告)日：2003-01-08
申请号：EP99915533.6
申请日：1999-02-23
发明人： VOIT, Guido , OHLBACH, Frank , LUYKEN, Hermann , MERGER, Martin , REHFINGER, Alwin , FISCHER, Rolf, Hartmuth , BASSLER, Peter , ANSMANN, Andreas
IPC分类号： C07C209/00
CPC分类号： C07C253/30 , B01J23/02 , B01J23/78 , C07C209/48 , C07C211/12 , C07C255/24
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4.发明公开
公开(公告)号：EP1206459A1
公开(公告)日：2002-05-22
申请号：EP00958331.1
申请日：2000-07-31
发明人： TELES, Joaquim, Henrique , REHFINGER, Alwin , BASSLER, Peter , RIEBER, Norbert , WENZEL, Anne , WALCH, Andreas , HARDER, Wolfgang
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The invention concerns a method for reacting an organic compound with a hydroperoxide using at least a heterogeneous catalyst. Said method is characterised in that the pH and the temperature of the reaction medium are modified during the reaction.
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公开(公告)号：EP0927157B1
公开(公告)日：2001-12-05
申请号：EP97940102.3
申请日：1997-08-21
IPC分类号： C07C253/34 , C07C209/84 , C07C255/24 , C07C211/12
CPC分类号： C07C253/30 , C07C209/48
摘要： The invention concerns a process for simultaneously preparing 6-aminocapronitrile and hexamethylene diamine proceeding from adipodinitrile. The process is characterized in that: (1) adipodinitrile is partially hydrogenated in the presence of a catalyst in order to obtain a mixture containing 6-aminocapronitrile, hexamethylene diamine and adipodinitrile; (2) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture; (3) between 0.01 and 10 wt %, relative to adipodinitrile, of an acid or an acidic ion exchanger is added to the part substantially containing adipodinitrile, and the adipodinitrile is separated from the mixture; and (4) the adipodinitrile is returned to step (1).
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公开(公告)号：EP1060158B1
公开(公告)日：2004-04-28
申请号：EP99937925.8
申请日：1999-02-23
发明人： VOIT, Guido , FISCHER, Rolf , BASSLER, Peter , ANSMANN, Andreas , LUYKEN, Hermann , MERGER, Martin , OHLBACH, Frank , REHFINGER, Alwin
IPC分类号： C07C209/48 , C07C211/12
CPC分类号： C07C211/12 , B01J23/745 , C07C209/48
摘要： The invention relates to a method for producing aliphatic alpha-, omega-diamines by hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a catalyst, characterised in that the catalyst used for the hydrogenation contains a) iron or a compound based on iron or mixtures thereof, b) 0.001 to 0.3 wt. % in relation to a) of a promoter based on 2, 3, 4 or 5 elements from the following group: aluminium, silicon, zirconium, titanium and vanadium and c) 0 to 0.3 wt. % in relation to a) of a compound based on an alkaline and/or alkaline earth metal.
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7.发明授权VERFAHREN ZUR ABTRENNUNG VON 2-AMINOMETHYLCYCLOPENTYLAMIN AUS EINER MISCHUNG ENTHALTEND HEXAMETHYLENDIAMIN UND 2-AMINOMETHYLCYCLOPENTYLAMIN 失效方法分离共混含己二胺2 aminomethylcyclopentylamine和2 aminomethylcyclopentylamine
公开(公告)号：EP0931054B1
公开(公告)日：2003-05-28
申请号：EP97942889.3
申请日：1997-08-28
发明人： LUYKEN, Hermann , REHFINGER, Alwin , BASSLER, Peter , VOIT, Guido , FISCHER, Rolf , MERGER, Martin , RUST, Harald
IPC分类号： C07C209/86
CPC分类号： C07C209/86 , C07C211/36 , C07C2601/08 , Y10S203/11 , C07C211/12
摘要： Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.
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8.发明授权VERFAHREN ZUR ABTRENNUNG VON 6-AMINOCAPRONSÄURENITRIL AUS MISCHUNGEN, DIE 6-AMINOCAPRONSÄURENITRIL UND EIN IMIN ENTHALTEN 失效METHOD FOR从AND A MIN含6氨基己腈的混合物中分离6-氨基己腈
公开(公告)号：EP0961768B1
公开(公告)日：2001-09-19
申请号：EP98905375.6
申请日：1998-01-30
发明人： REHFINGER, Alwin , LUYKEN, Hermann
IPC分类号： C07C253/34
CPC分类号： C07C253/34
摘要： The invention relates to a method for separating by distillation 6-aminocaproic acid nitrile from mixtures (I) containing 6-aminocaproic acid nitrile and an imine (II). Said method is characterized in that distillation takes place in a distillation column and that the distillation mixture remains on at least one level of the distillation column for an average period of at least 5 minutes.
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公开(公告)号：EP1107942A1
公开(公告)日：2001-06-20
申请号：EP99944417.7
申请日：1999-08-17
发明人： FISCHER, Rolf , BASSLER, Peter , LUYKEN, Hermann , OHLBACH, Frank , MELDER, Johann-Peter , MERGER, Martin , ANSMANN, Andreas , REHFINGER, Alwin , VOIT, Guido
IPC分类号： C07C209/48 , C07C211/12
CPC分类号： C07C209/48 , C07C211/12
摘要： The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent. The method is characterised in that a) adipodinitrile is hydrogenated at temperatures of 70 to 220 °C and at pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent to produce a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers, until the sum of the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. % in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6-aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).
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10.发明公开VERBESSERTES VERFAHREN ZUR GLEICHZEITIGEN HERSTELLUNG VON 6-AMINOCAPRONITRIL UND HEXAMETHYLENDIAMIN 无效改进方法的6-氨基己腈和六亚甲基二胺同时生产
公开(公告)号：EP1107941A1
公开(公告)日：2001-06-20
申请号：EP99942875.8
申请日：1999-08-17
发明人： LUYKEN, Hermann , OHLBACH, Frank , ANSMANN, Andreas , BASSLER, Peter , FISCHER, Rolf , MELDER, Johann-Peter , MERGER, Martin , REHFINGER, Alwin , VOIT, Guido , ACHHAMMER, Günther
IPC分类号： C07C209/48 , C07C253/30
CPC分类号： C07C253/30 , C07C209/48
摘要： The invention relates to a method for simultaneous preparation of 6-aminocapronitrile and hexamethylene diamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the eight subgroup as catalytically active component to obtain a mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers; b) separating by distillation hexamethylene diamine from the mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers and c1) separating by distillation 6-aminocapronitrile and subsequently d1) separating by distillation adipodinitrile or c2) simultaneously separating by distillation 6-aminocapronitrile and adipodinitrile into separate fractions. The method is characterized in that the temperature of the bottom in steps d1) or c2) is below 185 ° C.
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