公开(公告)号：EP1940892A1

公开(公告)日：2008-07-09

申请号：EP06806459.1

申请日：2006-10-23

申请人： BASF Coatings AG

发明人： TECKLENBORG, Michael ,  GIESEN, Bianca ,  DEYDA, Marco ,  BAUMGART, Hubert ,  RÖCKRATH, Ulrike ,  AUSSMANN, Corinna ,  WOLTERING, Joachim

IPC分类号： C08F220/06 ,  C09D133/06 ,  C09D5/03

CPC分类号： C09D5/031 ,  C08F220/18 ,  C08F220/28 ,  C09D133/06

摘要： The invention relates to structurally viscous, curable, aqueous powder dispersions that are substantially or entirely devoid of organic solvents, and that contain dimensionally stable particles (A), said particles having an average particle size, measured by laser diffraction, of D (v, 0.5) = 1 to 10 µm. The dimensionally stable particles (A) contain as a binder 10 to 100 % by weight of at least one (meth)acrylate copolymer (A1) having a hydroxyl number of 40 to 250 mg KOH/g and an acid number of 5 to 100 mg KOH/g. Said binder is produced by multi-step copolymerization of (a11) hydroxyl-containing acrylate and/or methacrylate monomers and (a12) acid groups-containing, olefinically saturated monomers in an organic solvent, whereby (1) in a step, the entire portion or the major portion of the monomers (a11) is optionally (co)polymerized with a lower portion of the monomers (a12) before (2) in an additional step, the entire portion or the major portion of the monomers (a12) is optionally (co)polymerized with the remainder of the monomers (a11). The invention also relates to a method for producing said dispersions and to their use.

公开(公告)号：EP1409434B1

公开(公告)日：2008-02-13

申请号：EP02764751.0

申请日：2002-07-23

申请人： BASF Coatings AG

发明人： WOLTERING, Joachim ,  TECKLENBORG, Michael ,  OTT, Günther

IPC分类号： C04B41/00 ,  C09D5/00

CPC分类号： C08G18/807 ,  C08G18/0866 ,  C08G18/62 ,  C08G18/6254 ,  C08G2150/20 ,  C09D5/02 ,  C09D5/04 ,  C09K3/10

摘要： The invention relates to structurally viscose clear lacquer slurry containing strong and/or highly viscose particles which are dimensionally stable when stored or used, and at least one water-soluble salt, preferably 0.1 to 50 mmol per 1000 g water, said salt being residue-free or essentially residue-free decomposable. The invention also relates to a method for the production and use thereof.

摘要翻译： 本发明涉及包含当储存或使用时尺寸稳定的强和/或高粘度颗粒以及至少一种水溶性盐，优选0.1至50mmol / 1000g水的结构性粘胶清漆涂料浆料， 不含或基本无残留可分解。 本发明还涉及一种生产和使用它的方法。

公开(公告)号：EP1332186A1

公开(公告)日：2003-08-06

申请号：EP01993655.8

申请日：2001-11-08

申请人： BASF Coatings AG

发明人： WOLTERING, Joachim ,  OTT, Günther ,  RAKA, Fatmir ,  FLORACK, Heike

IPC分类号： C09D5/02

CPC分类号： C08G18/6254 ,  C08G18/8025 ,  C08G18/807 ,  C08G2150/20 ,  C09D175/04

摘要： The invention relates to a structurally viscous powder clearcoat slurry that is free from organic solvents and external emulsifiers and that comprises solid and/or highly viscous particles that are dimensionally stable under the conditions of storage and use. The slurry is characterized in that 1) the particles (1.1) have an average particle size of 1.0 to 20 νm, with 99 % of the particles having a particle size of ≤30 νm, and 1.2) contain, as the binder, at least one polyol with an OH number >110 mg KOH/g, containing potentially ionic groups. Furthermore, 2) the powder clearcoat slurry has 2.1) a content of potentially ionic groups of 0.05 to 1 meq/g of the solid body, 2.2) at a neutralization degree of not more than 50 % a content in ionic groups produced by neutralization of the potentially ionic groups of 0.005 to 0.1 meq/g of the solid body, and 2.3) a viscosity of (i) 50 to 1000 mPas at a shearing rate of 1000 s-1, (ii) 150 to 8000 mPas at a shearing rate of 10 s-1 and (iii) 180 to 12000 mPas at a shearing rate of 1 s-1. The invention further relates to the use of the corresponding slurries.

摘要翻译： 本发明涉及一种不含有机溶剂和外部乳化剂并且包含在储存和使用条件下尺寸稳定的固体和/或高粘度颗粒的结构粘稠粉末透明涂层浆料。 该浆料的特征在于：1）颗粒（1.1）具有1.0至20νm的平均粒度，其中99％的颗粒具有≤30νm的粒度，并且1.2）至少含有作为粘合剂的至少一种 一种OH值> 110mg KOH / g的多元醇，含有潜在的离子基团。 此外，2）粉末清漆浆料具有2.1）潜在离子基团含量为0.05至1meq / g固体，2.2）中和度不超过50％的离子基团的含量通过中和 0.005至0.1毫当量/克固体的潜在离子基团和2.3）在1000s -1的剪切速率下（i）50至1000mPas的粘度，（ii）在剪切速率下150至8000mPas 10 s-1和（iii）180至12000 mPas，剪切速率为1 s-1。 本发明还涉及相应浆料的用途。

公开(公告)号：EP1017750B1

公开(公告)日：2003-04-09

申请号：EP98951333.8

申请日：1998-08-29

申请人： BASF Coatings AG

发明人： SCHWARTE, Stephan ,  WOLTERING, Joachim ,  BAUMGART, Hubert

IPC分类号： C09D133/14 ,  C09D5/03 ,  C09D5/02

CPC分类号： C09D133/068 ,  C08G59/42 ,  C08G59/4238 ,  C08L61/32 ,  C08L2666/14 ,  C08L2666/28

摘要： A clear powder coating contains (a) at least one epoxide-containing binder with 20 to 45 wt.%, preferably 25 to 40 wt.% glycidyl-containing monomers, and optional vinyl aromatic compounds, preferably styrene; (b) tris(alkoxycarbonylamino)triazine and polycarboxylic acids, preferably straight-chain aliphatic dicarboxylic acids and/or carboxyfunctional polyesters as cross-linking agents; and (c) optional catalysts, auxiliary substances and additives typical of clear powder coatings, such as degassifiers, levelling agents, UV absorbers, free-radical scavengers and antioxidants.

公开(公告)号：EP1119592B1

公开(公告)日：2004-11-17

申请号：EP99942853.5

申请日：1999-08-11

申请人： BASF Coatings AG

发明人： OTT, Günther ,  WOLTERING, Joachim ,  RÖCKRATH, Ulrike ,  WONNEMANN, Heinrich ,  SCHWARTE, Stephan

IPC分类号： C09D133/14 ,  C09D5/03 ,  C09D5/02

CPC分类号： C09D163/00 ,  C08G59/3209 ,  C08L61/32 ,  C09D5/02 ,  C09D133/068 ,  C08L2666/14 ,  C08L2666/28

摘要： The invention relates to novel powder clear varnish and novel powder clear varnish slurries consisting of: a) at least one epoxide-containing binder containing, in relation to the binder, 0.5 to 40 % by weight of a polymerized monomer containing glycidyl groups and b) at least one tris(alkoxycarbonylamino)triazine and at least one polycarboxylic acid, especially a straight-chained dicarboxylic acid and/or a carboxy-functional polyester as crosslinking agent or, alternatively, a) at least one tris(alkoxycarbonylamino)triazine and at least one oligomeric or polymeric epoxide-containing crosslinking agent containing, in relation to the crosslinking agent, 0.5 to 40 % by weight of a polymerized monomer containing glycidyl groups and/or low molecular epoxide-containing crosslinking agent and b) at least one polymer containing carboxyl groups as binder, wherein both variants contain at least one polyol c).

公开(公告)号：EP1412436A1

公开(公告)日：2004-04-28

申请号：EP02751157.5

申请日：2002-07-23

申请人： BASF Coatings AG

发明人： RAKA, Fatmir ,  WOLTERING, Joachim ,  FLORACK, Heike

IPC分类号： C09D5/02 ,  C09D133/06

CPC分类号： C09D5/027 ,  C08L71/02 ,  C09D5/02 ,  C09D133/10 ,  C08L2666/22

摘要： The invention relates to structurally viscose clear lacquer slurry containing strong and/or highly viscose particles which are dimensionally stable when stored or used, and at least one cross-linking agent which is selected from the group consisting of alkyoxylated fatty alcohols with 16 to 18 carbon atoms in the alkyl residue and in the statistical agent at least 20 oxaalkandiyl groups in the molecule. The invention also relates to the method for the production and use thereof.

摘要翻译： 本发明涉及含有在储存或使用时尺寸稳定的强和/或高粘度颗粒以及至少一种选自具有16至18碳的烷氧基化脂肪醇的交联剂的结构性粘胶清漆漆浆 烷基残基中的原子和统计试剂中分子中至少20个氧杂二烷基。 本发明还涉及其生产和使用的方法。

公开(公告)号：EP1373347A1

公开(公告)日：2004-01-02

申请号：EP02727498.4

申请日：2002-03-28

申请人： BASF Coatings AG

发明人： WILKE, Guido ,  RÖCKRATH, Ulrike ,  WOLTERING, Joachim ,  WEGNER, Egon ,  BAUMGART, Hubert ,  OTT, Günther

IPC分类号： C08G18/08 ,  C08G18/62 ,  C08G18/80 ,  C09D175/16

CPC分类号： C08G18/0866 ,  C08G18/6254 ,  C08G18/807 ,  C08G2150/20 ,  C09D175/16

摘要： The invention relates to powder slurries which can be hardened thermally and by means of actinic radiation, and which contain solid and/or highly viscous particles which are dimensionally stable under conditions of storage and use. Said particles contain (A) a binding agent which is free of carbon-carbon double bonds which can be activated by means of actinic radiation, said binding agent containing at least one (meth)acrylate copolymer having a statistical mean of at least one isocyanate-reactive functional group and at least one ionic group in the molecule, (B) at least one blocked and/or unblocked polyisocyanate, and (C) at least one olefinically unsaturated constituent which is free of isocyanate-reactive functional groups and has a statistical mean of more than four carbon-carbon double bonds which can be activated by means of actinic radiation in the molecule, and at least one hardening segment in the molecule. The invention also relates to a method for producing said slurries and the use of the same.

公开(公告)号：EP1015519A1

公开(公告)日：2000-07-05

申请号：EP98945298.2

申请日：1998-08-29

申请人： BASF Coatings AG

发明人： SCHWARTE, Stephan ,  WOLTERING, Joachim ,  BAUMGART, Hubert

IPC分类号： C09D5/02 ,  C09D133/14

CPC分类号： C08G59/4238 ,  C08G59/42 ,  C08L61/32 ,  C09D133/068 ,  C08L2666/14

摘要： The invention relates to a clear powder varnish dispersion containing a solid powdery component A and an aqueous component B. Component A is a clear powder varnish containing a) at least one epoxide-containing binder with 30 to 45 wt. %, preferably 30 to 35 wt. % glycidyl-containing monomers, and optional vinyl aromatic compounds, preferably styrene; b) tris(alkoxycarbonylamino)triazine and polycarboxylic acids, preferably straight-chain aliphatic dicarboxylic acids and/or carboxyfunctional polyesters as cross-linking agents; and c) optional catalysts, auxiliary agents and additives typical of clear powder varnishes such as degasifiers, leveling agents, UV absorbers, free-radical scavengers and antioxidants. Component B is an aqueous dispersion containing a) at least one non-ionic thickener and b) optional catalysts, auxiliary agents, antifoaming agents, wetting agents, dispersion auxiliary agents, preferably carboxyfunctional dispersion agents, antioxidants, UV absorbers, free-radical scavengers, biocides, low amounts of solvents, leveling agents, neutralizing agents, preferably amines and/or water retentive agents.

公开(公告)号：EP0826018A2

公开(公告)日：1998-03-04

申请号：EP96916028.0

申请日：1996-05-09

申请人： BASF Coatings AG

发明人： MÖLLER, Dietmar ,  WOLTERING, Joachim

IPC分类号： C09D5 ,  C08J3 ,  C09D163

CPC分类号： C09D163/00 ,  C08J3/03 ,  C09D5/02

摘要： The present invention concerns an aqueous powder coating dispersion consisting of a solid powder component A and an aqueous component B. Component A is a powder coating containing (a) at least one epoxy-containing binder including a quantity (30-45 %, preferably 30-35 %) of glycidyl-containing monomers, optionally containing vinyl-aromatic compounds, preferably styrene; (b) at least one cross-linking agent, preferably straight-chain aliphatic dicarboxylic acids and/or carboxy-functional polyesters; and (c) optionally, catalysts, auxiliary agents, powder-coating typical additives such as de-gassing agents, levelling agents, UV-absorbents, radical capturers and antioxidants. Component (B) is an aqueous dispersion containing (a) at least one non-ionic thickening agent; and (b) optionally, catalysts, auxiliary agents, antifoaming agents, dispergents, wetting agents, preferably carboxy-functional dispergents, antioxidants, UV-absorbents, radical capturers, biocides, small quantities of solvents and/or water retaining agents. Also object of the invention is a process for producing the powder coating dispersion and the use of the dispersion for motor vehicle bodies.

公开(公告)号：EP1412442B1

公开(公告)日：2008-06-04

申请号：EP02754925.2

申请日：2002-07-23

申请人： BASF Coatings AG

发明人： WOLTERING, Joachim ,  RAKA, Fatmir ,  RÖCKRATH, Ulrike ,  BÖHMER, Ute

IPC分类号： C09D133/10 ,  C09D5/02 ,  B05D7/26 ,  C09J5/00

CPC分类号： C09D133/10 ,  C08G18/6254 ,  C08G18/807 ,  C08G2190/00 ,  C09D175/04 ,  C09J133/10

摘要： Intrinsically-viscous clear-lacquer slurry, comprising solid and/or highly viscous particles which are dimensionally-stable under conditions of storage and application, containing methacrylate copolymers as binding agent, which, relative to a given methacrylate copolymer, comprises at least 90 wt. % of methacrylate comonomers, including (meth)acrylate comonomers with potentially ionic groups. The invention also relates to a method for production and use thereof.

摘要翻译： 包含固体和/或高粘度颗粒的本质上粘稠的清漆浆料，其在储存和应用条件下尺寸稳定，含有甲基丙烯酸酯共聚物作为粘合剂，其相对于给定的甲基丙烯酸酯共聚物包含至少90wt。 ％的甲基丙烯酸酯共聚单体，包括具有潜在离子基团的（甲基）丙烯酸酯共聚单体。 本发明还涉及一种生产和使用它的方法。