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    VERFAHREN ZUR HERSTELLUNG VON CHLOR AUS HCI
    3.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR AUS HCI 有权
    用于生产氯FROM HCI

    公开(公告)号：EP2445831A1

    公开(公告)日：2012-05-02

    申请号：EP10725697.6

    申请日：2010-06-17

    申请人： BASF SE

    发明人： KARCHES, Martin ,  BACHMANN, Kati ,  SESING, Martin ,  SEIDEMANN, Lothar ,  JACOBSEN, Knud

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04

    摘要： The invention relates to a method for producing chlorine by the oxidation of hydrogen chloride with oxygen in a fluidized bed reactor in the presence of a particulate catalyst, the reaction heat produced by the exothermic hydrogen chloride oxidation being carried away by water which circulates in the tubes of a shell-and-tube heat exchanger. The method comprises the following steps: (i) heating the fluidized bed reactor to an operating temperature in the range of 350 to 420°C in a heating phase and (ii) reacting the hydrogen chloride with oxygen at the operating temperature in an operating phase. The method is characterized in that (i-1) the fluidized bed reactor is heated to a temperature below the operating temperature in a first heating phase, and (i-2) hydrogen chloride and oxygen are fed to the fluidized bed reactor and reacted in a second heating phase, the fluidized bed reactor being heated to the operating temperature by the reaction heat produced by the exothermic hydrogen chloride oxidation.

    VERFAHREN ZUR HERSTELLUNG VON CHLOR
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR 有权

    公开(公告)号：EP2414283A1

    公开(公告)日：2012-02-08

    申请号：EP10710046.3

    申请日：2010-03-25

    申请人： BASF SE

    发明人： KARCHES, Martin ,  BACHMANN, Kati ,  SESING, Martin ,  RUMPF, Bernd ,  ODENWALD, Oliver ,  SEIDEMANN, Lothar

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04

    摘要： A process is proposed for preparing chlorine by oxidizing hydrogen chloride in the presence of a heterogeneous particulate catalyst by the Deacon process in a fluidized bed reactor (1), wherein the heat of reaction is removed by evaporative cooling with water which circulates in the tubes (2) of a shell and tube heat exchanger, wherein the water is supplied from a steam drum (4) via a feed line (5) to the tubes (2) of the shell and tube heat exchanger at one end thereof, it heats up in the tubes (2) by absorbing the heat of reaction and evaporates partly to obtain a water/steam mixture which is passed back into the steam drum (4) via a return line (6) at the other end of the tubes (2) of the shell and tube heat exchanger, which is characterized in that the maximum pressure for which the fluidized bed reactor (1) has to be designed for the event of fracture of a tube (2) of the shell and tube heat exchanger is minimized by introducing a valve (7) into the feed line (5) and into the return line (6), said valve (7), in the event of a pressure rise owing to the fracture of a tube (2), blocking the feed line (5) and the return line (6), thus preventing water from flowing out of the steam drum (4) into the fluidized bed reactor (1).

    摘要翻译： 提出了一种通过在流化床反应器（1）中通过Deacon法在非均相颗粒催化剂存在下氧化氯化氢来制备氯气的方法，其中反应热通过用在管中循环的水进行蒸发冷却而除去 2）的壳管式热交换器，其中水从蒸汽鼓（4）经由供给管线（5）供给到其一端的壳管式热交换器的管（2），其加热 在管（2）中通过吸收反应热并且部分地蒸发以获得水/蒸汽混合物，所述水/蒸汽混合物经由管（2）的另一端处的返回管线（6）返回到蒸汽鼓（4） 其特征在于，流化床反应器（1）必须设计用于壳管式热交换器的管（2）断裂事件的最大压力最小化为 将阀（7）引入进料管线（5）和进料管中 所述阀（7）在由于管（2）的断裂而导致压力升高的情况下阻塞供给管线（5）和返回管线（6），从而防止水流动 离开蒸汽鼓（4）进入流化床反应器（1）。

    GASVERTEILERDÜSE
    7.
    发明公开
    GASVERTEILERDÜSE 审中-公开

    公开(公告)号：EP3077097A1

    公开(公告)日：2016-10-12

    申请号：EP14805930.6

    申请日：2014-12-03

    申请人： BASF SE

    发明人： GARELLA, Dominik ,  BACHMANN, Kati

    IPC分类号： B01J8/44 ,  B01J4/00 ,  F16K15/06 ,  B01J8/18

    CPC分类号： B01J8/1818 ,  B01J4/002 ,  B01J4/007 ,  B01J8/1809 ,  B01J8/24 ,  B01J8/44 ,  B01J2208/00548 ,  B01J2208/00902

    摘要： The invention relates to a gas distribution nozzle (25), comprising a vertically upwardly directed gas inlet (1) and a floating body (13), by means of which an outlet opening from the gas inlet (1) can be closed, when no gas is flowing, wherein the floating body (13) has a centre of gravity that lies below a point of application of force of the gas flow. The invention further relates to a reactor having a solid bed and at least one gas distribution nozzle (25).

    摘要翻译： 本发明涉及一种气体分配喷嘴（25），其包括垂直向上定向的气体入口（1）和浮体（13），借助于该浮体可以关闭来自气体入口（1）的出口开口， 气体在流动，其中浮体（13）的重心位于气流力的作用点之下。 本发明还涉及具有固体床和至少一个气体分配喷嘴（25）的反应器。

    VERFAHREN ZUR HERSTELLUNG VON CHLOR DURCH GASPHASENOXIDATION VON CHLORWASSERSTOFF IN EINEM WIRBELSCHICHTREAKTOR
    9.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR DURCH GASPHASENOXIDATION VON CHLORWASSERSTOFF IN EINEM WIRBELSCHICHTREAKTOR 审中-公开
    用于生产氯氯化氢气相氧化流化床反应器

    公开(公告)号：EP2462054A1

    公开(公告)日：2012-06-13

    申请号：EP10737322.7

    申请日：2010-07-28

    申请人： BASF SE

    发明人： KARCHES, Martin ,  BACHMANN, Kati ,  SESING, Martin ,  SEIDEMANN, Lothar ,  PILZ, Michael

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04 ,  B01J8/0055 ,  B01J8/18

    摘要： The invention relates to a method for producing chlorine by gas phase oxidation of hydrogen chloride on a heterogeneous, particulate catalyzer in a fluidized-bed reactor, obtaining a product gas mixture that is freed of any carried catalyzer particles in cyclones (1) disposed in the upper region of the fluidized-bed reactor, comprising a cylindrical upper part (2) having a tangential or spiral inlet (3) for the product gas mixture and narrowing at the lower end thereof via a conical part (4) into a cyclone downpipe (5), and a central immersion pipe (6) in the upper region of the cyclone (1) for diverting the product gas mixture freed of the carried catalyzer particles, characterized in that – one to seven cascades of two to five cyclones each connected in series are used, wherein the cyclones (1) of each cascade, except for the cyclone (1) first permeated, which is designed that approximately 90 to 99% by weight of the carried catalyst particles are precipitated, each comprise a trickle valve (7) at the lower end of the cyclone downpipe (5) comprising an angled pipe terminator (8) and a loose flap valve (9) suspended at an angle α to the vertical, wherein the angle α and the weight of the flap valve (9) are designed so that the torque of the flap valve (9) based on the diameter of the outlet opening out of the angled pipe terminator (8) is in the range of 2 to 300 N/m
    2 .