ABSCHEIDEVORRICHTUNG MIT EINEM GRAVITATIONSVORABSCHEIDER GEFOLGT VON EINEM ZENTRIFUGALABSCHEIDER
    4.
    发明公开

    公开(公告)号:EP2512684A1

    公开(公告)日:2012-10-24

    申请号:EP10798032.8

    申请日:2010-12-13

    Applicant: BASF SE

    CPC classification number: B01D45/12 B04C5/04 B04C5/13 B04C5/181 B04C9/00

    Abstract: The invention relates to a device for precipitating liquid droplets from a feed gas flow containing said droplets, comprising a residence time tank (1) for preliminarily precipitating part of the liquid droplets from the feed gas flow under the effect of gravity, having an inlet line (2) for the feed gas flow into the residence time tank (1) and a discharge line (3) for the gas flow having reduced liquid droplet content and flowing out of the residence time tank (1), and tangential feeding of same to a centrifugal drop separator (4), wherein the discharge line (3) is disposed in the upper region of the residence time tank (1) and is spaced apart from the inlet line (2) to the extent that the residence time of the gas flow in the residence time tank (1) is a maximum, and having a discharge line (5) for the fluid precipitated in the residence time tank (1) on the floor of same, and wherein an axially symmetrical apparatus having a vertical longitudinal axis and circular cross section, having a jacket and hoods at the upper and lower ends of the jacket, is used as the centrifugal drop separator (4), and wherein a discharge fitting (6) for the liquid precipitated in the centrifugal drop separator (4) is disposed in the region of the bottom hood of the centrifugal drop separator (4), dimensioned such that said fitting is immersed in the liquid standing on the floor of the residence time tank (1) or in a liquid standing in a cup in the interior of the residence time tank (1), and having a gas outlet fitting (7) at the upper end of the centrifugal drop separator (4) for the gas flow further purified in the centrifugal drop separator (4),and wherein both the feeding of the gas flow having reduced liquid droplet content from the residence time tank (1) through the discharge line (3) and the draining of the liquid precipitated in the centrifugal drop separator (4) take place via the line (6) into the residence time tank (1) without the use of pumps and shutoff valves.

    VERFAHREN ZUR HERSTELLUNG VON CHLOR DURCH GASPHASENOXIDATION VON CHLORWASSERSTOFF IN EINEM WIRBELSCHICHTREAKTOR
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CHLOR DURCH GASPHASENOXIDATION VON CHLORWASSERSTOFF IN EINEM WIRBELSCHICHTREAKTOR 审中-公开
    用于生产氯氯化氢气相氧化流化床反应器

    公开(公告)号:EP2462054A1

    公开(公告)日:2012-06-13

    申请号:EP10737322.7

    申请日:2010-07-28

    Applicant: BASF SE

    CPC classification number: C01B7/04 B01J8/0055 B01J8/18

    Abstract: The invention relates to a method for producing chlorine by gas phase oxidation of hydrogen chloride on a heterogeneous, particulate catalyzer in a fluidized-bed reactor, obtaining a product gas mixture that is freed of any carried catalyzer particles in cyclones (1) disposed in the upper region of the fluidized-bed reactor, comprising a cylindrical upper part (2) having a tangential or spiral inlet (3) for the product gas mixture and narrowing at the lower end thereof via a conical part (4) into a cyclone downpipe (5), and a central immersion pipe (6) in the upper region of the cyclone (1) for diverting the product gas mixture freed of the carried catalyzer particles, characterized in that – one to seven cascades of two to five cyclones each connected in series are used, wherein the cyclones (1) of each cascade, except for the cyclone (1) first permeated, which is designed that approximately 90 to 99% by weight of the carried catalyst particles are precipitated, each comprise a trickle valve (7) at the lower end of the cyclone downpipe (5) comprising an angled pipe terminator (8) and a loose flap valve (9) suspended at an angle α to the vertical, wherein the angle α and the weight of the flap valve (9) are designed so that the torque of the flap valve (9) based on the diameter of the outlet opening out of the angled pipe terminator (8) is in the range of 2 to 300 N/m
    2 .

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