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    DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS
    3.
    发明公开
    DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS 审中-公开
    DITHIENOPHTHALIMID半导体聚合物

    公开(公告)号：EP2729514A1

    公开(公告)日：2014-05-14

    申请号：EP12731460.7

    申请日：2012-07-04

    申请人： BASF SE

    发明人： NOGUCHI, Hiroyoshi ,  DÖTZ, Florian ,  MISHRA, Ashok, Kumar ,  VAIDYANATHAN, Subramanian ,  MINH-TIEN, Mai

    IPC分类号： C08G61/12 ,  C09K11/00 ,  H01B1/00 ,  H01L51/00

    CPC分类号： H01L51/0036 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/3327 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0558 ,  Y02E10/549

    摘要： The invention concerns apolymer of the formula (I): wherein: M1 is an optionally substituted dithienophthalimide formula (II): wherein: X is N or C-R, wherein R is H or a C
    1 -C
    40 alkyl group, R
    1 , at each occurrence, is independently selected from H, a C
    1-40 alkyl group, a C
    2-40 alkenyl group, a C
    1-40 haloalkyl group, and a monocyclicor polycyclic moiety, wherein: each of the C
    1-40 alkyl group, the C
    2-40 alkenyl group, and the C
    1-40 haloalkyl group can be optionally substituted with 1-10 substituents independently selected from a halogen, CN, -NO
    2 , OH, NH
    2 , -NH(C
    1-20 alkyl), N(C
    1-20 alkyl)
    2 , -S(O)
    2 OH, -CHO, -C(O)-C
    1-20 alkyl, -C(O)OH, -C(O)-OC
    1-20 alkyl, -C(O)NH
    2 , -C(O)NH-C
    1-20 alkyl, -C(O)N(C
    1-20 alkyl)
    2 , -OC
    1-20 alkyl, -SiH
    3 , -SiH(C
    1-20 alkyl)
    2 , -SiH
    2 (C
    1-20 alkyl), and -Si(C
    1-20 alkyl)
    3 ; and the monocyclic or polycyclic moiety can be covalently bonded to the imide nitrogen via an optional linker, and can be optionally substituted with 1-5 substituentsindependently selected from a halogen, oxo, -CN, -NO
    2 , OH, =C(CN)
    2 , -NH
    2 , -NH(C
    1-20 alkyl), N(C
    1-20 alkyl)
    2 , -S(O)
    2 OH,-CHO, -C(O)OH, -C(O)-C
    1-20 alkyl, -C(O)-OC
    1-20 alkyl, -C(O)NH
    2 , -C(O)NH-C
    1-20 alkyl, -C(O)N(C
    1-20 alkyl)
    2 , -SiH
    3 , -SiH(C
    1-20 alkyl)
    2 , -SiH
    2 (C
    1-20 alkyl), -Si(C
    1-20 alkyl)
    3 ,-O-C
    1-20 alkyl, -O-C
    1-20 alkenyl, -O-C
    1-20 haloalkyl, C
    1-20 alkyl, C
    1-20 alkenyl, C
    1-20 haloalkyl, C
    7-20 arylalkyl, C
    6-20 aryloxy and C
    7-20 arylcarbonyl. M
    2 is a repeating unit comprising one or more cyclic moieties; and n is an integer between 2 and 5,000.