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公开(公告)号：EP2099732A1
公开(公告)日：2009-09-16
申请号：EP07848497.9
申请日：2007-12-11
IPC分类号： C07C6/04 , C07C11/107
CPC分类号： C10L1/06 , B01J21/04 , B01J31/121 , B01J37/0209 , B01J2531/66 , C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/107
摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminium, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600 °C, under a total absolute pressure of 0.01 to 100 MPa.
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公开(公告)号：EP2099732B1
公开(公告)日：2011-08-10
申请号：EP07848497.9
申请日：2007-12-11
IPC分类号： C07C6/04 , C07C11/107
CPC分类号： C10L1/06 , B01J21/04 , B01J31/121 , B01J37/0209 , B01J2531/66 , C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/107
摘要： The present invention relates to a process for manufacturing neohexene, comprising contacting isobutene with a supported catalyst comprising a tungsten compound chosen from tungsten hydrides, organometallic tungsten compounds and organometallic tungsten hydrides, and a support comprising an oxide of aluminium, so as to form a reaction mixture comprising neohexene, and preferably separating neohexene from the reaction mixture, so as to isolate it. The contacting leads to the direct production of neohexene, in particular in a single (reaction) stage and with a high molar selectivity for neohexene. The contacting can be performed at a temperature of 50 to 600 °C, under a total absolute pressure of 0.01 to 100 MPa.
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公开(公告)号：EP2102136A1
公开(公告)日：2009-09-23
申请号：EP07848602.4
申请日：2007-12-18
发明人： Basset, Jean-Marie , Chakka, Sudhakar , Soulivong, Daravong , Taoufik, Mostafa , Thivolle-cazat, Jean
CPC分类号： C07C6/10 , C07C2521/08 , C07C2531/12 , C07C9/10 , C07C9/14 , C07C9/08
摘要： The present invention relates to a process for converting methane into a higher alkane mixture, preferably a liquid alkane mixture, comprising (C3+) alkanes having 3 carbon atoms and more, preferably (C4+) alkanes having 4 carbon atoms, especially (C5+) alkanes having 5 carbon atoms and more. The process comprises: - a stage (1) comprising contacting methane with a metal catalyst (C1) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, so as to form by a non-oxidative methane coupling reaction a mixture (M1) comprising ethane and hydrogen, - preferably a stage (2) comprising fractionating the mixture (M1) so as to separate and to isolate the ethane, and - a stage (3) comprising, preferably simultaneously, (i) contacting the mixture (M1) or preferably the ethane isolated in stage (2) with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, said catalyst being identical to or different from catalyst (C1), so as to form by simultaneous ethane self- and cross-metathesis reactions a mixture (M2) comprising methane and the higher alkane mixture, and (ii) fractionating the mixture (M2) so as to separate and to isolate said higher alkane mixture, preferably in liquid form, and particularly the methane which is preferably recycled into stage (1). The hydrogen produced in stage (1) is preferably separated and isolated in stage (2) and then used for various applications and stages, e.g. for producing thermal and/or electrical energies preferably employed to run the process.
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