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    PROCESS FOR CONVERTING METHANE INTO A HIGHER ALKANE MIXTURE.
    2.
    发明公开
    PROCESS FOR CONVERTING METHANE INTO A HIGHER ALKANE MIXTURE. 审中-公开
    用于甲烷在十九烷的混合物转化

    公开(公告)号：EP2102136A1

    公开(公告)日：2009-09-23

    申请号：EP07848602.4

    申请日：2007-12-18

    申请人： BP Oil International Limited

    发明人： Basset, Jean-Marie ,  Chakka, Sudhakar ,  Soulivong, Daravong ,  Taoufik, Mostafa ,  Thivolle-cazat, Jean

    IPC分类号： C07C6/10 ,  C07C9/08 ,  C07C9/10 ,  C07C9/14

    CPC分类号： C07C6/10 ,  C07C2521/08 ,  C07C2531/12 ,  C07C9/10 ,  C07C9/14 ,  C07C9/08

    摘要： The present invention relates to a process for converting methane into a higher alkane mixture, preferably a liquid alkane mixture, comprising (C3+) alkanes having 3 carbon atoms and more, preferably (C4+) alkanes having 4 carbon atoms, especially (C5+) alkanes having 5 carbon atoms and more. The process comprises: - a stage (1) comprising contacting methane with a metal catalyst (C1) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, so as to form by a non-oxidative methane coupling reaction a mixture (M1) comprising ethane and hydrogen, - preferably a stage (2) comprising fractionating the mixture (M1) so as to separate and to isolate the ethane, and - a stage (3) comprising, preferably simultaneously, (i) contacting the mixture (M1) or preferably the ethane isolated in stage (2) with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, said catalyst being identical to or different from catalyst (C1), so as to form by simultaneous ethane self- and cross-metathesis reactions a mixture (M2) comprising methane and the higher alkane mixture, and (ii) fractionating the mixture (M2) so as to separate and to isolate said higher alkane mixture, preferably in liquid form, and particularly the methane which is preferably recycled into stage (1). The hydrogen produced in stage (1) is preferably separated and isolated in stage (2) and then used for various applications and stages, e.g. for producing thermal and/or electrical energies preferably employed to run the process.

    Process for converting methane into liquid alkane mixtures
    3.
    发明公开
    Process for converting methane into liquid alkane mixtures 审中-公开
    Verfahren zur Umwandlung von Methan在flüssigeAlkangemische

    公开(公告)号：EP2022772A1

    公开(公告)日：2009-02-11

    申请号：EP07253120.5

    申请日：2007-08-09

    申请人： BP OIL INTERNATIONAL LIMITED

    发明人： Basset, Jean-Marie ,  Taoufik, Mostafa ,  Thivolle-Cazat, Jean ,  Chakka, Sudhakar

    IPC分类号： C07C2/76 ,  C07C6/08 ,  C07C9/00

    CPC分类号： C07C9/00 ,  C07C2/76 ,  C07C2/78 ,  C07C2/80 ,  C07C5/08 ,  C07C6/10 ,  C07C7/09 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/44 ,  C07C2531/12 ,  C10G50/00 ,  Y02P20/127 ,  C07C11/24 ,  C07C9/06

    摘要： The present invention relates to a process for converting methane into a liquid mixture of (C 3+ ) alkanes having 3 carbon atoms and more, preferably (C 4+ ) alkanes having 4 carbon atoms and more, especially (C 5+ ) alkanes having 5 carbon atoms and more. It comprises a stage (1) comprising converting methane into acetylene, performed by submitting methane to a thermal cracking reaction, so as to form a reaction mixture (M1) comprising acetylene and hydrogen, a stage (2) comprising converting acetylene into ethane, performed by contacting the acetylene or the reaction mixture (M1) previously obtained with hydrogen in the presence of a hydrogenation catalyst (C1), so as to form a reaction mixture (M2) comprising ethane, a stage (3) comprising simultaneous ethane self- and cross-metathesis reactions performed by contacting the ethane or the reaction mixture (M2) previously obtained with a metal catalyst (C2) capable of producing, in contact with alkane, reactions involving the splitting and recombining of C-C and/or C-H and/or C-metal bonds, so as to form a reaction mixture (M3) comprising methane and a mixture of the (C 3+ ), preferably the (C 4+ ), especially the (C 5+ ) alkanes, and a stage (4) comprising fractionating the reaction mixture (M3) so as to separate and to isolate said mixture in liquid form. Preferably, the methane is also separated in stage (4) and recycled into stage (1) for methane conversion into acetylene

    摘要翻译： 本发明涉及将甲烷转化成具有3个碳原子的（C 3+）烷烃和更多（优选（C 4+）具有4个碳原子的（C 4+）烷烃，更优选（C 5+）烷烃）的液体混合物的方法， 5个碳原子和更多。 它包括一个阶段（1），包括将甲烷转化成乙炔，通过将甲烷送入热裂解反应进行，以形成包括乙炔和氢的反应混合物（M1），包括将乙炔转化为乙烷的阶段（2） 通过在氢化催化剂（C1）的存在下将预先获得的乙炔或预先获得的反应混合物（M1）与乙烷接触，形成包含乙烷的反应混合物（M2），阶段（3）包括同时进行乙烷自身和 通过使先前获得的乙烷或反应混合物（M2）与能够与烷烃接触的金属催化剂（C2）接触涉及CC和/或CH和/或C的分解和重组的反应进行交叉复分解反应 金属键，以便形成包含甲烷和（C 3+），优选（C 4+），特别是（C 5+）烷烃的混合物的反应混合物（M3）和级（4） 包括分馏反应混合物 （M3），以分离和分离液体形式的所述混合物。 优选地，甲烷也在阶段（4）中分离并再循环到阶段（1）中，用于甲烷转化成乙炔