公开(公告)号：EP1831945B1

公开(公告)日：2008-04-30

申请号：EP05809230.5

申请日：2005-10-18

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GAUBICHER, Joël ,  GUYOMARD, Dominique ,  DUBARRY, Matthieu ,  DESCHAMPS, Marc ,  MOREAU, Philippe

IPC分类号： H01M4/48 ,  H01M10/40 ,  C01G31/02 ,  C01D15/02 ,  C01B31/00

CPC分类号： H01M4/622 ,  B01J23/22 ,  H01M4/133 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2004/028 ,  Y10S977/773 ,  Y10S977/811 ,  Y10T428/292 ,  Y10T428/2993

摘要： The invention relates to a nanostructured material. Said material is a nanostructured carbon material consisting of agglomerates of small needles of Li1+aV3O8 and ßLixV2O5 (0,l≤ α ≤ 0,25 et 0,03 ≤ x ≤ 0,667 surrounded by a discontinuous coating of spherical carbon particles. It is obtained by means of a process consisting in preparing a carbon precursor gel by bringing carbon, V2O5- α an a Li precursor into contact with each other, the amounts thereof being such that the ratio of concentrations [V2O5]/[Li] ranges from 1.15 to 1.5, and the mass ratio (carbon)/ (carbon + V2O5+ Li precursor) is 10 to 15, and in subjecting the gel to heat treatment including a first stage at 8O0C - 15O0C pendant 3-12 h, and a second stage between 3000C and 35O0C, during 10 mins to 1 hour, in a nitrogen or argon atmosphere. n. Applications: positive-electrode active material.

公开(公告)号：EP1831110A1

公开(公告)日：2007-09-12

申请号：EP05809319.6

申请日：2005-10-18

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GAUBICHER, Joël ,  MOREL, Benoit ,  DUBARRY, Matthieu ,  GUYOMARD, Dominique ,  DESCHAMPS, Marc

IPC分类号： C01G31/00 ,  H01M4/58

CPC分类号： H01M4/131 ,  C01G31/00 ,  H01M4/136 ,  H01M4/485 ,  H01M4/5825 ,  H01M4/62 ,  H01M10/0525 ,  Y02E60/122

摘要： The invention relates to a lithium and vanadium oxide. The oxide corresponds to formula Li1+α V3O8 (0,1≤ α ≤0,25) and is made up of agglomerates of small needles whose length L is 400 - 1000 nm, whose width is such that 10

摘要翻译： 本发明涉及锂和钒氧化物。 该氧化物对应于式Li1 +αV3O8（0,1≤α≤0.25）并且由长度L为400-1000nm，宽度为10

公开(公告)号：EP1831109A1

公开(公告)日：2007-09-12

申请号：EP05809094.5

申请日：2005-10-18

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GUYOMARD, Dominique ,  DESCHAMPS, Marc ,  DUBARRY, Matthieu ,  MOREL, Benoit ,  GAUBICHER, Joël

IPC分类号： C01G31/00 ,  H01M4/58

CPC分类号： C01G31/00 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/136 ,  H01M4/405 ,  H01M4/485 ,  H01M4/525 ,  H01M4/58 ,  H01M4/5815 ,  H01M4/5825 ,  H01M4/62 ,  H01M4/625 ,  H01M10/0525

摘要： The invention relates to the preparation of a Ϝ-LiV2O5 optionally carbon material. The method consists in preparing a composition consisting of carbon and Li and V precursors, and in subjecting it to thermal treatment. The composition is prepared by bringing carbon, V2O5-α and a Li precursor into contact, the quantities thereof being such that the ratio of concentrations [V2O5]/[Li] is 0.95 1.05, carbon exceeding by at least 25 % in relation to the stoichiometry. Thermal treatment is carried out in two stages: a first stage at a temperature of 90 °C -150 °C during 1 -12 hours; a second stage at a temperature of 420 °C - 500 °C, during 10 mins - 1 hour, in a nitrogen or argon atmosphere or in a vacuum. Applications: positive-electrode active matter.

公开(公告)号：EP1831945A2

公开(公告)日：2007-09-12

申请号：EP05809230.5

申请日：2005-10-18

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GAUBICHER, Joël ,  GUYOMARD, Dominique ,  DUBARRY, Matthieu ,  DESCHAMPS, Marc ,  MOREAU, Philippe

IPC分类号： H01M4/48 ,  H01M10/40 ,  C01G31/02 ,  C01D15/02 ,  C01B31/00

CPC分类号： H01M4/622 ,  B01J23/22 ,  H01M4/133 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2004/028 ,  Y10S977/773 ,  Y10S977/811 ,  Y10T428/292 ,  Y10T428/2993

摘要： The invention relates to a nanostructured material. Said material is a nanostructured carbon material consisting of agglomerates of small needles of Li1+aV3O8 and ßLixV2O5 (0,l≤ α ≤ 0,25 et 0,03 ≤ x ≤ 0,667 surrounded by a discontinuous coating of spherical carbon particles. It is obtained by means of a process consisting in preparing a carbon precursor gel by bringing carbon, V2O5- α an a Li precursor into contact with each other, the amounts thereof being such that the ratio of concentrations [V2O5]/[Li] ranges from 1.15 to 1.5, and the mass ratio (carbon)/ (carbon + V2O5+ Li precursor) is 10 to 15, and in subjecting the gel to heat treatment including a first stage at 8O0C - 15O0C pendant 3-12 h, and a second stage between 3000C and 35O0C, during 10 mins to 1 hour, in a nitrogen or argon atmosphere. n. Applications: positive-electrode active material.

公开(公告)号：EP1718567A2

公开(公告)日：2006-11-08

申请号：EP05717638.0

申请日：2005-02-16

申请人： Batscap ,  Centre National de la Recherche Scientifique (CNRS)

发明人： GUYOMARD, Dominique ,  DUBARRY, Matthieu ,  DESCHAMPS, Marc ,  GAUBICHER, Joel

IPC分类号： C01G31/00

CPC分类号： H01M4/485 ,  C01G31/00 ,  C01P2004/03 ,  C01P2004/10 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/136 ,  H01M10/052

摘要： The invention relates to a method for preparing a lithium and vanadium oxide and the thus obtained products consisting in preparing a precursor gel by reacting hydrogen peroxide with V2O5-α in an aqueous medium in the presence of a lithium precursor and in exposing said gel to a heat treatment in an oxidant atmosphere at a temperature ranging from 260 °C to 580 °C. A compound of a formula Li1+α V3O8, (0,1=α= 0,25) consists of needle-shaped grains having a bimodal distribution, wherein the length (L) of the first distribution needles ranges from 10 to 50 νm and the length (L) of the second distribution needles ranges from 1 to 10 νm. When l is the grain width, L the length and e the thickness thereof, said dimensions are such as 4

摘要翻译： 含有呈双峰分布的针状晶粒的锂钒氧化物复合物（I）是新的。 式Li 1 +αV 3 O 8（其中α大于0.1且小于0.25）的钒钒络合物（I），其包含呈现双峰分布的针形式的晶粒（其中针的第一种模式的长度为10 -50微米，针的长度为1-50微米，长宽比和长度比大于4，小于100），是新的。 还包括：（1）（I）的准备; （2）锂电池用正极（A），其包含（I）作为活性物质; 和（3）包含（A）和由电解质分离的负极的电池，所述电解质在溶剂中包含锂盐溶液。

公开(公告)号：EP1602139A2

公开(公告)日：2005-12-07

申请号：EP04717657.3

申请日：2004-03-05

申请人： Batscap ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

发明人： GUYOMARD, Dominique ,  GUY, Delphine ,  LESTRIEZ, Bernard ,  GAUBICHER, Jo[l ,  DESCHAMPS, Marc

IPC分类号： H01M4/62

CPC分类号： H01M4/13 ,  H01G11/24 ,  H01G11/32 ,  H01G11/38 ,  H01G11/48 ,  H01G11/50 ,  H01G11/56 ,  H01M4/131 ,  H01M4/136 ,  H01M4/139 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  Y02E60/13 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The invention relates to a method for producing material for composite electrode. The aim of said invention is to produce a composite material consisting of an active electrode material M1, a conductive material (C1), an organic binder and a salt. Said binder comprises a polymer (P1) whose mass composition in heteroatoms O, N, P or S is equal to or higher than 15 %, a polymer (P2) whose mass composition in heteroatoms O, N, P or S is equal or lower than 5 %, and an liquid non-volatile organic solvent (S1). Said method comprises a stage for preparing a viscous solution containing at least one type of polymers (P1) and P2, the material C1, the active electrode material M1 and at least one type of the liquid non-volatile organic solvent S1, and a stage consisting in forming a film from the thus obtained viscous solution.

公开(公告)号：EP2351126B1

公开(公告)日：2013-09-11

申请号：EP09755977.7

申请日：2009-10-07

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GAUBICHER, Joël ,  GUYOMARD, Dominique ,  DESCHAMPS, Marc ,  LESTRIEZ, Bernard ,  TANGUY, François

IPC分类号： H01M4/36 ,  H01M4/62 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/40 ,  H01M10/052

CPC分类号： H01M4/5825 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/405 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  Y10T29/49108 ,  Y10T29/49115

公开(公告)号：EP2351126A1

公开(公告)日：2011-08-03

申请号：EP09755977.7

申请日：2009-10-07

申请人： Batscap ,  Centre National de la Recherche Scientifique

发明人： GAUBICHER, Joël ,  GUYOMARD, Dominique ,  DESCHAMPS, Marc ,  LESTRIEZ, Bernard ,  TANGUY, François

IPC分类号： H01M4/62 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/13 ,  H01M4/36 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/40

CPC分类号： H01M4/5825 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/405 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The subject of the invention is an electrode comprising an electrically conducting support carrying an electrode material, which comprises an active substance consisting of particles of a complex oxide which at their surface carry organic phosphorous groups fixed by covalent bonding. The complex oxide may be LiV
3 O
8 , LiMn
2 O
4 , LiCoO
2 , LiMPO
4 with M = Fe, Mn or Co, Li
2 MSiO
4 with M = Fe, Mn or Co, LiFeBO
3 , Li
4 Ti
5 O
12 , LiMn
2 O
4 , LiNi
1-y-z Mn
y Co
z Al
t O
2 (0 2 O
5 , MnO
2 , LiFePO
4 F, Li
3 V
2 (PO
4 )
3 , and LiVPO
4 F. The electrode is useful in particular for lithium batteries.

摘要翻译： 电极包括承载电极材料的导电载体，其具有由复合氧化物颗粒组成的活性物质，所述复合氧化物在其表面带有通过共价键固定的有机磷基团。 复合氧化物可以是具有M = Fe，Mn或Co的LiV 3 O 8，LiMn 2 O 4，LiCoO 2，具有M = Fe，Mn或Co的Li 2 MSiO 4，LiFeBO 3，Li 4 Ti 5 O 12，LiMn 2 O 4，LiNi 1-y-z Mn x Co y Al 2 O 2（O 2 O 5，MnO 2，LiFePO 4 F， Li3V2（PO4）3和LiVPO4F，电极特别适用于锂电池。

公开(公告)号：EP3592744A1

公开(公告)日：2020-01-15

申请号：EP18712972.1

申请日：2018-03-07

申请人： Blue Solutions ,  Centre National de la Recherche Scientifique ,  Universite de Nantes

发明人： DESCHAMPS, Marc ,  LECUYER, Margaud ,  PERTICARARI, Sofia ,  POIZOT, Philippe ,  ODOBEL, Fabrice ,  GAUBICHER, Joël ,  GUYOMARD, Dominique

IPC分类号： C07D471/06 ,  H01M8/08 ,  H01M4/60 ,  H01M10/0564

公开(公告)号：EP1718567B1

公开(公告)日：2017-09-13

申请号：EP05717638.0

申请日：2005-02-16

申请人： Blue Solutions ,  Centre National de la Recherche Scientifique (C.N.R.S.)

发明人： GUYOMARD, Dominique ,  DUBARRY, Matthieu ,  DESCHAMPS, Marc ,  GAUBICHER, Joel

IPC分类号： C01G31/00 ,  H01M4/131 ,  H01M4/136 ,  H01M4/485 ,  H01M10/052

CPC分类号： H01M4/485 ,  C01G31/00 ,  C01P2004/03 ,  C01P2004/10 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/136 ,  H01M10/052